# positions[].organizations[].parent[].label
Texas A&M Engineering Experiment Station (TEES)

# overview
My research has traditionally been centered around organometallic chemistry, and from this core area branches into catalysis, organic synthesis, enantioselective reactions, stereochemistry, mechanism, and materials chemistry. About half of my group is involved with catalysis projects. Areas receiving emphasis include (a) structurally novel new families of highly enantioselective catalysts, (b) metal-containing "organocatalysts" and (c) recoverable catalysts, particularly those with "ponytails" of the formula (CH2)m(CF2)nF; these can be recycled via "fluorous" liquid or solid phases, such as Teflon. The other half of my group synthesizes organometallic building blocks for molecular devices. These include (a) molecular wires composed of metal endgroups and linear (sp) carbon chains, including stable species with C28 bridges, (b) analogs in which the charge-transmitting bridges are insulated by a pair of polymethylene or (CH2)n chains that adopt a double-helical conformation, (c) polygons and multistranded molecular wires based upon such building blocks, and (d) molecular gyroscopes and compasses consisting of a rotating MLn fragment and an external cage (stator) that insulates the rotator from neighboring molecules, exactly as with the commercial gyroscopes used for aircraft and space-station navigation.

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0307 Theoretical And Computational Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0307 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0307 Theoretical And Computational Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0202 Atomic, Molecular, Nuclear, Particle And Plasma Physics

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
12 Responsible Consumption And Production

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# educationAndTraining[].organization.label
University of Michigan-Ann Arbor - (Ann Arbor, Michigan, United States)

# educationAndTraining[].organization.label
Stanford University - (Stanford, California, United States)

# awardsAndHonors[].label
Association of Former Students University-Level Distinguished Achievement Award, The

# awardsAndHonors[].label
Alexander von Humboldt Senior Research Award

# awardsAndHonors[].label
Distinguished Scholarly and Creative Research Award

# publications[].label
Metal-Templated Hydrogen Bond Donors as "Organocatalysts" for Carbon-Carbon Bond Forming Reactions: Syntheses, Structures, and Reactivities of 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes

# publications[].label
SYNTHESIS, CONFORMATION, AND REACTIVITY OF THE RHENIUM PHOSPHIDE COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(PPH2) - THE GAUCHE EFFECT IN TRANSITION-METAL CHEMISTRY

# publications[].label
Award-Winning Organometallic Chemistry: The Year 2012 Israel Prize

# publications[].label
CYCLOTRIMERIZATION OF CYCLIC DIYNES VIA METAL ATOM CO-CONDENSATION - REVISED STRUCTURE FOR REPORTED PERCYCLOPHANE-4

# publications[].label
Synthesis, reactions, and properties of new fluorocarbon-immobilized catalysts: Applications in organic synthesis.

# publications[].label
FLUO 6-Fluorocarbon microenvironments and phases for catalyst activation and recovery

# publications[].label
Enantioselective catalysis of intramolecular Morita-Baylis-Hillman and related reactions by chiral rhenium-containing phosphines of the formula (eta(5)-C5H5)Re(NO)(PPh3)(CH2PAr2)

# publications[].label
SYNTHESIS, STRUCTURE, AND DYNAMIC BEHAVIOR OF SYMMETRICAL CIS-ALKENE AND TRANS-ALKENE COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - BINDING SELECTIVITIES AND ISOMERIZATION PROCESSES

# publications[].label
Associate Editors, Past, Present, and Future: A Warm Welcome to Professor Deryn E. Fogg

# publications[].label
Award-Winning Organometallic Chemistry: the Israeli Chemical Society (ICS) Outstanding Young Scientist Prize

# publications[].label
Efficient syntheses of fluorous primary phosphines that do not require PH3

# publications[].label
SYNTHESES AND STRUCTURES OF COMPLEXES OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS AND THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - DIVERGENT KINETIC AND THERMODYNAMIC O=C/C=C BINDING SELECTIVITIES

# publications[].label
SYNTHESES AND STRUCTURES OF UNSYMMETRICALLY 1,1-DISUBSTITUTED AND 1,2-DISUBSTITUTED ALKENE COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+ - ENANTIOFACE BINDING SELECTIVITIES AND CONFORMATIONAL EQUILIBRIA

# publications[].label
Convenient syntheses of fluorous aryl iodides and hypervalent iodine compounds: ArI(L)n reagents that are recoverable by simple liquid/liquid biphase workups, and applications in oxidations of hydroquinones.

# publications[].label
Potentiometric sensors based on fluorous membranes doped with highly selective ionophores for carbonate.

# publications[].label
A synthetic breakthrough into an unanticipated stability regime: a series of isolable complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 polyynediyl chains span two platinum atoms.

# publications[].label
1ST CARBONYLATION OF AN ISOLABLE METAL ALPHA-HYDROXYALKYL COMPLEX - GENERAL-SYNTHESIS AND CARBONYLATION CHEMISTRY OF METALLACYCLIC ALPHA-HYDROXYALKYL AND RELATED COMPLEXES

# publications[].label
THE SELECTIVE ACTIVATION OF ONE METHYL KETONE ENANTIOFACE VIA DELTA-BINDING TO A CHIRAL METAL TEMPLATE - SYNTHESIS AND REACTIVITY OF RHENIUM KETONE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-1-ME(R)C=O)]+PF6-

# publications[].label
Enantioselective Syntheses of Multiply Functionalized Six-Membered Carbocycles from Nitroalkenes and ,-Unsaturated -Ketoesters using Chiral Catalysts Derived from Cobalt(III) and 1,2-Diphenylethylenediamine

# publications[].label
Syntheses, Structures, and Dynamic Properties of Dicobalt pi Complexes of Diplatinum Polyynediyl Complexes

# publications[].label
ACTIVATION OF ORGANIC CARBONYL-COMPOUNDS BY LEWIS-ACIDS - RELATIVE REACTIVITIES OF SIGMA AND PI-ADDUCTS TOWARD NUCLEOPHILES AND IMPLICATIONS FOR ENANTIOSELECTIVE ADDITION-REACTIONS

# publications[].label
A New Associate Editor, and an Appreciation

# publications[].label
SYNTHETIC APPROACHES TO THE CHIRAL, PYRAMIDAL, TRANSITION-METAL LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+X- - GENERATION, CHARACTERIZATION, AND REACTIONS OF A DICHLOROMETHANE ADDUCT

# publications[].label
Platinum complexes containing or derived from olefinic phosphines P(X)((CH2)6CH=CH2)2 (X = OH, Ph, (CH2)6CH=CH2); ring closing metatheses, structures, and trans/cis isomerizations

# publications[].label
Award-Winning Organometallic Chemistry:(1) The 2013 Yao Zeng Award in Organometallic Chemistry (vol 32, pg 6851, 2013)

# publications[].label
Quest for stable wire-like sp carbon chains capped by bis(tri-p-tolylphosphine)arylplatinum with more than 30 sp carbon atoms

# publications[].label
Synthesis, structure, and reactivity of bridging cyanide complexes of the formula [(5-C5R5)Re(NO)(PPh3)CN(Ph 3P)(ON)Re(5-C5R5)] +TfO- (R, R = H, Me)

# publications[].label
Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate

# publications[].label
New trends and developments in fluorous catalysis.

# publications[].label
Hydrogen bond mediated enantioselective organic transformations by bifunctional Werner complexes

# publications[].label
Fluorous catalysis without fluorous solvents: a friendlier catalyst recovery/recycling protocol based upon thermomorphic properties and liquid/solid phase separation.

# publications[].label
A new route to heterobimetallic C-3 complexes via C C metatheses of 1,3-diynyl ligands: Synthesis and structure of (eta(5)-C5Me5)Re(NO)(PPh3)(C CC )W(O-t-Bu)(3)

# publications[].label
Transition metal complexes for enantioselective catalysis of carbon-carbon, carbon-heteroatom, and carbon-hydrogen bond forming reactions

# publications[].label
Synthesis, crystal structure, and reactions of the 17-valence-electron rhenium methyl complex [(eta(5)-C5Me5)Re(NO)(P(4-C6H4CH3)(3))(CH3)](center dot+) B(3,5-C6H3(CF3)(2))(4)(-): experimental and computational bonding comparisons with 18-electron methyl and methylidene complexes

# publications[].label
Supramolecular chemistry of chiral rhenium Lewis acids of the formula [(eta(5)-C5R5)Re(NO)(CO)(PPh3)](+): Synthesis and crystal structure of a 2 : 1 adduct of an ammonia complex and 18-crown-6

# publications[].label
Dibridgehead diphosphine dioxide cages: Syntheses and unusual structural features

# publications[].label
Synthesis of fluorous ponytail-tagged pyridine ligands and their applications in analogs of Grubbs 3rd generation catalyst

# publications[].label
Phase transfer of enantiopure Werner cations into organic solvents: an overlooked family of chiral hydrogen bond donors for enantioselective catalysis.

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF BRIDGING HALIDE-COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)]2X+BF4- - PREFERENTIAL BINDING OF ONE ENANTIOMER OF HALIDE-COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(X) BY THE CHIRAL LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
An unexpected insertion of acetone into the silicon-carbon terminus of an sp carbon chain: syntheses and structures of model monoplatinum hexatriynyl and octatetraynyl complexes

# publications[].label
Gyroscope-like platinum(IV) complexes of the macrocyclic dibridgehead diphosphine P((CH2)14)(3)P

# publications[].label
Syntheses of dimetallamacrocycles by intramolecular oxidative couplings of dinuclear bis(1,3-butadiynyl) complexes (see abstract)

# publications[].label
Phase transfer activation of catalysts for olefin metathesis

# publications[].label
HIGH-PRESSURE CYCLOADDITIONS OF PYRONES - SYNTHESIS OF HIGHLY FUNCTIONALIZED 6-MEMBERED RINGS BY INHIBITION OF CARBON-DIOXIDE LOSS

# publications[].label
Octahedral Gyroscope-like Molecules Consisting of Rhenium Rotators within Cage-like Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties.

# publications[].label
SUBSTITUTION MECHANISMS AT METAL-CARBONYL CENTERS - CONVERSION OF PH3P(CO)4REBR TO PH3P(CO)4RECH3 VIA AN ANIONIC ACYL INTERMEDIATE

# publications[].label
Syntheses, Structures, Reactivities, and Basicities of Quinolinyl and Isoquinolinyl Complexes of an Electron Rich Chiral Rhenium Fragment and Their Electrophilic Addition Products.

# publications[].label
A NEW CATALYST FOR THE EPIMERIZATION OF SECONDARY ALCOHOLS - CARBON-HYDROGEN BOND ACTIVATION IN RHENIUM ALKOXIDE COMPLEXES (ETA-5-C5R5)RE(NO)(PPH3)(OCHRR1)

# publications[].label
SUBSTITUENT EFFECTS UPON ALKYL MIGRATION TO COORDINATED CO - SYNTHESES AND CARBONYLATION STUDIES OF (CO)5MNCH2I AND (CO)5MNCH2OSI(CH3)3

# publications[].label
Facile and selective carbonylation of methane in superacids

# publications[].label
Ionic transformations in extremely nonpolar fluorous media: easily recoverable phase-transfer catalysts for halide-substitution reactions.

# publications[].label
Chiral Werner complexes as hydrogen bond donor catalysts for enantioselective organic synthesis

# publications[].label
MECHANISM OF EQUILIBRATION OF DIASTEREOMERIC CHIRAL RHENIUM ALKENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+BF4- - THE METAL TRAVERSES BETWEEN ALKENE ENANTIOFACES WITHOUT DISSOCIATION

# publications[].label
PYRROLYL-N AND PYRROLYL-C COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - SYNTHESIS, PROTONATION, AND REARRANGEMENT CHEMISTRY

# publications[].label
SYNTHESES AND REACTIONS OF RHENIUM VINYLIDENE AND ACETYLIDE COMPLEXES - UNPRECEDENTED CHIRALITY TRANSFER THROUGH A C=C TRIPLE BOND

# publications[].label
PREPARATION AND ALKYLATION REACTIONS OF K+[(CO)4-FESI(CH3)3]- - REDUCTIVE ELIMINATION OF TETRAMETHYLSILANE FROM ISOLABLE (CO)4FERSI(CH3)3 COMPLEXES

# publications[].label
Additions and corrections published in 2013

# publications[].label
HALOGENOLYSIS OF METHYL COMPLEX, (ETA-5-C5H5)RE(NO)(PPH3)(CH3) - STEREOCHEMISTRY AND MECHANISM

# publications[].label
MECHANISM OF EQUILIBRATION OF DIASTEREOMERIC RHENIUM AMIDE COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(NHCHRR') - RHENIUM VS CARBON EPIMERIZATION

# publications[].label
Convenient and convergent syntheses of long-chain alpha,omega-dibromides and diphosphines of the formula X(CH2)(n)X (n=18-32)

# publications[].label
Syntheses and structural analyses of chiral rhenium containing amines of the formula (eta(5)-C5H5)Re(NO)(PPh3)((CH2)(n)NRR ') (n=0, 1)

# publications[].label
Olefin metatheses in metal coordination spheres: a new approach to steric shielding in dirhenium sp carbon chain complexes of the formula (eta(5)-C5Me5)-Re(NO)(PR3)(C CC CC CC C)(R3P)(ON)Re(eta(5)-C5Me5)

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF FUNCTIONALIZED GERMYL COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(GEPH2X) - EQUILIBRIA INVOLVING THE GERMYLENE COMPLEX [(ETA-5-C5H5)RE(NO)(PPH3)(=GEPH2)]+TFO-

# publications[].label
Highly bulky and electron-rich terminal ruthenium phosphido complexes: new donor ligands for palladium-catalyzed suzuki cross-couplings.

# publications[].label
Award-Winning Organometallic Chemistry: Le Grand Prix Achille Le Bel of the Societe Chimique de France (SCF)

# publications[].label
Homeomorphic Isomerization as a Design Element in Container Molecules; Binding, Displacement, and Selective Transport of MCl2 Species (M = Pt, Pd, Ni).

# publications[].label
ALPHA-SILYLOXY AND ALPHA-HYDROXY MANGANESE ALKYLS - GENERATION VIA A NEW 5-MEMBERED METALLOCYCLE

# publications[].label
Fluorous chemistry and technology - A symposium showcases ever-broadening frontiers

# publications[].label
ELECTROPHILE INDUCED DISPROPORTIONATION OF THE NEUTRAL FORMYL (ETA-C5H5)RE(PPH3)(NO)-(CHO) - ISOLATION AND PROPERTIES OF THE RHENIUM METHYLIDENE [(ETA-C5H5)RE(PPH3)(NO)(CH2)]+

# publications[].label
A NEW ROUTE TO METAL ALKYLIDENE COMPLEXES - SYNTHESIS OF YLIDE ADDUCTS (CO)4FE-CH(R)P+AR3 FROM ALDEHYDES, TRIARYLPHOSPHINES, AND (CO)4FESI(CH3)2CH2CH2SI(CH3)2

# publications[].label
ENE REACTIONS OF BETA-PINENE AT ROOM-TEMPERATURE AND 40-KBAR PRESSURE

# publications[].label
REACTION OF THE YLIDE COMPLEX [(ETA-5-C5H5)RE(NO)(PPH3)(CH2P+AR3)]PF6- WITH NORMAL-BUTYL-LITHIUM TETRAMETHYLETHYLENEDIAMINE - GENERATION AND STEREOSPECIFIC ALKYLATION OF A TRANSITION METAL-SUBSTITUTED WITTIG REAGENT

# publications[].label
A new family of highly stable metal capped sp-carbon wires.

# publications[].label
Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer ligands and metal complexes.

# publications[].label
SYNTHESIS AND CHEMISTRY OF SECONDARY ALKYL IODIDE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(ICHRR')]+BF4-

# publications[].label
Introduction - Fluorous chemistry: from biphasic catalysis to a parallel chemical universe and beyond

# publications[].label
GENERATION AND REACTIVITY OF THE CHIRAL RHENIUM CHLOROBENZENE COMPLEX [ETA-5-C5H5)RE(NO)(PPH3)(CIC6H5)]+BF4- - AN IMPROVED FUNCTIONAL EQUIVALENT OF THE CHIRAL LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+BF4-

# publications[].label
Configurational equilibria in amido and lithioamido complexes of formulas (5-C5H5)Re(NO)(PAr3)(NHCHRR) and (5-C5H5)Re(NO)(PAr3)(NLiR): Epimerization occurs at rhenium via phosphine dissociation

# publications[].label
Tracking Energy Transfer across a Platinum Center.

# publications[].label
FACILE SEPARATIONS OF ENANTIOMERS OF CHIRAL ORGANOMETALLIC COMPOUNDS WITH A BAKERBOND CHIRALCEL HPLC COLUMN

# publications[].label
SYNTHESIS, STRUCTURE, DYNAMIC BEHAVIOR, AND REACTIVITY OF RHENIUM PHOSPHIDO COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(PR2) - THE GAUCHE EFFECT IN TRANSITION-METAL CHEMISTRY

# publications[].label
Editors' Comments on the Addition/Correction to "Synthesis, Structure, and Catalytic Studies of Palladium and Platinum Bis-Sulfoxide Complexes"

# publications[].label
Synthesis and reactivity of novel forms of coordinated carbon: C-8-C-20 chains that span two transition metals.

# publications[].label
Bonding and electronic structure in consanguineous and conjugal iron and rhenium sp carbon chain complexes [MC4M'](n)+: computational analyses of the effect of the metal.

# publications[].label
Methods for attaching metal-capped sp carbon chains to metal clusters: Synthesis, structure and reactivity of rhenium-triosmium carbon complexes[(eta(5)-C(5)Me(5))Re(NO)(PPh(3))(CC)(n)Os-3(CO)(10)H]

# publications[].label
Octahedral gyroscope-like molecules with M(CO)(3)(X) rotators encased in three-spoked diphosphine stators: Syntheses by alkene Metathesis/Hydrogenation sequences, structures, dynamic properties, and reactivities

# publications[].label
Dibridgehead diphosphines that turn themselves inside-out: Molecular recognition and coordination behavior

# publications[].label
Probing inherent helical preferences in Pt-beanpole complexes using molecular mechanics

# publications[].label
Synthesis and reactivity of fluorous and nonfluorous aryl and alkyl iodine(III) dichlorides: new chlorinating reagents that are easily recycled using biphasic protocols.

# publications[].label
"Catalyst-on-a-tape"-Teflon: a new delivery and recovery method for homogeneous fluorous catalysts.

# publications[].label
BINUCLEAR AND MIXED METAL FORMYL COMPLEXES - ISOLATION, CHARACTERIZATION, AND CHEMISTRY

# publications[].label
Additions of PH(3) to Monosubstituted Alkenes of the Formula H(2)C=CH(CH(2))(x)()(CF(2))(y)()CF(3): Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkylphosphines with Modulated Electronic Properties and Fluorous Phase Affinities.

# publications[].label
Synthesis and properties of chiral rhenium pentatetraenylidene complexes of the formula [(eta(5)-C5Me5)Re(NO)(PPh3)(= C = C = C = C = CAr2)]+BF4- (CAr2=9-fluorenylidene)

# publications[].label
REGIOSPECIFIC, DIASTEREOSPECIFIC AND ENANTIOSPECIFIC NUCLEOPHILIC ADDITIONS TO CHIRAL MONOSUBSTITUTED ALKENE COMPLEXES OF THE FORMULA [ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+ BF4-

# publications[].label
Triisopropylsilyl (TIPS) Alkynes as Building Blocks for Syntheses of Platinum Triisopropylsilylpolyynyl and Diplatinum Polyynediyl Complexes

# publications[].label
INOR 13-Alkene metathesis in metal coordination spheres: The quest for molecular gyroscopes

# publications[].label
EPIMERIZATION OF SECONDARY ALCOHOLS BY NEW HOMOGENEOUS, LOW OXIDATION-STATE METAL-CATALYSTS - CARBON HYDROGEN-BOND ACTIVATION IN RHENIUM ALKOXIDE COMPLEXES (ETA-5-C5R5)RE(NO)(PPH3)(OCHRR')

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF ALLENE COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
Werner Complexes with -Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen-Bond-Donor Catalysts for Highly Enantioselective Michael Additions.

# publications[].label
Solvent free enantioselective catalysis with chiral cobalt(iii) Werner complexes via ball milling

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF STABLE ALKYL AND ARYL IODIDE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(IR)]+BF4-

# publications[].label
REACTIONS OF (CO)5MNSI(CH3)3 WITH ORGANIC CARBONYL-COMPOUNDS

# publications[].label
REACTIONS OF (CO)5MNSI(CH3)3 WITH ALPHA-BROMO CARBONYL AND RELATED ORGANIC-COMPOUNDS - FACILE REDUCTIVE SILYLATION

# publications[].label
Rhenium-containing phosphorus donor ligands for palladium-catalyzed Suzuki cross-coupling reactions: A new strategy for high-activity systems

# publications[].label
Cubic nonlinear optical properties of platinum-terminated polyynediyl chains.

# publications[].label
Award-Winning Organometallic Chemistry: The 2012 Werner Prize of the Swiss Chemical Society

# publications[].label
Gyroscope-like molecules consisting of three-spoke stators that enclose "switchable" neutral dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and Rh(CO)2I species.

# publications[].label
New chiral cyclopentadienylrhenium Lewis acids featuring fluorinated triarylphosphanes and enhanced acceptor abilities - An unusual carbon-fluorine bond activation in a metal coordination sphere

# publications[].label
SELECTIVE BINDING AND ACTIVATION OF ONE ALDEHYDE ENANTIOFACE BY A CHIRAL TRANSITION-METAL LEWIS ACID - SYNTHESIS, STRUCTURE, AND REACTIVITY OF RHENIUM ALDEHYDE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-2-O=CHR)]+X-

# publications[].label
Nonenzymic nitrogen fixation by an iron-molybdenum model for nitrogenase.

# publications[].label
NEW FAMILIES OF COORDINATED CARBON - OXIDATIVE COUPLING OF AN ETHYNYL COMPLEX TO ISOLABLE AND CRYSTALLOGRAPHICALLY CHARACTERIZED MC-EQUIVALENT-TO-CC-EQUIVALENT-TO-CM AND +M=C=C=C=C=M+ ASSEMBLIES

# publications[].label
SYNTHESIS AND CHEMISTRY OF CHIRAL RHENIUM ACYLS (ETA-C5H5)RE(NO)(PPH3)(COR)

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE NITROSYL LIGAND LEWIS ACID ADDUCT (ETA-5-C5H5)RE(NO.BCL3)(PPH3)(SIME2CL)

# publications[].label
A NEW ALKENE CARBON-HYDROGEN BOND ACTIVATION REACTION - FACILE AND STEREOSPECIFIC VINYLIC DEPROTONATION OF THE CHIRAL CATIONIC RHENIUM ALKENE COMPLEXES [(ETA(5)-C5H5)RE(NO)(PPH(3))(H2C=CHR)](BF4-)

# publications[].label
Ring opening metathesis polymerization of an 4-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of  bound metal fragments.

# publications[].label
Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C1 Chemistry.

# publications[].label
Syntheses, rearrangements, and structural analyses of unsaturated nitrogen donor ligands derived from diphenyldiazomethane and the chiral rhenium Lewis acid [(5-C5H5)Re(NO)(PPh3)].

# publications[].label
REACTIONS OF KETALS AND ACETALS WITH (CO)5MNSI(CH3)3 - A NEW VINYL ETHER SYNTHESIS

# publications[].label
Steric control of the in/out sense of bridgehead substituents in macrobicyclic compounds: isolation of new "crossed chain" variants of in/out isomers.

# publications[].label
Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity.

# publications[].label
SYNTHESIS AND STRUCTURE OF CHIRAL RHENIUM ALLYL COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(CH2C(R')=CHR)

# publications[].label
A NEW FORM OF COORDINATED CARBON - A C3 CHAIN THAT IS ANCHORED BY A TRANSITION-METAL ON EACH END AND SPANNED BY A 1/3

# publications[].label
Gyroscope-Like Platinum and Palladium Complexes with Trans-Spanning Bis(pyridine) Ligands

# publications[].label
UNPRECEDENTED REGIOSPECIFICITY AND STEREOSPECIFICITY IN REACTIONS OF PH3C+PF6- WITH RHENIUM ALKYLS OF THE FORMULA (ETA-C5H5)RE(NO)(PPH3)(CH2R)

# publications[].label
C-8 and C-12 sp carbon chains that span two platinum atoms: The first structurally characterized 1,3,5,7,9,11-hexayne

# publications[].label
Fluorous catalysis under homogeneous conditions without fluorous solvents: a "greener" catalyst recycling protocol based upon temperature-dependent solubilities and liquid/solid phase separation.

# publications[].label
ELECTROCHEMICAL OXIDATION OF RHENIUM ALKYL COMPLEXES OF THE TYPE [RE(ETA-C5H5)(NO)(PPH3)R] - IMPLICATIONS FOR THE MECHANISM OF HYDRIDE ABSTRACTION BY PH3C+PF6-

# publications[].label
DEPROTONATION OF RHENIUM TERMINAL ACETYLIDE COMPLEXES OF THE FORMULA (ETA-5-C5R5)RE(NO)(PPH3)(CCH) - GENERATION AND REACTIVITY OF RHENIUM LITHIUM C2 COMPLEXES

# publications[].label
Award-Winning Organometallic Chemistry: The 2014 RSC Main Group Chemistry Award

# publications[].label
Oxidations of secondary alcohols to ketones using easily recyclable bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)(n-1)I(OCOCF3)2.

# publications[].label
SYNTHESIS AND REACTIVITY OF FUNCTIONALIZED DIMETHYLSILYL COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(SIME2X) - NEW BASE-STABILIZED SILYLENE COMPLEXES, NOVEL LEWIS ACID ADDUCTS, AND EVIDENCE FOR BASE-FREE SILYLENE COMPLEXES

# publications[].label
REACTIONS OF (CO)5MNSI(CH3)3 AND CO WITH ALDEHYDES AND CYCLIC ETHERS - SYNTHESES OF FUNCTIONALIZED PENTACARBONYLMANGANESE ACYLS AND HOMOLOGATED ORGANIC-COMPOUNDS

# publications[].label
A Quest for Atropisomerism in Cojoined Square-Planar Metal Complexes: Synthesis and Structures of Sterically Congested Diplatinum Ethynediyl Adducts

# publications[].label
Launching Werner Complexes into the Modern Era of Catalytic Enantioselective Organic Synthesis.

# publications[].label
A NEW CATALYST FOR THE EPIMERIZATION OF SECONDARY ALCOHOLS - CARBON HYDROGEN-BOND ACTIVATION IN THE RHENIUM ALKOXIDE COMPLEXES (ETA-5-C5R5)RE(NO)(PPH3)(OCHRR')

# publications[].label
DEOXYGENATION OF NITRO AND NITROSO ARENES VIA CHROMIUM ATOM CO-CONDENSATION

# publications[].label
The robust, readily available cobalt(iii) trication [Co(NH2CHPhCHPhNH2)3]3+ is a progenitor of broadly applicable chirality and prochirality sensing agents.

# publications[].label
STRUCTURES OF PROPIONALDEHYDE, BUTYRALDEHYDE, AND PIVALALDEHYDE COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+

# publications[].label
Festschrift in Honor of Istvan T. Horvath

# publications[].label
CHEMISTRY VIA METAL ATOM CO-CONDENSATION - ISOMERIZATION AND COMPLEXATION REACTIONS OF ORGANOCYCLOPROPANES AND SPIROCYCLES

# publications[].label
Chelating diphosphines that contain a rhenium stereocenter in the backbone: Applications in rhodium-catalyzed enantioselective ketone hydrosilylations and alkene hydrogenations

# publications[].label
Frontiers in Metal-Catalyzed Polymerization: Designer Metallocenes, Designs on New Monomers, Demystifying MAO, Metathesis Dshabill.

# publications[].label
Organometallic reactivity patterns in fluorocarbons and implications for catalysis: Synthesis, structure, solubility, and oxidative additions of a fluorous analogue of Vaska's complex, trans-Ir(CO)(Cl)[P(CH<inf>2</inf>CH<inf>2</inf>(CF<inf>2</inf>) <inf>5</inf>CF<inf>3</inf>)<inf>3</inf>]<inf>2</inf>

# publications[].label
A new cyclometalation motif: Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone and are catalyst precursors for Heck reactions

# publications[].label
A "conjugal" consanguineous family of butadiynediyl-derived complexes: Synthesis and electronic ground states of neutral, radical cationic, and dicationic iron/rhenium C-4 species

# publications[].label
Reactions of t-BuOK and dibenzyl, benzyl allyl, and allyl beta-keto sulfide complexes of the chiral rhenium Lewis acid [(eta(5)-C5H5)Re(NO)(PPh(3))](+): Highly diastereoselective or chemoselective [2,3]-sigmatropic rearrangements

# publications[].label
Catalysis of Intramolecular Morita-Baylis-Hiliman and Rauhut-Currier Reactions by Fluorous Phosphines; Facile Recovery by Liquid/Solid Organic/Fluorous Biphase Protocols Involving Precipitation, Teflon (R) Tape, and Gore-Rastex (R) Fiber

# publications[].label
Alkyne metatheses in transition metal coordination spheres: Convenient tungsten- and molybdenum-catalyzed syntheses of novel metallamacrocycles

# publications[].label
Toward Frameworks with Multiple Aligned and Interactive Fe(CO)3 Rotators: Syntheses and Structures of Diiron Complexes Linked by Two trans-Diaxial ,-Diphosphine Ligands Ar2P(CH2)nPAr2.

# publications[].label
Origin of Shielding and Deshielding Effects in NMR Spectra of Organic Conjugated Polyynes.

# publications[].label
New Author Guidelines for 2014: A Format for Computational Structural Data That Can Be Opened with Freely Available Programs such as "Mercury"

# publications[].label
Synthesis, Structure, and Oxidative Additions of a Fluorous Analogue of Vaska's Complex, trans-[IrCl(CO){P[CH<inf>2</inf>CH<inf>2</inf>(CF<inf>2</inf>) <inf>5</inf>CF<inf>3</inf>]<inf>3</inf>}<inf>2</inf>] - Altered Reactivity in Fluorocarbons and Implications for Catalysis

# publications[].label
Substitution and Catalytic Chemistry of Gyroscope-Like Complexes Derived from Cl-Rh-CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands

# publications[].label
SYNTHESIS, STRUCTURE AND REACTIVITY OF CHIRAL RHENIUM ALLENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(RR'C=C=CHR'')]+BF4-.

# publications[].label
NEW FORMS OF COORDINATED CARBON - UNSUPPORTED AND SUPPORTED C3 CHAINS THAT SPAN 2 TRANSITION-METALS

# publications[].label
Azide- and Fluorine-Containing Polystyrenes as Potential "Phosphine Sponges" Based upon Staudinger Reactions: Application to the Phase Transfer Activation of Grubbs' Catalyst

# publications[].label
HIGH-PRESSURE CYCLOADDITIONS OF PYRONES - SYNTHESIS OF HIGHLY FUNCTIONALIZED 6-MEMBERED RINGS BY INHIBITION OF CO2 LOSS

# publications[].label
Computational Investigations of Enantioselection in Carbon-Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts

# publications[].label
Towards multistranded molecular wires: syntheses, structures, and reactivities of tetraplatinum bis(polyynediyl) complexes with [upper bond 1 start]Pt-C(x)-Pt-(P(CH2)3P)2-Pt-C(x)-Pt-(P(CH2)3P[upper bond 1 end])2 cores (x = 4, 6, 8).

# publications[].label
The Inaugural 2012 Organometallics Symposium

# publications[].label
A new transition metal templated reaction: Ring closing olefin metathesis in metal coordination spheres.

# publications[].label
Divergent kinetic and thermodynamic acidity in organotransition-metal hydride complexes: synthesis, structure, and reactivity of the rhenium anion of Li+ [(.eta.-C5H5)Re(NO)(PPh3)]-.

# publications[].label
REACTIONS OF DIAZO-COMPOUNDS AND CHIRAL RHENIUM ALKYLIDENE COMPLEXES OF THE FORMULA [(ETA(5)-C5H5)RE(NO)(PPH(3))(=CHR)]+PF6- - A VERSATILE AND HIGHLY STEREOSELECTIVE ROUTE TO ALKENE COMPLEXES

# publications[].label
Computational Investigation of Dichloromethane Ligand Substitution in the Enantiopure Cation [(5-C5H5)Re(NO)(PPh3)(ClCH2Cl)]+, a Functional Equivalent of a Chiral Lewis Acid

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM ALKYNE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(RCCR')]+BF4-

# publications[].label
SYNTHESIS AND CHEMISTRY OF CHIRAL VINYL RHENIUM COMPLEXES (ETA-C5H5)RE(NO)(PPH3)(CH=CHR) - STEREOSELECTIVE REACTIONS WITH ELECTROPHILES AND A SPONTANEOUS ALKYLIDENE TO OLEFIN REARRANGEMENT

# publications[].label
A VERSATILE NEW SYNTHESIS OF ORGANIC-COMPOUNDS WITH CHIRAL METHYL-GROUPS - STEREOCHEMISTRY OF PROTOLYTIC RHENIUM-CARBON BOND-CLEAVAGE IN CHIRAL ALKYL COMPLEXES (ETA5-C5H5)RE(NO)(PPH3)(R)

# publications[].label
Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis.

# publications[].label
Award-Winning Organometallic Chemistry: The 2012 Strem Chemicals Award for Pure or Applied Inorganic Chemistry of the Canadian Society for Chemistry

# publications[].label
HIGHLY STEREOSELECTIVE REDUCTION OF METHYL KETONE COMPLEXES OF THE CHIRAL LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+ BY K(SEC-C4H9)3BH - SYNTHESIS OF OPTICALLY-ACTIVE SECONDARY ALCOHOLS AND DERIVATIVES

# publications[].label
REACTIONS OF METAL-CARBONYL COMPLEXES WITH TRIALKYLBOROHYDRIDES - SYNTHESIS OF ANIONIC AND NEUTRAL FORMYL COMPLEXES

# publications[].label
SYNTHESIS OF TRANSITION-METAL ANIONS VIA HYDRIDE CLEAVAGE OF METAL-CARBONYL DIMERS

# publications[].label
ORGANIC TRANSFORMATIONS VIA METAL SILANE REAGENTS - SYNTHESES OF VINYL ETHERS FROM DIMETHYL KETALS AND (CO)5MNSI(CH3)3

# publications[].label
Alkene metatheses in transition metal coordination spheres: Effect of ring size and substitution on the efficiencies of macrocyclizations that join trans positions of square-planar platinum complexes

# publications[].label
Convenient modular syntheses of fluorous secondary phosphines and selected derivatives

# publications[].label
Award-Winning Organometallic Chemistry: the 2012 Alfred-Stock-Gedachtnispreis of the GDCh

# publications[].label
Clash of two stereochemical cultures: Stereoisomerism in Werner complexes from an organic perspective

# publications[].label
Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age.

# publications[].label
Syntheses and structures of square planar diplatinum butadiynediyl complexes with two different monophosphine ligands on each terminus; probing the feasibility of a new type of inorganic atropisomerism

# publications[].label
DIASTEREOSELECTIVE 1,2-ADDITIONS OF NUCLEOPHILES TO QUINOLINE COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA(5)-C5H5)RE(NO)(PPH(3))](+)

# publications[].label
CONVENIENT PREPARATION OF METAL-CARBONYL MONOANIONS BY TRIALKYLBOROHYDRIDE CLEAVAGE OF METAL-CARBONYL DIMERS - OBSERVATION AND REACTIONS OF A BIMETALLIC MANGANESE-FORMYL INTERMEDIATE

# publications[].label
DIRECT CONVERSION OF ALDEHYDES, ESTERS, AND 1,2-OXIDES TO ALKANES WITH CARBON SKELETON PRESERVATION

# publications[].label
SYNTHESIS AND PROPERTIES OF [(ETA-C5H5)RE(NO)(PPH3)(=CHC6H5)]+PF6- - A BENZYLIDENE COMPLEX THAT IS FORMED BY A STEREOSPECIFIC ALPHA-HYDRIDE ABSTRACTION, EXISTS AS 2 GEOMETRIC ISOMERS, AND UNDERGOES STEREOSPECIFIC NUCLEOPHILIC-ATTACK

# publications[].label
Synthesis and oxidation of chiral rhenium phosphine methyl complexes of the formula (eta(5)-C5Me5)Re(NO) (PR3)(CH3): in search of radical cations with enhanced kinetic stabilities

# publications[].label
A NEW, STEREOSPECIFIC ALKENE METALATION REACTION - FACILE VINYLIC CARBON-HYDROGEN BOND ACTIVATION IN CHIRAL RHENIUM COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+BF4-

# publications[].label
SYNTHESIS AND STRUCTURE OF SIGMA-COMPLEXES OF THE CHIRAL RHENIUM LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+ AND AROMATIC NITROGEN-HETEROCYCLES

# publications[].label
SYNTHESES AND REACTIVITY OF BRIDGING RHENIUM CO2 COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(CO2M)

# publications[].label
Update 1 of: Carbon in one dimension: structural analysis of the higher conjugated polyynes.

# publications[].label
Synthesis, photovoltaic performances and TD-DFT modeling of push-pull diacetylide platinum complexes in TiO2 based dye-sensitized solar cells.

# publications[].label
Monodisperse Molecular Models for the sp Carbon Allotrope Carbyne; Syntheses, Structures, and Properties of Diplatinum Polyynediyl Complexes with PtC20Pt to PtC52Pt Linkages.

# publications[].label
Recoverable catalysts. Ultimate goals, criteria of evaluation, and the green chemistry interface

# publications[].label
A synthetic breakthrough into an unanticipated stability regime: readily isolable complexes in which C16-C28 polyynediyl chains span two platinum atoms.

# publications[].label
SYNTHESIS AND REACTIVITY OF METALLACYCLIC MANGANESE ALPHA-HYDROXYALKYL COMPLEXES CONTAINING ALIPHATIC BRIDGES AND PHOSPHORUS AND NITROGEN DONOR ATOMS - 1ST CARBONYLATION OF AN ISOLABLE ALPHA-HYDROXYALKYL COMPLEX

# publications[].label
Over four hundred million characters served: 99 volumes, 2567 articles, 85623 pages, and more than 85 million words.

# publications[].label
Alkene and alkyne metatheses in metal coordination spheres: From insulated molecular wires to molecular gyroscopes.

# publications[].label
NEW REARRANGEMENTS LEADING TO ANIONIC ORGANORHENIUM COMPLEXES

# publications[].label
Synthesis and reactivity of new heterodinuclear iron/rhenium C-x complexes of the formula (eta(5)-C5Me5)Re(NO)(PPh3)(C C)(n)(eta(2)-dppe)Fe(eta(5)-C5Me5) (n=3, 4): Redox properties and a dicobalt hexacarbonyl adduct

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF CYCLIC AMINE, AMIDO AND IMINE COMPLEXES OF THE CHIRAL RHENIUM LEWIS ACID [ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
Enantioselective Additions of Stabilized Carbanions to Imines Generated from alpha-Amido Sulfones By Using Lipophilic Salts of Chiral Tris(1,2-diphenylethylenediamine) Cobalt(III) Trications as Hydrogen Bond Donor Catalysts

# publications[].label
GENERATION AND REACTIVITY OF SUBSTITUTION-LABILE DICHLOROMETHANE AND CHLOROBENZENE ADDUCTS OF THE CHIRAL PENTAMETHYLCYCLOPENTADIENYL RHENIUM LEWIS-ACID [(ETA-5-C5ME5)RE(NO)(PPH3)]+

# publications[].label
Werner complexes: A new paradigm in enantioselective hydrogen bond mediated catalysis

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE CHIRAL RHENIUM PHENYL COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(C6H5)

# publications[].label
SYNTHESIS AND DECARBOXYLATION MECHANISM OF THE CHIRAL RHENIUM FORMATE (ETA-C5H5)RE(NO)(PPH3)(OCHO)

# publications[].label
NEW SYNTHETIC CHEMISTRY OF TRANSITION-METAL TRIALKYLSILANE COMPLEXES

# publications[].label
The Future of Organometallic Chemistry (vol 30, pg 1, 2010)

# publications[].label
AN IMPROVED FUNCTIONAL EQUIVALENT OF THE CHIRAL LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+BF4- - GENERATION OF A CHLOROBENZENE ADDUCT AND ITS FACILE CONVERSION TO ALKYNE AND CYCLIC ALKENE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(L)]+BF4-

# publications[].label
Syntheses and reactivity of analogues of Grubbs' second generation metathesis catalyst with fluorous phosphines: A new phase-transfer strategy for catalyst activation

# publications[].label
FRONTIERS IN BIOLOGICAL CHEMISTRY - INTRODUCTION

# publications[].label
CONFIGURATIONAL PROCESSES IN COORDINATED LIGANDS - EXTREMELY FACILE PHOSPHORUS INVERSION IN THE PYRAMIDAL TERMINAL PHOSPHIDE COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(PRR')

# publications[].label
"Heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails: facile syntheses from polybromocyclopentadienyl complexes, phase properties, and electronic effects.

# publications[].label
Design in organometallic synthesis: Molecular wires and gyroscopes

# publications[].label
Trapping of Terminal Platinapolyynes by Copper(I) Catalyzed Click Cycloadditions; Probes of Labile Intermediates in Syntheses of Complexes with Extended sp Carbon Chains, and Crystallographic Studies.

# publications[].label
REACTIONS OF THE TERMINAL RHENIUM ACETYLIDE COMPLEX RE(ETA-5-C5H5)(NO)(PPH3)(CCH) AND BUTYLLITHIUM - GENERATION, ALKYLATION AND STANNYLATION OF LITHIOCARBIDE COMPLEXES OF THE FORMULA RE(ETA-5-C5H4X)(NO)(PPH3)(CCLI) (X = H, LI)

# publications[].label
Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors.

# publications[].label
Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere Hydrogen Bond Donor Catalysts

# publications[].label
Temperature-Controlled Catalyst Recycling: New Protocols Based upon Temperature-Dependent Solubilities of Fluorous Compounds and Solid/Liquid Phase Separations

# publications[].label
Synthesis and characterization of a series of diarsine and substituted diphosphine gyroscopes

# publications[].label
Strategy and design in fluorous phase immobilization: a systematic study of the effect of 'pony tails' (CH2)(3)(CF2)(n-1)CF3 on the partition coefficients of benzenoid compounds

# publications[].label
ELECTROPHILE-INDUCED CYCLIZATIONS OF CHIRAL RHENIUM ETHYNYL AND C2LI COMPLEXES OF THE FORMULA (ETA(5)-C(5)ME(5))RE(NO)(PPH(3))(C-CX) - SYNTHESIS, STRUCTURE, AND REACTIVITY OF UNUSUAL 1,3-DIMETALLATED CYCLIC C4H3 AND C4H(4) SPECIES

# publications[].label
Ionic transformations in extremely nonpolar fluorous media: phase transfer catalysis of halide substitution reactions.

# publications[].label
CONVENIENT ONE-FLASK SYNTHESIS OF DIALKYL SELENIDES AND DISELENIDES VIA LITHIUM TRIETHYLBOROHYDRIDE REDUCTION OF SEX

# publications[].label
Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nucleophilic attack.

# publications[].label
Facile and Selective Carbonylation of Methane in Superacids

# publications[].label
Werner complexes: A new class of chiral hydrogen bond donor catalysts for enantioselective organic reactions

# publications[].label
Dynamic and topological properties of dibridgehead diphosphines and their oxides

# publications[].label
Macrobicyclic diphosphines from olefin metathesis in platinum coordination spheres: Synthesis, structures, and reactivity of three stable isomers

# publications[].label
Role of chlorides in reactivation of contaminant nickel on fluid catalytic cracking (FCC) catalysts

# publications[].label
NEUTRAL METAL FORMYL COMPLEXES - GENERATION, REACTIVITY, AND MODELS FOR FISCHER-TROPSCH CATALYST INTERMEDIATES

# publications[].label
New fluorous ruthenium metathesis pre-catalysts: Synthesis and their employment in phase-transfer activation

# publications[].label
Award-Winning Organometallic Chemistry: The 2011 ACS Award in Organometallic Chemistry

# publications[].label
NOVEL ELECTRON IMPACT-INDUCED HYDROGEN REARRANGEMENTS IN THE MASS-SPECTRA OF ORGANORHENIUM HYDRIDES AND ALKYLS

# publications[].label
Syntheses, Structures, and Spectroscopic Properties of 1,10-Phenanthroline-Based Macrocycles Threaded by PtC8 Pt, PtC12 Pt, and PtC16 Pt Axles: Metal-Capped Rotaxanes as Insulated Molecular Wires.

# publications[].label
GENERATION AND REACTIONS OF CHIRAL, PYRAMIDAL, TRANSITION-METAL LEWIS-ACIDS OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)]+X-

# publications[].label
BIOLOGICAL AND ABIOLOGICAL NITROGEN-FIXATION BY MOLYBDENUM-BOUND N2-4FE-4S CLUSTER SYSTEMS

# publications[].label
MONONUCLEAR ANIONIC FORMYL COMPLEXES - SYNTHESIS AND PROPERTIES

# publications[].label
Tails and steeds versus heads and beads - The case for fluorous phase methodology in combinatorial and parallel syntheses

# publications[].label
Bifunctional Werner complexes in enantioselective hydrogen bond mediating catalysis

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM N-PYRROLYL COMPLEXES [(ETA(5)-C5H5)RE(NO)(PPH(3))(NCR=CR'CH=CH)] - REGIOCHEMISTRY OF ELECTROPHILIC ADDITION AND UNPRECEDENTED REARRANGEMENTS TO CARBON-LIGATED SPECIES

# publications[].label
Syntheses and structures of missing links among polybromocyclopentadienyl rhenium and manganese tricarbonyl complexes

# publications[].label
Synthesis, structure, and reactivity of sp carbon chains with bis(phosphine) pentafluorophenylplatinum endgroups: butadiynediyl (C4) through hexadecaoctaynediyl (C16) bridges, and beyond.

# publications[].label
STATE-OF-THE-ART SYMPOSIUM ON CATALYSIS AND ORGANOMETALLIC CHEMISTRY - INTRODUCTION

# publications[].label
Lipophilic chiral cobalt (III) complexes of hexaamine ligands: Efficacies as enantioselective hydrogen bond donor catalysts

# publications[].label
Phase transfer activation of catalysts for olefin metathesis

# publications[].label
SYNTHESIS, STRUCTURE AND REACTIVITY OF RHENIUM HETEROARENE, AMINE AND AMIDE COMPLEXES

# publications[].label
New forms of coordinated carbon: Wirelike cumulenic C-3 and C-5 sp carbon chains that span two different transition metals and mediate charge transfer

# publications[].label
A Search for / Equilibria in Chiral Rhenium Imine Complexes of the Formula [(5-C5H5)Re(NO)(PPh 3)(N(H)=C(CF3)X)]+TfO-: Investigation of Electronic Effects upon the Binding Mode

# publications[].label
Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)(m)CH=CH2)(3)

# publications[].label
Introduction to the Review by Wright, Turrell, and Pickett in This Issue of Organometallics, and a Tip-of-the-Hat to Arnold (Arnie) Rheingold

# publications[].label
sp carbon chains surrounded by sp(3) carbon double helices: directed syntheses of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages via alkene metathesis.

# publications[].label
DEPROTONATION AND ANIONIC REARRANGEMENTS OF ORGANOMETALLIC COMPOUNDS .1. REACTIONS OF CYCLOPENTADIENYLRHENIUM ACYL AND ALKYL COMPLEXES WITH STRONG BASES

# publications[].label
Strategies for the Recovery of Fluorous Catalysts and Reagents: Design and Evaluation

# publications[].label
Gyroscope-like molecules consisting of PdX/PtX rotators within three-spoke dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties.

# publications[].label
MULTIFOLD RING-CLOSING OLEFIN METATHESES IN SYNTHESES OF ORGANOMETALLIC MOLECULES WITH UNUSUAL CONNECTIVITIES

# publications[].label
How to insulate a reactive site from a perfluoroalkyl group: photoelectron spectroscopy, calorimetric, and computational studies of long-range electronic effects in fluorous phosphines P((CH(2))(m)(CF(2))(7)CF(3))(3).

# publications[].label
Award-Winning Organometallic Chemistry and the Adolf-von-Baeyer-Denkmunze of the GDCh

# publications[].label
New C-1-Symmetric Ph2C-Bridged Multisubstituted ansa-Zirconocenes for Highly Isospecific Propylene Polymerization: Synthetic Approach via Activated Fulvenes

# publications[].label
Award-Winning Organometallic Chemistry: The 2011 Blaise Pascal Medal of the European Academy of Sciences

# publications[].label
Consanguineous families of coordinated carbon: A ReC4Re assembly that is isolable in three oxidation states, including crystallographically characterized ReC CC CRe and Re-+=C=C=C=C=Re+ adducts and a radical cation in which charge is delocalized between rhenium termini

# publications[].label
Award-Winning Organometallic Chemistry: The 2012 ACS Award in Organometallic Chemistry

# publications[].label
ONE-FLASK PREPARATION OF ANALYTICALLY PURE K2FE(CO)4

# publications[].label
Molecular cage synthesis and substitution chemistry of rhodium based molecular gyroscopes

# publications[].label
SYNTHESES AND STRUCTURES OF SIGMA-PYRIDINE, QUINOLINE, AND ISOQUINOLINE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(NCXHY)]+CF3SO3-

# publications[].label
SYNTHESIS AND REACTIVITY OF STABLE METALLACYCLIC MANGANESE AND RHENIUM ALPHA-HYDROXYALKYL COMPLEXES OF THE FORMULA (CO)4MP(C6H5)2(ORTHO-C6H4CHOH)

# publications[].label
Phase-Transfer Activation of Transition Metal Catalysts.

# publications[].label
Synthesis, structure, and reactivity of polymetallic C3OMe complexes of the formula (eta(5)-C5Me5)Re(NO)(PPh3)(C equivalent to CC(OMe)=)M-m(CO)(n) (M/m/n=Re/2/9, Os/3/11): A new form of coordinated carbon in which a C-3 chain links two metals and spans a third

# publications[].label
Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]C]mPtX segments; iterative syntheses and functionalization for measurements of single molecule properties.

# publications[].label
Award-Winning Organometallic Chemistry: The Centennial Sacconi Medal

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM CYCLOALKENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(CH = CH(CH2)N-2)]+BF4- - FACILE VINYLIC DEPROTONATION OF A COORDINATED ALKENE

# publications[].label
Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out.

# publications[].label
Syntheses, Structures, and Thermal Properties of Gyroscope-like Complexes Consisting of PtCl2 Rotators Encased in Macrocyclic Dibridgehead Diphosphines P((CH2)(n))(3)P with Extended Methylene Chains (n=20/22/30) and Isomers Thereof

# publications[].label
Chiral Cobalt(III) Tris(1,2-diamine) Catalysts That Incorporate Nitrogenous Base Containing Anions for the Bifunctional Activation of Nucleophiles and Electrophiles in Enantioselective Addition Reactions

# publications[].label
A GENERAL-METHOD FOR THE SELECTIVE BINDING AND ACTIVATION OF ONE ALDEHYDE ENANTIOFACE - SYNTHESIS AND REACTIVITY OF RHENIUM ALDEHYDE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-2-RCH=O)]+PF6-

# publications[].label
Synthesis, structure, and oxidative additions of a fluorous analogue of Vaska's complex, trans-[IrCl(CO){P[CH2CH2(CF2)(5)CF3](3)}(2)]-altered reactivity in fluorocarbons and implications for catalysis

# publications[].label
SYNTHESIS AND STRUCTURE OF THE RHENIUM PHENYLAMIDO COMPLEX RE(ETA-5-C5H5)(NO)(PPH3)(NHPH) - AN UNPRECEDENTED PYRAMIDAL AMIDO LIGAND

# publications[].label
Award Winning Organometallic Chemistry: The 2010 Balandin Prize of the Russian Academy of Sciences

# publications[].label
HIGHLY STEREOSELECTIVE K-SELECTRIDE REDUCTION OF METHYL KETONES VIA THE CHIRAL RHENIUM TEMPLATE [(ETA-5-C5H5)RE(NO)(PPH3)]+BF4-

# publications[].label
Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope-like Iron Carbonyl Complexes Based on Dibridgehead Diarsine Cages

# publications[].label
A Metal-Capped Conjugated Polyyne Threaded through a Phenanthroline-Based Macrocycle. Probing beyond the Mechanical Bond to Interactions in Interlocked Molecular Architectures

# publications[].label
Fluorous Chemistry Meets Green Chemistry: A Concise Primer

# publications[].label
Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone: New cyclometalation and catalyst design strategies.

# publications[].label
A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines

# publications[].label
Award-Winning Organometallic Chemistry: The 2011 RSC Organometallic Chemistry Award (and More)

# publications[].label
Synthesis and characterization of molecular gyroscopes and cage-like diphosphines via alkene metathesis

# publications[].label
Syntheses and structures of missing links among polybromocyclopentadienyl rhenium and manganese tricarbonyl complexes

# publications[].label
CLEAVAGE OF THE RHENIUM METHYL BOND OF (ETA-C5H5)RE(NO)(PPH3)(CH3) BY PROTIC AND HALOGEN ELECTROPHILES - STEREOCHEMISTRY AT RHENIUM

# publications[].label
Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands.

# publications[].label
Werner-type complexes as chirality and prochirality sensing agents for a variety of functional groups

# publications[].label
Are teflon "ponytails" the coming fashion for catalysts?

# publications[].publisher
American Association for the Advancement of Science (AAAS)

# publications[].label
A NOVEL HETEROBIMETALLIC ASYMMETRIC HYDROGENATION CATALYST BASED UPON A CHIRAL RHENIUM TEMPLATE CONTAINING 2 PHOSPHIDO SUBSTITUENTS

# publications[].label
Syntheses and Structures of Digold Complexes of Macrobicyclic Dibridgehead Diphosphines That Can Turn Themselves Inside Out

# publications[].label
Transition metal catalysis in fluorous media: Practical application of a new immobilization principle to rhodium-catalyzed hydroborations of alkenes and alkynes

# publications[].label
Molecular gyroscopes based on osmium and platinum, their reduction chemistry, and cage-like diphosphines.

# publications[].label
Structures and unexpected dynamic properties of phosphine oxides adsorbed on silica surfaces.

# publications[].label
New carbon-rich ligands anchored by the chiral rhenium fragment [(eta(5)-C5Me5)Re(NO)(PPh3)](+).

# publications[].label
SYNTHESES AND REACTIONS OF CHIRAL RHENIUM VINYLIDENE AND ACETYLIDE COMPLEXES OF THE FORMULAS [(ETA-5-C5H5)RE(NO)(PPH3)(=C=CRR')]+X- AND (ETA-5-C5H5)RE(NO)(PPH3)(C=CR)

# publications[].label
Highly Active Families of Catalysts for the Ring-Opening Polymerization of Lactide: Metal Templated Organic Hydrogen Bond Donors Derived from 2-Guanidinobenzimidazole

# publications[].label
Phase Transfer Activation of Fluorous Analogs of Grubbs' Second-Generation Catalyst: Ring-Opening Metathesis Polymerization

# publications[].label
New types of container molecules that can transport MCl2 fragments

# publications[].label
A NEW ASYMMETRIC-SYNTHESIS OF CYANOHYDRINS AND OXYGEN-FUNCTIONALIZED DERIVATIVES - STEREOSELECTIVE ADDITION OF CYANIDE TO CHIRAL RHENIUM ALDEHYDE AND KETONE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(O=CRR')]+BF4-

# publications[].label
Square-Planar Palladium Complexes with Trans Di- and Tribenzylphosphine Ligands Bearing O(CH2)(4)CH=CH2 Substituents; Two- and Three-Fold Intramolecular Ring-Closing Metatheses

# publications[].label
Sp Carbon chains surrounded by sp(3) carbon double helices: wire-like Pt(C C)(n)Pt moieties that are spanned by two alpha,omega-diphosphines that bear heteroatoms or alkyl substituents

# publications[].label
Rendering classical hydrophilic enantiopure Werner salts [M(en)3]n+nX- lipophilic (M/n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge.

# publications[].label
Syntheses of Enantiopure 1,2-Ethylenediamines with Tethered Secondary Amines of the Formula H2NCH2CH[(CH2)(n)NHMe]NH2(n=1-4) from alpha-Amino Acids: New Agents for Asymmetric Catalysis

# publications[].label
Associate Editors Past and Present: A Warm Welcome to Professor Daniel J. Mindiola, and Heartfelt Thanks to Professor Tobin J. Marks

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM AMIDO COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(NRR')

# publications[].label
Award-Winning Organometallic Chemistry: The 2013 Robert Robinson Award of the RSC

# publications[].label
SYNTHESIS AND REACTIVITY OF CHIRAL RHENIUM ALCOHOL COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(ROH)]+BF4(-)

# publications[].label
Highly selective detection of silver in the low ppt range with ion-selective electrodes based on ionophore-doped fluorous membranes.

# publications[].label
Olefin metatheses in metal coordination spheres: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

# publications[].label
ORGANOMETALLIC SULFONIUM SALTS AND RELATED SULFUR DERIVATIVES OF THE (ETA-C5H5)RE(NO)(PPH3)(=CH2)+ SYSTEM

# publications[].label
SYNTHESIS AND REACTIVITY OF FUNCTIONALIZED RHENIUM GERMYL COMPLEXES (ETA5-C5H5)RE(NO)(PPH3)(GEPH2X) - DYNAMIC EQUILIBRIA WITH GERMYLENE COMPLEX [(ETA5-C5H5)RE(NO)(PPH3)(=GEPH2)]+X-

# publications[].label
Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp(3) carbon chains

# publications[].label
Fluorous membrane ion-selective electrodes for perfluorinated surfactants: trace-level detection and in situ monitoring of adsorption.

# publications[].label
A NEW SYNTHESIS OF COMPOUNDS WITH CHIRAL METHYL-GROUPS - STEREOCHEMISTRY OF METAL-CARBON BOND-CLEAVAGE IN CHIRAL (ETA-5-C5H5)RE(NO)(PPH3)(R) COMPLEXES

# publications[].label
REACTIONS OF RHENIUM CYCLOPENTADIENYL AND INDENYL DICHLOROMETHANE COMPLEXES OF THE FORMULA [(ETA(5)-CXHY)RE(NO)(PPH3)(CLCH2CL)]+BF4- WITH KETONES - SUBSTITUTION RATES AND MECHANISM

# publications[].label
Three-Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH2) mCHCH2)3 (X = -, m = 5-10; X = O, m = 3-5): Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes.

# publications[].label
Theoretical study on the spin-state energy splittings and local spin in cationic [Re]-Cn-[Re] complexes.

# publications[].label
Crystal structure and computational investigation of an analogue of Grubbs' second generation catalyst with a fluorous phosphine.

# publications[].label
Vibrational progressions in the valence ionizations of transition metal hydrides: evaluation of metal-hydride bonding and vibrations in (eta(5)-C(5)R(5))Re(NO)(CO)H [R = H, CH(3)].

# publications[].label
A CRYSTALLOGRAPHIC MAP OF CHIRAL RECOGNITION IN PI-COMPLEXES OF AROMATIC-ALDEHYDES AND A CHIRAL TRANSITION-METAL LEWIS-ACID - ENANTIOFACE BINDING SELECTIVITIES IN SOLUTION CORRELATE TO DISTANCES BETWEEN METAL AND CARBON STEREOCENTERS IN THE SOLID-STATE

# publications[].label
Synthesis, structure, and reactivity of bridging cyanide complexes of the formula [(eta(5)-C5R5)Re(NO)(PPh3)CN(Ph3P)(ON)Re(eta(5)-C5R'5)]+TfO- (R, R'=H, Me)

# publications[].label
Insulation of metal-capped polyyne chains via the formation of rotaxanes

# publications[].label
REACTIONS OF METAL-CARBONYL ACYLS WITH CARBON AND HYDRIDE NUCLEOPHILES

# publications[].label
Syntheses and Palladium, Platinum, and Borane Adducts of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)(m)CH=CH2)(3)

# publications[].label
Crystal structure of an unusual bis(fluorous phosphine) ruthenium(III) complex derived from a fluorous Grubbs' catalyst

# publications[].label
Gyroscopes and the chemical literature: 1852-2002

# publications[].label
Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis.

# publications[].label
Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes

# publications[].label
SYNTHESIS AND PROPERTIES OF CHIRAL RHENIUM ETHER COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(OR2)]+X-

# publications[].label
PREPARATION AND PROPERTIES OF (ETA-C5H5)2ZRCL[SI(CH3)3] AND (ETA-C5H5)2ZR[SI(CH3)3]2 - TRIMETHYLSILYL GROUP TRANSFER FROM MERCURY TO ZIRCONIUM

# publications[].label
THIONE COMPLEXES OF GROUP VIB PENTACARBONYLS

# publications[].label
Werner complexes: A new class of chiral hydrogen bond donor catalysts for enantioselective organic reactions

# publications[].label
SYNTHESIS AND REACTIVITY OF BIMETALLIC BRIDGING HALOALKYL COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)X(CH2)XM(CO)5]+BF4-(X = I, BR, CL - M = RE, MN - X = 1, 4)

# publications[].label
A RATIONAL SYNTHESIS OF A STABLE ALPHA-HYDROXYALKYL COMPLEX

# publications[].label
Molecular polygons incorporating sp-hybridized carbon chains: Synthesis and characterization

# publications[].label
DEOXYGENATION AND DESULFURIZATION OF ORGANIC-COMPOUNDS VIA TRANSITION-METAL ATOM COCONDENSATION

# publications[].label
REDUCTION, ISOMERIZATION, AND COMPLEXATION OF ORGANIC-MOLECULES BY TRANSITION-METAL ATOMS

# publications[].label
sp Carbon Chains Surrounded by sp3 Carbon Double Helices: A Class of Molecules that are Accessible by Self-Assembly and Models for Insulated Molecular-Scale Devices We thank the Deutsche Forschungsgemeinschaft (SFB 583), Johnson Matthey PMC (platinum loan), the Spanish Ministerio de Educacin y Ciencia, and the Fulbright Commission (Fellowships, J.M.M.-A.) for support, and Dr. A. M. Arif for assistance with the analysis of one crystal structure.

# publications[].label
New hydrogen bonding motifs of phosphine oxides with a silanediol, a phenol, and chloroform

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF N-INDOLYL COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+ - DIASTEREOSELECTIVE ELECTROPHILIC ADDITIONS

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF ETA-2-1,3-DIENE AND ENYNE COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+ - OZONOLYSIS WITHIN A METAL COORDINATION SPHERE

# publications[].label
Computational simulation of homeomorphic isomerism in phosphine macrobicycles: Topology, spectroscopy, and stability of in/out isomers

# publications[].label
PYRROLYL-N, PYRROLYL-C AND INDOLYL-N COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH3)]+ - SYNTHESES, ELECTROPHILIC ADDITIONS, AND REARRANGEMENT CHEMISTRY

# publications[].label
REACTIONS OF BENZALDEHYDE WITH TRIALKYLSILYL METAL-CARBONYL COMPLEXES

# publications[].label
NEW PERSPECTIVES IN COORDINATION CHEMISTRY - INTRODUCTION

# publications[].label
Molecules that Turn Themselves Inside-Out: Tuning in/out Equilibria and Homeomorphic Isomerization in Macrobicyclic Dibridgehead Diphosphines P((CH2 )n )3 P Newly Accessible by Earth-Abundant-Metal Templates.

# publications[].label
Dibridgehead diphosphines that turn themselves inside out.

# publications[].label
Fluorocarbon anchored transition metal catalysts: Applications in hydrogenation, hydrosilylation, and hydroboration.

# publications[].label
Monophosphine and diphosphine ligands for diplatinum polyynediyl complexes: Efficient syntheses of new functionality-containing systems and model compounds

# publications[].label
SI-29 NMR-SPECTRA OF METAL-CARBONYL SILANES BY THE SELECTIVE POPULATION TRANSFER METHOD

# publications[].label
Preparing perfluoroalkyl substituted arenes via the Heck reaction

# publications[].label
A Search for pi/sigma Equilibria in Chiral Rhenium Imine Complexes of the Formula [(eta(5)-C(5)H(5))Re(NO)(PPh(3))(N(H)=C(CF(3))X)](+)TfO(-): Investigation of Electronic Effects upon the Binding Mode.

# publications[].label
Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, alpha,omega-Dibromides, and Resorcinol or 2,7-Dihydroxynaphthalene

# publications[].label
NUCLEOPHILIC ADDITIONS TO THE CHIRAL RHENIUM ALKENE COMPLEXES [RE(ETA(5)-C5H5)(NO)(PPH(3))(H2C=CHR)]BF4 (R=H, ME, CH(2)CH(2)ME, PH OR CH(2)PH) - REGIO-SELECTIVITIES, DEASTEREO-SELECTIVITIES AND ENANTIO-SELECTIVITIES

# publications[].label
A step-growth approach to metal-capped one-dimensional carbon allotropes: Syntheses of C-12, C-16, and C-20 mu-polyynediyl complexes

# publications[].label
Syntheses of Enantiopure Bifunctional 2-Guanidinobenzimidazole Cyclopentadienyl Ruthenium Complexes: Highly Enantioselective Organometallic Hydrogen Bond Donor Catalysts for Carbon-Carbon Bond Forming Reactions

# publications[].label
New media for classical coordination chemistry: phase transfer of Werner and related polycations into highly nonpolar fluorous solvents.

# publications[].label
SYNTHESES OF KINETICALLY UNSTABLE NEUTRAL FORMYL COMPLEXES VIA LI(C2H5)3BH AND TRANSFORMYLATION REACTIONS OF METAL-CARBONYL CATIONS

# publications[].label
Fluorous chemistry meets green chemistry: A concise primer an overview from an authority on recoverable and recyclable catalysts and organometallic chemistry

# publications[].label
Syntheses and properties of fluorous quaternary phosphonium salts that bear four ponytails; New candidates for phase transfer catalysts and ionic liquids

# publications[].label
Novel insights into the mechanism of methane carbonylation in superacids using high-pressure NMR spectroscopy.

# publications[].label
Partially Shielded Fe(CO)(3) Rotors: Syntheses, Structures, and Dynamic Properties of Complexes with Doubly trans Spanning Diphosphines, trans-($)over-barFe(CO)(3)(PhP((CH2)(n))(2)PPh)

# publications[].label
A Nontemplated Route to Macrocyclic Dibridgehead Diphosphorus Compounds: Crystallographic Characterization of a "Crossed-Chain" Variant of in/out Stereoisomers.

# publications[].label
A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of Chiral-at-Rhenium Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations

# publications[].label
Molecular wires in single-molecule junctions: charge transport and vibrational excitations.

# publications[].label
Synthesis and crystal structure of the conjugated tetrayne (eta(5)-C5Me5)Re(NO)(PPh3)(C CC CC CC CSiMe3): application of the Cadiot-Chodkiewicz coupling reaction to the chain extension of metal-capped sp-carbon wires

# publications[].label
Carbon in one dimension: structural analysis of the higher conjugated polyynes.

# publications[].label
HYDRIDE TRANSFER-REACTIONS OF ANIONIC METAL FORMYL COMPLEXES - MECHANISTIC TEST

# publications[].label
Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts Derived from Trications of the Formula [Co(NH2CHArCHArNH2)3]3.

# publications[].label
5,6-DEHYDRO[3.3]PARACYCLOPHANE - BRIDGED BENZOBARRELENE FORMATION BY INTRAMOLECULAR TRAPPING OF A NOVEL ARYNE

# publications[].label
A NEW CARBON HYDROGEN-BOND ACTIVATION REACTION - STEREOSPECIFIC ABSTRACTION OF VINYLIC PROTONS FROM RHENIUM ALKENE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+BF4-BY THE BASE TERT-BUO-K+

# publications[].label
A GENERAL-CLASS OF STABLE ALKYL HALIDE-COMPLEXES - SYNTHESIS, STRUCTURE, AND REACTIVITY OF ALKYL IODIDE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(IR)]+BF4-

# publications[].label
Sp carbon chains surrounded by sp3 carbon double helices: a class of molecules that are accessible by self-assembly and models for "insulated" molecular-scale devices.

# publications[].label
Gyroscope-like molecules consisting of PdX2/PtX2 rotators encased in three-spoke stators: synthesis via alkene metathesis, and facile substitution and demetalation.

# publications[].label
New applications of the olefin metathesis reaction in transition metal coordination spheres: Generation of novel polymacrocyclic complexes.

# publications[].label
Award-Winning Organometallic Chemistry: The 2012 RSC Sir Geoffrey Wilkinson Award

# publications[].label
Syntheses and reactions of phosphines and metal phosphine complexes with (CH2)(x)(CF2)(y)CF3 "pony tails": Tuning electronic properties and fluorous phase affinities.

# publications[].label
Convenient syntheses of a family of easily recoverable fluorous primary, secondary, and tertiary aliphatic amines NH3-x[(CH2)(m)(CF2)(7)CF3](x) (m=3-5; x=1-3) - Fine tuning of basicities and fluorous phase affinities

# publications[].label
CRYSTAL-STRUCTURES OF DIASTEREOMERIC STYRENE COMPLEXES OF THE CHIRAL RHENIUM FRAGMENT [(ETA(5)-C5H5)RE(NO)(PPH(3))](+) - EFFECT OF LIGATING ENANTIOFACE UPON BONDING AND CONFORMATION

# publications[].label
HIGHLY SELECTIVE C=C AND C-H BOND ACTIVATION MEDIATED BY A CHIRAL TRANSITION-METAL LEWIS-ACID

# publications[].label
C<inf>8</inf> and C<inf>12</inf> sp Carbon Chains That Span Two Platinum Atoms: The First Structurally Characterized 1,3,5,7,9,11-Hexayne

# publications[].label
Synthesis of supramolecular vinyl alcohol (VA) copolymers via ring-opening metathesis polymerization (ROMP) for biogenic amine delivery

# publications[].label
Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer complexes derived from P(CH2)(5)P backbones

# publications[].label
NEW METHODS FOR METAL-CARBON BOND FORMATION - REACTIONS OF (OC)5MNSIME3 WITH CYCLIC ETHERS

# publications[].label
Fluorous chemistry without fluorous solvents: New catalyst recovery protocols based upon fluoropolymers

# publications[].label
Fluorous Grubbs metathesis catalysts: Applications in phase transfer activation

# publications[].label
ENANTIOSELECTIVE SYNTHESES OF ORGANOSULFUR COMPOUNDS VIA [2,3]-REARRANGEMENTS OF YLIDES DERIVED FROM DI(ALLYL) AND DI(PROPARGYL) SULFIDE COMPLEXES - CONTROL OF CARBON CONFIGURATION BY AN EASILY RESOLVED AND RECYCLED CHIRAL TRANSITION-METAL AUXILIARY

# publications[].label
Convenient syntheses of "heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails.

# publications[].label
Synthesis, structure, and interconversion of chiral rhenium oxygen- and sulfur-bound sulfoxide complexes of formula [(eta(5)-C5H5)Re(NO)(PPh3)(OS(Me)R)](+) X-; diastereoselective oxidations of coordinated methyl alkyl sulfides

# publications[].label
DEPROTONATION AND ANIONIC REARRANGEMENTS OF ORGANOMETALLIC COMPOUNDS .3. THE 1ST CARBON CARBON BOND-FORMING REACTION OF AN ETA-1-FORMYL LIGAND

# publications[].label
Transition metal catalysis in fluorous media: Practical application of a new immobilization principle to rhodium-catalyzed hydroboration

# publications[].label
A NEW REACTION OF COORDINATED SULFOXIDES - FACILE AND HIGHLY DIASTEREOSELECTIVE DEPROTONATION OF A CHIRAL, CATIONIC RHENIUM DMSO COMPLEX TO AN YLIDE AND SUBSEQUENT [1,2] MIGRATION OF RHENIUM FROM SULFUR TO CARBON

# publications[].label
INOR 539-Polyynediyl systems anchored by transition metals

# publications[].label
Syntheses, oxidations, and palladium complexes of fluorous dialkyl sulfides: new precursors to highly active catalysts for the Suzuki coupling

# publications[].label
sp carbon chains surrounded by sp(3) carbon double helices: coordination-driven self-assembly of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages.

# publications[].label
Selective methane carbonylation in liquid superacids: High-pressure NMR and IR spectroscopic studies.

# publications[].label
Enantioselective syntheses of organosulfur compounds via [2,3] sigmatropic rearrangements of ylides derived from di(allyl), di(propargyl), and di(benzyl) sulfide complexes; Control of carbon configuration by an easily resolved and recycled rhenium auxiliary

# publications[].label
Fluorous phase-transfer activation of catalysts: application of a new rate-enhancement strategy to alkene metathesis.

# publications[].label
Cleaning of pH Selective Electrodes with Ionophore-doped Fluorous Membranes in NaOH Solution at 90 degrees C

# publications[].label
Werner complexes: A new class of chiral hydrogen bond donor catalysts for enantioselective organic reactions

# publications[].label
Elucidating homeomorphic isomerism in macrobicycles of the pnictogen-series

# publications[].label
REACTION OF CYANOMETHYL COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(CH2CN) WITH NORMAL-BULI/TMEDA - GENERATION, STEREOSPECIFIC ALKYLATION, AND BASICITY OF A TRANSITION-METAL-SUBSTITUTED CARBANION

# publications[].label
REACTIONS OF BENZALDEHYDE WITH TRIALKYLSILYL METAL-CARBONYL COMPLEXES

# publications[].label
Building Blocks for Molecular Polygons Based on Platinum Vertices and Polyynediyl Edges

# publications[].label
CONJUGATE ADDITIONS OF ORGANOCUPRATES TO CYCLOALKENONE COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA(5)-C5H5)RE(NO)(PPH(3))](+) - ENANTIOSELECTIVE SYNTHESES OF 3-SUBSTITUTED CYCLOALKANONES

# publications[].label
Appreciably bent sp carbon chains: synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (eta(5)-C5Me5)Re(NO)(PPh3)((C C)n-p-C6H4Me)

# publications[].label
Introduction to frontiers in transition metal catalyzed reactions (and a brief adieu).

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM CARBOXYLIC AND CARBONIC-ACID ESTER COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-1-O=C(X)X')]+X''-

# publications[].label
SYNTHESIS OF METAL-CARBONYL MONO-ANIONS BY TRIALKYLBOROHYDRIDE CLEAVAGE OF METAL-CARBONYL DIMERS - CONVENIENT ONE-FLASK PREPARATION OF METAL ALKYLS, METAL ACYLS, AND MIXED-METAL COMPOUNDS

# publications[].label
Alkene metathesis in transition metal coordination spheres: The quest for molecular gyroscopes

# publications[].label
NEW CHIRAL CHELATING TRANSITION-METAL PHOSPHIDE COMPLEXES - A NOVEL BIMETALLIC ASYMMETRIC HYDROGENATION CATALYST

# publications[].label
ALKENE CHEMISTRY OF THE HIGHLY ELECTROPHILIC RHENIUM LEWIS ACID [ETA-5-C5H5)RE-(NO)(PPH3)]+ - NONDISSOCIATIVE EXCHANGE OF C=C BINDING FACES

# publications[].label
Convenient protocols for Mizoroki-Heck reactions of aromatic bromides and polybromides with fluorous alkenes of the formula H2C[double bond, length as m-dash]CH(CF2)n-1CF3 (n = 8, 10).

# publications[].label
Spectroscopic Observation of the Formyl Cation in a Condensed Phase.

# publications[].publisher
American Association for the Advancement of Science (AAAS)

# publications[].label
Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts LnPt(C C)(z)PtLn

# publications[].label
Generation of trans-spanning diphosphine ligands via alkene metathesis: Synthesis, structure, and dynamic behavior of a missing link in a series of square-planar platinum complexes

# publications[].label
Tungsten-catalyzed alkyne metatheses in transition-metal coordination spheres: Versatile new syntheses of metallamacrocycles

# publications[].label
DELOCALIZED ELECTRONIC INTERACTIONS IN CHIRAL CYCLOPENTADIENYLRHENIUM HALIDE-COMPLEXES - VALENCE PHOTOELECTRON-SPECTRA OF CPRE(NO)(L)X (CP = ETA-5-C5H5, ETA-5-C5(CH3)5 L = CO, P(C6H5)3 X = CL, BR, I)

# publications[].label
ELECTROPHILE-INDUCED DISPROPORTIONATION OF THE NEUTRAL FORMYL (ETA-C5H5)RE(PPH3)(NO)(CHO) - GENERATION OF CATIONIC RHENIUM CARBENES OF THE FORMULA "[(ETA-C5H5)RE(PPH3)(NO)(CHX)]+(X=H, OCH3, OH)

# publications[].label
SYNTHESES, CHEMICAL-PROPERTIES, AND X-RAY CRYSTAL-STRUCTURES OF RHENIUM FORMALDEHYDE AND THIOFORMALDEHYDE COMPLEXES

# publications[].label
Hydrogen bond mediated enantioselective catalysis by Werner complexes

# publications[].label
REACTIONS OF ORGANORHENIUM COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(CH2R) WITH PH3C+PF6- - ANALYSIS OF THE ENERGETICS OF ALPHA-HYDRIDE ABSTRACTION

# publications[].label
An Unexpected Role of Carbon Disulfide: A New and Efficient Method for the Synthesis of 2-Substituted Benzimidazoles

# publications[].label
A CRYSTALLOGRAPHIC MAP OF CHIRAL RECOGNITION IN PI-COMPLEXES OF AROMATIC-ALDEHYDES AND A CHIRAL TRANSITION-METAL LEWIS-ACID

# publications[].label
Fluorous environment toward catalyst recovery in phase transfer catalysis

# publications[].label
Organometallic reactivity patterns in fluorocarbons and implications for catalysis: Synthesis, structure, solubility, and oxidative additions of a fluorous analogue of Vaska's complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)(5)CF3)(3)](2)

# publications[].label
Recycling and Delivery of Homogeneous Fluorous Rhodium Catalysts Using Poly(tetrafluoroethylene): "Catalyst-on-a-Tape"

# publications[].label
Macrocyclic Complexes Derived from Four cis-L2 Pt Corners and Four Butadiynediyl Linkers; Syntheses, Electronic Structures, and Square versus Skew Rhombus Geometries.

# publications[].label
CRYSTALLOGRAPHIC AND THEORETICAL ANALYSES OF THE STRUCTURES OF RHENIUM FORMYL AND ACYL COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PR3)(COR')

# publications[].label
Fluorophilic ionophores for potentiometric pH determinations with fluorous membranes of exceptional selectivity.

# publications[].label
Synthesis and reactivity of 1,2- and 1,3-diphosphanes that contain four chiral rhenium fragments: Architecturally novel tetrametallo-DMPE and -DMPP species that are unprivileged ligands for enantioselective catalysis

# publications[].label
Hydrogen bonding motifs in structurally characterized salts of the tris (ethylenediamine) cobalt trication, [Co(en)(3)](3+); An interpretive review, including implications for catalysis

# publications[].label
NEW MECHANISTIC PROBES OF HYDRIDE ABSTRACTION FROM RHENIUM ALKYL COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(R) BY PH3C+PF6- - EVIDENCE FOR INITIAL ELECTRON-TRANSFER

# publications[].label
Gyroscopes and the Chemical Literature, 2002-2020: Approaches to a Nascent Family of Molecular Devices.

# publications[].label
Metal-metal interactions across bridging elemental carbon chains: a computational study of odd-carbon complexes

# publications[].label
Attaching metal-capped sp carbon chains to metal clusters: Synthesis, structure, and reactivity of rhenium/triosmium complexes of formula [(5-C5Me5)Re(NO)(PPh3)(CC)(n)Os3(CO)(y)(X)(Z)]m+, including carbon geometries more distorted than planar tetracoordinate

# publications[].label
Rhodium(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Syntheses, Structures, and Applications as Chiral Hydrogen Bond Donor Catalysts and Agents for Enantiomer Purity Determinations

# publications[].label
HYDROGEN-BONDING IN ORGANOMETALLIC LIGANDS AND POSSIBLE IMPLICATIONS FOR CO/H2 CHEMISTRY - 1ST CARBONYLATION OF AN ISOLABLE METAL ALPHA-HYDROXYALKYL COMPLEX

# publications[].label
SYNTHESES, PROPERTIES, AND X-RAY CRYSTAL-STRUCTURES OF STABLE METHYLIDENE COMPLEXES OF THE FORMULA [(ETA-C5ME5)RE(NO)(L)(=CH2)]+PF6-

# publications[].label
ISOMERIZATION OF DIASTEREOISOMERIC ALKENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+ - THE ALKENE ENANTIOFACE BOUND TO THE METAL CAN FLIP WITHOUT ALKENE DISSOCIATION

# publications[].label
Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity.

# publications[].label
PI/SIGMA EQUILIBRIA IN METAL-COMPLEXES OF ORGANIC CARBONYL-COMPOUNDS - SYNTHESIS AND STRUCTURE OF CHIRAL RHENIUM COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O = CHAR)]X

# publications[].label
REACTIONS OF PHOSPHORUS ELECTROPHILES WITH [(ETA-5-C5ME5)FE(CO)2] - SPECTROSCOPIC EVIDENCE FOR A PHOSPHINIDINE COMPLEX

# publications[].label
A phase based approach to insulated molecular wires: Diplatinum octatetraynediyl complexes bearing fluorous trialkylphosphine ligands

# publications[].label
Diallyl sulfide complexes of chiral iron and ruthenium Lewis acids: Ylide generation and diastereoselective [2,3] sigmatropic rearrangements to give thiolate complexes with new carbon stereocenters

# publications[].label
Syntheses and carbonyliridium complexes of unsymmetrically substituted fluorous trialkylphosphanes: Precision tuning of electronic properties, including insulation of the perfluoroalkyl groups

# publications[].label
Monophasic and biphasic hydrosilylations of enones and ketones using a fluorous rhodium catalyst that is easily recycled under fluorous-organic liquid-liquid biphasic conditions

# publications[].label
SIMPLIFIED IN SITU SYNTHESES OF ANHYDROUS HMN(CO)5

# publications[].label
THE ROLE OF VIRTUAL HALOGEN D ORBITALS IN THE STABILITY AND REACTIVITY OF RHENIUM ALKYL HALIDE-COMPLEXES OF THE FORM [(ETA-5-C5H5)RE(NO)(PPH3)(XR)]+

# publications[].label
Chiral Recognition in  Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities

# publications[].label
pi complexes of fluorous alkynes, cyclobutadienes, and benzenes: Syntheses and phase properties of cobalt and chromium tricarbonyl adducts

# publications[].label
ELECTROCHEMICAL OXIDATION OF RHENIUM ALKYL COMPLEXES OF THE FORMULA (ETA-5-C5H5)RE(NO)(PPH3)(R) - EVIDENCE FOR ONE-ELECTRON CHARGE-TRANSFER

# publications[].label
Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)(2)(I) Rotators and Cage-like Trans Aliphatic Dibridgehead Diphosphine Stators

# publications[].label
OPTICAL-ROTATION MEASUREMENTS OF ORGANOMETALLIC COMPOUNDS - CAVEATS AND RECOMMENDED PROCEDURES

# publications[].label
Syntheses and reactivities of disubstituted and trisubstituted fluorous pyridines with high fluorous phase affinities: solid state, liquid crystal, and ionic liquid-phase properties.

# publications[].label
Photophysics of platinum tetrayne oligomers: delocalization of triplet exciton.

# publications[].label
Photophysics of diplatinum polyynediyl oligomers: chain length dependence of the triplet state in sp carbon chains.

# publications[].label
An Air- and Water-Stable Hydrogen-Bond-Donor Catalyst for the Enantioselective Generation of Quaternary Carbon Stereocenters by Additions of Substituted Cyanoacetate Esters to Acetylenic Esters.

# publications[].label
Syntheses, structures, and catalytic reactions of palladium adducts of chiral diphosphines that contain a rhenium stereocenter in the backbone

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM ALKENE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+X-

# publications[].label
New approaches to high-activity transition-metal catalysts for carbon-carbon bond forming reactions. Rhenium-containing phosphorus donor ligands for palladium-catalyzed Suzuki cross-couplings.

# publications[].label
METAL-COMPLEXES OF SULFUR-CONTAINING LIGANDS - SYNTHESIS AND PROPERTIES OF A SERIES OF RHENIUM-SUBSTITUTED SULFONIUM SALTS [(ETA-5-C5H5)RE(NO)(PPH3)(CH2-)]NS+(CH3)3-N(N=1-3)

# publications[].label
Olefin metatheses in metal coordination spheres: Versatile new strategies for the construction of novel monohapto or polyhapto cyclic, macrocyclic, polymacrocyclic, and bridging ligands

# publications[].label
Syntheses of dimetallamacrocycles by intramolecular oxidative couplings of dinuclear bis(1,3-butadiynyl) complexes: A new approach to steric shielding in (sp-carbon chain)dirhenium complexes [(eta(5)-C5Me5)Re(NO)(PR3)(C CC CC CC C)(R3P)(ON)Re(eta(5)-C5Me5)]

# publications[].label
Syntheses, structures, and electronic and photophysical properties of unsymmetrically substituted butadiynediyl and hexatriynediyl complexes derived from (C6F5)(R3P)(2)Pt, (p-tol)(R3P)(2)Pt, and (Ph3P)Au end-groups

# publications[].label
A new family of chelating diphosphines with a transition metal stereocenter in the backbone: novel applications of "chiral-at-rhenium" complexes in rhodium-catalyzed enantioselective alkene hydrogenations.

# publications[].label
NEW STRATEGIES FOR ENANTIOSELECTIVE SYNTHESES OF 1-ALKYL-1,2,3,4-TETRAHYDROISOQUINOLINES AND 1,4-DIALKYL-1,2,3,4-TETRAHYDROISOQUINOLINES - DIASTEREOSELECTIVE ADDITIONS OF NUCLEOPHILES AND ELECTROPHILES TO ISOQUINOLINE MEDIATED BY AN EASILY RESOLVED AND RECYCLED CHIRAL TRANSITION-METAL AUXILIARY

# publications[].label
MECHANISM OF EQUILIBRATION OF DIASTEREOMERIC CHIRAL RHENIUM ALKENE COMPLEXES[(ETA-5-C5H5)RE(NO)-(PPH3)(H2C=CHR)]+BF4- - THE METAL TRAVERSES BETWEEN ALKENE ENANTIOFACES WITHOUT DISSOCIATION

# publications[].label
SELECTIVE BINDING OF ONE ENANTIOFACE OF MONOSUBSTITUTED ALKENES TO THE CHIRAL TRANSITION-METAL LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
Chemistry in fluorous media: a user's guide to practical considerations in the application of fluorous catalysts and reagents

# publications[].label
How do the electronic structures of low-symmetry metal-hydride and -alkyl complexes compare? Photoelectron spectroscopy and computational studies of (eta(5)-C5R5)Re(NO)(L)R ' (L = CO, P(C6H5)(3); R, R ' = H, CH3)

# publications[].label
SYNTHESIS AND REACTIVITY OF METALLACYCLIC MANGANESE ALPHA-(SILYLOXY)ALKYL COMPLEXES (CO)4MNC(R)(OSI(CH3)3)P(C6H5)2 - A NEW THERMODYNAMIC DRIVING FORCE FOR CO INSERTION

# publications[].label
Electronic structure and chain-length effects in diplatinum polyynediyl complexes trans,trans-[(X)(R3P)2Pt(C triple bond C)(n)Pt(PR3)2(X)]: a computational investigation.

# publications[].label
TRANSITION-METAL FORMYL COMPLEXES - SYNTHESIS BY TRIALKYLBOROHYDRIDE ATTACK UPON METAL-CARBONYL ACYLS AND METAL-CARBONYL DIMERS

# publications[].label
INTRODUCTION OF SULFUR INTO ORGANIC-MOLECULES VIA LITHIUM TRIETHYLBOROHYDRIDE REDUCTION OF S-8

# publications[].label
Surface reactivity studies of bimetallic complexes, (eta(5)-C5Me5)Re(NO)(PPh3)(C equivalent to C)(n)(Ph3P)(ON)Re(eta(5)-C5Me5) (n=2,4,6): candidates for molecular wires

# publications[].label
Fluorous Chemistry: Scope and Definition

# publications[].label
An Analogue of Grubbs Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis

# publications[].label
TOWARDS ONE-DIMENSIONAL CARBON WIRES CONNECTING SINGLE METAL CENTERS - A CUMULENIC C-5 CHAIN THAT MEDIATES CHARGE-TRANSFER BETWEEN RHENIUM AND MANGANESE TERMINI

# publications[].label
Synthesis, reactivity, structures, and dynamic properties of gyroscope like iron complexes with dibridgehead diphosphine cages: pre- vs. post-metathesis substitutions as routes to adducts with neutral dipolar Fe(CO)(NO)(X) rotors.

# publications[].label
Award-Winning Organometallic Chemistry: The 2013 Yao Zeng Award in Organometallic Chemistry

# publications[].label
Potentiometric Selectivities of Ionophore-Doped Ion-Selective Membranes: Concurrent Presence of Primary Ion or Interfering Ion Complexes of Multiple Stoichiometries.

# publications[].label
Platinum(II) alkyl complexes of chelating dibridgehead diphosphines P((CH2)n)3P (n = 14, 18, 22); facile cis/trans isomerizations interconverting gyroscope and parachute like adducts.

# publications[].label
NEW FORMS OF LIGATING CARBON DERIVED FROM THE RHENIUM LITHIUM C2 SPECIES (ETA-5-C5ME5)RE(NO)(PPH3)(CCLI)

# publications[].label
STEREOSELECTIVE ADDITION OF CYANIDE ION TO CHIRAL RHENIUM PI-ALDEHYDE COMPLEXES OF THE FORMULAS [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-2-O=CHR)]+BF4- - A NEW SYNTHESIS OF OPTICALLY-ACTIVE CYANOHYDRIN DERIVATIVES

# publications[].label
Molecular gyroscopes: [Fe(CO)(3)] and [Fe(CO)(2)(NO)](+) rotators encased in three-spoke stators; facile assembly by alkene metatheses.

# publications[].label
Synthesis and Structure of -Complexes of the Chiral Rhenium Lewis Acid [(5-C5H5)Re(NO)(PPh3)]+ and Aromatic Nitrogen Heterocycles

# publications[].label
A new supramolecular bonding motif involving NH bonds of ammonium salts and macrocycles derived from platinum corners and butadiynediyl linkers.

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF CHIRAL RHENIUM AMINE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(NRR'R'')]+TFO-

# publications[].label
A promising new catalyst family for enantioselective cycloadditions involving allenes and imines: chiral phosphines with transition metal-CH2-P: linkages

# publications[].label
SYNTHESIS, STRUCTURE, AND REDOX CHEMISTRY OF HETEROPOLYMETALLIC CARBON COMPLEXES WITH MC(2)M', MC(4)M', AND MC(4)M'C(4)M LINKAGES - TRANSMETALATIONS OF LITHIOCARBON COMPLEXES (ETA(5)-C(5)ME(5))RE(NO)(PPH(3))(C-CLI) AND (ETA(5)-C(5)ME(5))RE(NO)(PPH(3))(C-CC-CLI)

# publications[].label
Liquid/solid phase transfer activation of Grubbs-type alkene metathesis catalysts; application of silver salts of sulfonated polystyrene

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF CHIRAL RHENIUM SIGMA-KETONE COMPLEXES - BINDING-PROPERTIES OF SYMMETRICAL KETONES AND ALKYLCYCLOHEXANONES

# publications[].label
Transition metal catalysis in fluorous media: extension of a new immobilization principle to biphasic and monophasic rhodium-catalyzed hydrosilylations of ketones and enones

# publications[].label
SYNTHESIS AND REACTIVITY OF FUNCTIONALIZED RHENIUM PHOSPHIDO COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(PXX') - AN UNUSUAL CCL4 1,3-ADDITION LEADING TO AN EXO-SUBSTITUTED ETA-4-CYCLOPENTADIENE COMPLEX

# publications[].label
New perfluorocarbon system for multilayer growth of anchorage-dependent mammalian cells.

# publications[].label
REACTIONS OF RHENIUM HALIDE-COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(X) AND ORGANOCOPPER NUCLEOPHILES - NEW ROUTES TO RACEMIC AND OPTICALLY-ACTIVE HYDROCARBYL COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(R)

# publications[].label
Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts.

# publications[].label
Mono- and disubstitution reactions of gyroscope like complexes derived from Cl-Pt-Cl rotators within cage like dibridgehead diphosphine ligands

# publications[].label
PREPARATION OF OPTICALLY-ACTIVE CYANOHYDRIN DERIVATIVES VIA THE CHIRAL RHENIUM TEMPLATE [(ETA-5-C5H5)RE(NO)(PPH3)]+BF4-

# publications[].label
Coordination-driven self-assembly, structures, and dynamic properties of diplatinum hexatriynediyl and butadiynediyl complexes in which the sp carbon chains are shielded by sp3 carbon chains: towards endgroup-endgroup interactions.

# publications[].label
Longitudinally extended molecular wires based upon PtC equivalent to CC equivalent to CC equivalent to CC equivalent to C repeat units: Iterative syntheses of functionalized linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt assemblies

# publications[].label
Wire-like PtC[triple bond]CC[triple bond]CC[triple bond]CC[triple bond]CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P linkages.

# publications[].label
NEW METHODOLOGY FOR THE INTRODUCTION OF SULFUR INTO ORGANIC-MOLECULES - SYNTHESIS OF ANHYDROUS LI2S, LI2S2 AND LISR SPECIES BY LITHIUM TRIETHYLBOROHYDRIDE REDUCTION OF ELEMENTAL SULFUR AND DISULFIDES

# publications[].label
Structurally novel palladacycle and Lewis base catalysts containing the chiral rhenium fragment CPRE(NO)(PPH3).

# publications[].label
FLUO 9-Fluorocarbon microenvironments and phases for catalyst activation and recovery

# publications[].label
EXTENDED ELECTRONIC INTERACTIONS IN CPRE(NO)(CO)R COMPLEXES - VIBRATIONAL ANALYSIS OF RE-H BOND IONIZATIONS AND COMPARISON WITH RE-CH3 BOND IONIZATIONS

# publications[].label
Chiral Tricationic Tris(1,2-diphenylethylenediamine) Cobalt(III) Hydrogen Bond Donor Catalysts with Defined Carbon/Metal Configurations; Matched/Mismatched Effects upon Enantioselectivities with Enantiomeric Chiral Counter Anions

# publications[].label
Olefin metatheses in metal coordination spheres: A new strategy for cyclic and macrocyclic organometallic compounds

# publications[].label
Award-Winning Organometallic Chemistry: The 2012 "Prix de l'Etat" and "Medaille Berthelot" of the French Academy of Sciences

# publications[].label
Rotaxanes Derived from Dimetallic Polyynediyl Complexes: Extended Axles and Expanded Macrocycles

# publications[].label
Additions of carbon nucleophiles to acyclic imine complexes of the chiral rhenium Lewis acid [(eta(5)-C5H5)Re(NO)(PPh3)](+): controlling factors in 1,3-asymmetric induction and syntheses of non-racemic organic amines

# publications[].label
SYNTHESIS, STRUCTURE AND REACTIVITY OF CHIRAL METAL IMINE COMPLEXES DERIVED FROM THE RHENIUM FRAGMENT [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
SYNTHESIS, STRUCTURE, AND ALKYLATION OF CHIRAL VINYLRHENIUM COMPLEXES (ETA-5-C5H5)RE(NO)(PPH3)(CX=CHR) (X = H, OCH3) - A MECHANISTIC STUDY OF 1,3-ASYMMETRIC INDUCTION FROM RHENIUM TO CARBON

# publications[].label
A NEW ORGANO-METALLIC PHOTOREACTION - INTERCONVERSION OF METAL-ALKYLIDENE GEOMETRIC ISOMERS

# publications[].label
REACTIONS OF METAL ATOMS WITH ORGANO-CYCLOPROPANES - IRON ATOM TEMPLATED FERROCENEOPHANE SYNTHESIS

# publications[].label
SYNTHESIS, STRUCTURE, AND DYNAMIC BEHAVIOR OF RHENIUM SULFIDE AND SULFOXIDE COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(L)(XRR')]+X'- (X = S, SO)

# publications[].label
SYNTHESIS AND REACTIVITY OF BRIDGING BIS(ALKYL) AND BIS(ALKYLIDENE) COMPLEXES DERIVED FROM THE CHIRAL RHENIUM FRAGMENT [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
ENANTIOSELECTIVE SYNTHESES OF ORGANOSULFUR COMPOUNDS VIA [2,3] SIGMATROPIC REARRANGEMENTS OF YLIDES OF DI(ALLYL) AND DI(PROPARGYL) SULFONIUM SALTS - CONTROL OF CARBON CONFIGURATION BY AN EASILY RESOLVED AND RECYCLED CHIRAL TRANSITION-METAL AUXILIARY

# publications[].label
A new family of chelating diphosphines with transition-metal and carbon stereocenters in the backbone: A second-generation rhenium-containing system

# publications[].label
Highly active thermomorphic fluorous palladacycle catalyst precursors for the Heck reaction; evidence for a palladium nanoparticle pathway.

# publications[].label
Synthesis, crystal structure, and reactions of the 17-valence-electron rhenium methyl complex [(5-C5Me5)Re(NO)(P(4-C6H 4CH3)3)(CH3)]+ B(3,5-C6H3(CF3)2)-4

# publications[].label
Correction to Fluorophilic Ionophores for Potentiometric pH Determinations with Fluorous Membranes of Exceptional Selectivity.

# publications[].label
DEPROTONATION AND ANIONIC REARRANGEMENTS OF ORGANOMETALLIC COMPOUNDS .5. KINETIC VS THERMODYNAMIC DEPROTONATION IN REACTIONS OF CYCLOPENTADIENYLRHENIUM ACYL AND ALKYL COMPLEXES WITH STRONG BASES

# publications[].label
ANHYDROUS MONOMERIC GLYOXAL PYROLYTIC GENERATION AND STABILIZATION BY THE CHIRAL RHENIUM FRAGMENT [ETA(5)-C5H5)RE(NO)(PPH3)]+

# publications[].label
Synthesis, reactivity, and metal complexes of fluorous triarylphosphines of the formula P(p-C6H4(CH2)(3)(CF2)(n-1)CF3)(3) (n=6, 8, 10)

# publications[].label
From SP carbon chains to SP3 carbon double helices: How to insulate a molecular wire.

# publications[].label
Thermomorphic fluorous phosphines as organocatalysts for Michael addition reactions

# publications[].label
Thematic issue ... Natural product synthesis

# publications[].label
Structures and energies of 10-azatriquinacene and its hydrogenation products: a computational study.

# publications[].label
Molecular gyroscopes based on osmium via alkene metathesis in the metal coordination sphere: Synthesis and characterization

# publications[].label
The Experimental Assay of Catalyst Recovery: General Concepts

# publications[].label
"Giant" gyroscope-like molecules consisting of dipolar Cl-Rh-CO rotators encased in three-spoke stators that define 25-27-membered macrocycles.

# publications[].label
From SP carbon chains to SP3 carbon double helices: How to insulate a molecular wire.

# publications[].label
ALDEHYDE AND KETONE LIGANDS IN ORGANOMETALLIC COMPLEXES AND CATALYSIS

# publications[].label
METAL-HYDRIDE VERSUS METAL-METHYL BONDING IN CHIRAL CYCLOPENTADIENYL RHENIUM COMPOUNDS

# publications[].label
Metal-catalyzed synthesis of cis-[Re(CO)<inf>4</inf>LI] [L = P(OMe) <inf>3</inf>, PMe<inf>2</inf>Ph, PPh<inf>3</inf>]

# publications[].label
BIMETALLIC ANIONIC FORMYL COMPLEXES - SYNTHESIS AND PROPERTIES

# publications[].label
Transition metal complexes for enantioselective catalysis of carbon-carbon, carbon-heteroatom, and carbon-hydrogen bond forming reactions

# publications[].label
Award-Winning Organometallic Chemistry: the Alfred-Stock-Gedachtnispreis of the GDCh

# publications[].label
Toward Permetalated Alkyne/Azide 3+2 or "Click" Cycloadducts

# publications[].label
Structural, physical, and chemical properties of fluorous compounds.

# publications[].label
Dedication to the Special Volume for Dietmar Seyferth

# publications[].label
A surprise landing on the terra incognita of macrocyclic dibridgehead diorganoarsines: syntheses, structures, and reactivities.

# publications[].label
DIASTEREOSELECTIVE AND ENANTIOSELECTIVE TRANSFORMATIONS MEDIATED BY THE CHIRAL RHENIUM LEWIS ACID [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
REACTIONS OF BENZYLRHENIUM COMPLEXES (ETA-5-C5H5)RE(NO)(L)(CH2AR) WITH PH3C+PF6- - ANALYSIS OF THE RE-C-ALPHA ROTAMERS INVOLVED IN ALPHA-HYDRIDE ABSTRACTION

# publications[].label
Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents

# publications[].label
SYNTHESIS AND REACTIVITY OF METAL ALPHA-HYDROXYALKYL COMPLEXES - GENERATION OF (CO)5MNCH(C6H5)OH, (CO)5RECH(C6H5)OH

# publications[].label
A NEW FORM OF COORDINATED CARBON - AN UNSUPPORTED C3 CHAIN SPANNING 2 DIFFERENT TRANSITION-METALS

# publications[].tags
12 Responsible Consumption and Production

# publications[].label
Toward metal-capped one-dimensional carbon allotropes: Wirelike C-6-C-20 polyynediyl chains that span two redox-active (eta(5)-C5Me5)Re(NO)(PPh3) endgroups

# publications[].label
Synthesis, structure, and reactivity of doubly trans-spanning bis(dialkyl selenide) complexes; a new route to diselenamacrocycles via alkene metathesis in metal coordination spheres

# publications[].label
Olefin metatheses in metal coordination spheres: versatile new strategies for the construction of novel monohapto or polyhapto cyclic, macrocyclic, polymacrocyclic, and bridging ligands.

# publications[].label
SYNTHESIS AND REACTIVITY OF CHIRAL METAL FLUORIDE AND WATER COMPLEXES DERIVED FROM THE RHENIUM FRAGMENT [(ETA-5-C5H5)RE(NO)(PPH3)]+

# publications[].label
Synthesis of a series of omega-dimethylaminoalkyl substituted ethylenediamine ligands for use in enantioselective catalysis

# publications[].label
A crystallographic map of chiral recognition in pi complexes of aromatic aldehydes and a chiral transition metal Lewis acid: Enantioface binding selectivities in solution correlate to distances between metal and carbon stereocenters in the solid state

# publications[].label
A PORTRAIT OF A CHIRAL TRANSITION-METAL LEWIS-ACID - HIGHLY SELECTIVE BINDING-PROPERTIES AND LIGAND ADDITION-REACTIONS

# publications[].label
NEW FAMILIES OF COORDINATED CARBON - LINEAR CARBON CHAINS THAT SPAN 2 RHENIUM METALS

# publications[].label
"Click" Chemistry in Metal Coordination Spheres: Copper(I)-Catalyzed 3+2 Cycloadditions of Benzyl Azide and Platinum Polyynyl Complexes trans-(C6F5)(p-tol(3)P)(2)Pt(C C)(n)H (n=2-6)

# publications[].label
REGIOSPECIFIC AND STEREOSPECIFIC REACTIONS OF PH3C+PF6- WITH RHENIUM ALKYLS (ETA-C5H5)RE(NO)(PPH3)(R) - ALPHA-HYDRIDE VS BETA-HYDRIDE ABSTRACTION

# publications[].label
Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring-Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR

# publications[].label
Shortwave Infrared Fluorofluorophores for Multicolor In Vivo Imaging.

# publications[].label
AN ISOLABLE ORGANOMETALLIC CATION-RADICAL IN WHICH A C4 CHAIN CONDUCTS CHARGE BETWEEN 2 CHIRAL AND CONFIGURATIONALLY STABLE RHENIUM TERMINI

# publications[].label
Transition metal catalysis in fluorous media: application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes

# publications[].label
Synthesis and properties of fluorous arenes and triaryl phosphorus compounds with branched fluoroalkyl moieties ("split pony tails")

# publications[].label
Phase transfer activation of Grubbs' ROMP catalyst systems

# publications[].label
Inaugural Schlenk Lecture at the University of Tubingen

# publications[].label
ALKYLATION AND ACYLATION OF THE IRON CARBONYL ANION M+[(CO)4FESI(CH3)3]-

# publications[].label
Thermomorphic fluorous imine and thioether palladacycles as precursors for highly active Heck and Suzuki catalysts; evidence for palladium nanoparticle pathways

# publications[].label
SYNTHESIS AND CHEMISTRY OF THE RHENIUM-CARBON DOUBLE-BOND

# publications[].label
Configurational equilibria in amido and lithioamido complexes of formulas (eta(5)-C5H5)Re(NO)(PAr3)(NHCHRR') and (eta(5)-C5H5)Re(NO)(PAr3)(NLiR''): Epimerization occurs at rhenium via phosphine dissociation

# publications[].label
EXPLORATORY ORGANOMETAL-SULFUR CHEMISTRY - SYNTHESES AND UNUSUAL PROPERTIES OF RHENIUM CH2SR, CHSRR', AND =CHSR]+ COMPLEXES

# publications[].label
-[Co((S,S)-dpen)3]3+ 2I-B(C6F5)4-: A Second Generation Air- and Water-Stable Chiral Solvating Agent for Chirality Sensing (dpen = NH2CHPhCHPhNH2).

# publications[].label
THERMODYNAMIC ALDEHYDE ENANTIOFACE BINDING SELECTIVITIES IN COMPLEXES OF CHIRAL METAL FRAGMENTS - MECHANISM OF INTERCONVERSION OF DIASTEREOMERIC PI-ALDEHYDE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-2-O = CHAR)]BF4

# publications[].label
ALPHA-SILYLOXY AND ALPHA-HYDROXY METAL ALKYLS - SYNTHESIS AND CHEMISTRY

# publications[].label
Synthesis of fluorous sulfur/carbon/sulfur pincer ligands and palladium complexes: New catalyst precursors for the Heck reaction

# publications[].label
DEOXYGENATION OF EPOXIDES BY METAL ATOM CO-CONDENSATION

# publications[].label
Synthesis and oxidation of dirhenium C-4, C-6, and C-8 complexes of the formula (eta(5)-C5Me5)Re(NO)(PR3)(C C)(n)(R3P)(ON)Re(eta(5)-C5Me5)(R=4-C6H4R ', c-C6H11): In search of dications and radical cations with enhanced stabilities

# publications[].label
Announcement: Organometallics Symposium, 2012 (Philadelphia ACS Meeting, August 19-23)

# publications[].label
Another Great Day for Organometallic Chemistry

# publications[].label
A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated tetrayne.

# publications[].label
Syntheses, structures, and reactions of cyrhetrenylphosphines; applications in palladium catalyzed Suzuki cross-coupling reactions

# publications[].label
Appreciably bent sp carbon chains: Synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (5-C5Me5)Re(NO)(PPh 3)((CC)n-p-C6H4Me)

# publications[].label
SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF CHIRAL RHENIUM AROMATIC ALDEHYDE COMPLEXES [(ETA(5)-C5H5)RE(NO)(PPH3)(O=CHAR)]+X- - EQUILIBRIA BETWEEN PI-ALDEHYDE AND SIGMA-ALDEHYDE BINDING MODES

# publications[].label
Synthesis, purification, and characterization of phosphine oxides and their hydrogen peroxide adducts.

# publications[].label
SELECTIVE ACTIVATION OF ONE METHYL KETONE ENANTIOFACE VIA SIGMA-BINDING TO A CHIRAL TRANSITION-METAL TEMPLATE - SYNTHESIS, STRUCTURE, AND REACTIVITY OF RHENIUM KETONE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(ETA-1-O=C(CH3)R)]+X-

# publications[].label
Application of olefin metathesis in a metal coordination sphere: Synthesis of molecular gyroscopes and related complexes

# publications[].label
REACTIONS OF ORGANO-CYCLOPROPANES AND SPIROCYCLES WITH METAL ATOMS

# publications[].label
SYNTHESES OF CYCLIC IMINE COMPLEXES OF THE CHIRAL RHENIUM LEWIS-ACID [(ETA(5)-C5H5)RE(NO)(PPH3)]+ BY HYDRIDE ION ABSTRACTION FROM AMIDO COMPLEXES

# publications[].label
SYNTHESIS AND REACTIVITY OF CHIRAL RHENIUM INDENYL COMPLEXES OF THE FORMULA [(ETA(5)-C9H7)RE(NO)(PPH3)(X)]N+

# publications[].label
Metal template approach towards efficiency enhancement in hydrogen-bond promoted enantioselective organocatalysis

# publications[].label
Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands.

# publications[].label
Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties.

# publications[].label
TRANSITION-METAL FORMYL COMPLEXES - SYNTHESIS BY TRIALKYLBOROHYDRIDE ATTACK ON METAL-CARBONYL ACYLS

# publications[].label
Award Winning Green Organometallic Chemistry: The Presidential Green Chemistry Challenge

# publications[].label
Analogs of Grubbs' second generation catalyst with hydrophilic phosphine ligands: phase transfer activation of ring closing alkene metathesis.

# publications[].label
NEW FAMILIES OF COORDINATED CARBON - OXIDATIVE COUPLING AND CROSS-COUPLING OF A TRANSITION-METAL BUTADIYNYL COMPLEX TO BIMETALLIC M-C-CC-CC-CC-C-M AND M-C-CC-CC-C-M ADDUCTS

# publications[].label
Attaching metal-capped sp carbon chains to metal clusters: Synthesis, structure, and reactivity of rhenium/triosmium complexes of formula [(eta(5)-C5Me5)Re(NO)(PPh3)(CC)(n)Os-3(CO)(y)(X)(z)](m+), including carbon geometries more distorted than planar tetracoordinate

# publications[].label
Syntheses, structures, and catalytic reactions of palladium adducts of chiral diphosphines that contain a rhenium stereocenter in the backbone

# publications[].label
SYNTHESIS, STRUCTURE, DYNAMIC BEHAVIOR, AND REACTIVITY OF CHIRAL RHENIUM PRIMARY PHOSPHINE AND PHOSPHIDO COMPLEXES OF THE FORMULA [(ETA-5-C5H5)RE(NO)(PPH3)(PRH2)]+X- AND (ETA-5-C5H5)RE(NO)(PPH3)(PRH)

# publications[].label
New macrocyclic components for rotaxanes

# publications[].label
NEW DEOXYGENATIVE TRANSFORMATIONS - REACTIONS OF (CO)4FE[SI(CH3)3]2 WITH ACYCLIC ETHERS

# publications[].label
Metal-metal interaction across bridging elemental carbon chains: A computational study of odd-carbon complexes.

# publications[].label
Revealing and predicting the stability of PtII-containing molecular gyroscope isomers

# publications[].label
ASYMMETRIC CONJUGATE ADDITION AND DIELS-ALDER REACTIONS PROMOTED BY THE CHIRAL RHENIUM LEWIS-ACID [(ETA(5)-C5H5)RE(NO)(PPH3)]+

# publications[].label
LIGAND WRAPPING AROUND CHROMIUM - REACTIONS OF DIPHENYLMETHANE, 1,4-DIPHENYLBUTANE, BENZYL ETHER, AND BENZYL SULFIDE WITH CHROMIUM ATOMS

# publications[].label
A VERSATILE NEW ROUTE TO CARBON COMPLEXES OF THE FORMULA L(N)MCCM'L'(N') - DEPROTONATION AND METALATION OF THE TERMINAL ACETYLIDE COMPLEX (ETA-5-C5ME5)RE(NO)(PPH3)(CCH)

# publications[].label
Synthesis, properties, and reactions of enantiomerically pure, chiral fluorous phosphines of the formula (menthyl)P(CH2CH2(CF2)(n-1)CF3)(2) (n=6, 8)

# publications[].label
New fluorous palladium catalyst for aryl halide coupling reactions.

# publications[].label
Bent and stretched but not yet to the breaking point: C(8)-C(16) sp carbon chains that span two platinum atoms and the first structurally characterized 1,3,5,7,9,11,13,15-octayne.

# publications[].label
Generation and reactions of ruthenium phosphido complexes [(eta5-C5H5)Ru(PR'3)2(PR2)]: remarkably high phosphorus basicities and applications as ligands for palladium-catalyzed Suzuki cross-coupling reactions.

# publications[].label
REACTIONS OF DIPHENYL(TRIMETHYLSILYL)PHOSPHANE WITH ALKYL(PENTACARBONYL)MANGANESE - SYNTHESIS OF THE YLIDE COMPLEXES (CO)4MNCR(OSIME3)PPH2 AND A NEW DRIVING FORCE FOR CO INSERTION

# publications[].label
MECHANISM OF COUPLING OF =CH2 TO H2C=CH2 AT A HOMOGENEOUS (ETA-C5H5)RE(NO)(PPH3)+ CENTER - REMARKABLE ENANTIOMER SELF-RECOGNITION

# publications[].label
Chiral recognition in pi complexes of alkenes, aldehydes, and ketones with transition metal Lewis acids; Development of a general model for enantioface binding selectivities

# publications[].label
REACTIONS OF THE NEOHEXYL IODIDE COMPLEX [(ETA-5-C5H5)RE(NO)(PPH3)(ICH2CH2C(CH3)3)]+BF4- AND NUCLEOPHILES - STEREOCHEMISTRY OF CARBON-IODINE BOND-CLEAVAGE IN HIGHLY ACCELERATED SN2 REACTIONS

# publications[].label
Structures and Dynamics of Secondary and Tertiary Alkylphosphine Oxides Adsorbed on Silica.

# publications[].label
Gyroscope-Like Complexes Based on Dibridgehead Diphosphine Cages That Are Accessed by Three-Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)(+), and Fe(CO)3(H)(+) Rotators.

# publications[].label
Award-Winning Organometallic Chemistry: The 2013 RSC Sir Edward Frankland Fellowship

# publications[].label
A NEW METHOD FOR THE ACTIVATION OF METAL-BOUND METHYL-GROUPS - OXIDATIVE DISPROPORTIONATION TO COORDINATED ETHYLENE AND METHANE

# publications[].publisher
American Association for the Advancement of Science (AAAS)

# publications[].label
En route to diplatinum polyynediyl complexes trans, trans-(Ar)(R3P)(2)Pt(C C)(n)Pt(PR3)(2)(Ar): Untold tales, including end-group strategies

# publications[].label
3 RATIONAL SYNTHESES OF NEW STABLE METAL ALPHA-HYDROXYALKYL COMPLEXES

# publications[].label
Ring opening metathesis polymerization of an eta 4-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of pi bound metal fragments (vol 48, pg 7925, 2012)

# publications[].label
ALKYLATION AND ACYLATION OF THE IRON CARBONYL ANION [(CO)4FESI(CH3)3]- - EVIDENCE FOR 1,3-SILATROPIC SHIFTS FROM IRON TO ACYL OXYGEN

# publications[].label
Investigation of High-Pressure Phase Transitions in Castor Oil Using SH Surface Acoustic Waves

# publications[].publisher
Institute of Electrical and Electronics Engineers (IEEE)

# publications[].label
An easily accessed class of recyclable hypervalent iodide reagents for functional group oxidations: bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)(n-1)I(OCOCF3)(2)

# publications[].label
Syntheses and structures of tetraplatinum bis(polyynediyl) complexes with laterally arrayed sp carbon chains

# publications[].label
SYNTHESIS AND REACTIVITY OF CHIRAL RHENIUM AMINE AND AMIDE COMPLEXES OF THE FORMULAS [(ETA-5-C5H5)RE(NO)(PPH3)(NHRR')]+TFO- AND (ETA-5-C5H5)RE(NO)(PPH3)(NRR')

# publications[].label
Convenient syntheses of fluorous phenols of the formula HOC6H5-n((CH2)(3)(CF2)(7)CF3)(n) (n=1, 2) and the corresponding triarylphosphites

# publications[].label
Three-fold intramolecular ring-closing metatheses involving square-planar platinum complexes with cis-phosphorus donor ligands: syntheses, structures, and properties of parachute-like complexes.

# publications[].label
PI/SIGMA EQUILIBRIA IN RHENIUM KETONE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O=CRR')]+X- - A MARKED ELECTRONIC EFFECT UPON THE BINDING MODE

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# streetAddress
Texas A&M University; Chemistry Department; 3255 TAMU

# schools[]
Texas A&M Engineering Experiment Station (TEES)

# etdChairOf[].label
Lang, Georgette Marie (2016-08). Synthesis of Gyroscope like Complexes via Alkene Metathesis: The Effect of Ligand Substitutions on Rotational Barriers. Doctoral Dissertation.

# etdChairOf[].label
Sullivan, Ann R. (2012-02). A Novel Fluorous Biphasic System: Werner-type Complexes in Fluorous Media. Master's Thesis.

# etdChairOf[].label
Ghosh, Subrata Kumar (2017-09). The Development of New Classes of Enantioselective Hydrogen Bond Donor Catalysts for Organic Synthesis Based upon Werner Complexes. Doctoral Dissertation.

# etdChairOf[].label
Clough, Melissa

Catherine 1985- (2012-11). Studies of Platinum Polyynyl Complexes: Elaboration of Novel "Click" Cycloadducts and Fluorous and Polygon Based Platinum Polyyndiyl Systems. Doctoral Dissertation.

# etdChairOf[].label
Studies of Platinum Polyynyl Complexes: Elaboration of Novel "Click" Cycloadducts and Fluorous and Polygon Based Platinum Polyyndiyl Systems

# etdChairOf[].label
Mukherjee, Tathagata (2015-07). Second Coordination Sphere Promoted Catalysis: Organometallic Hydrogen Bond Donors for Enantioselective Organic Transformations. Doctoral Dissertation.

# etdChairOf[].label
Lewis, Kyle (2013-12). The Development of Werner-type Cobalt Complexes in Enantioselective Hydrogen Bond Mediated Catalysis. Doctoral Dissertation.

# etdChairOf[].label
Kharel, Sugam (2018-08). Topologically Novel Phosphorus Compounds and Metal Complexes. Doctoral Dissertation.

# etdChairOf[].label
Zeits, Paul (2012-02). Olefin Metatheses in Metal Coordination Spheres: Development of Gyroscope-like  trans-Spanning Bis(pyridine) Complexes and Organometallic pi-Adducts of Conjugated  Polymers. Doctoral Dissertation.

# etdChairOf[].label
Hilliard, Casie Renee (2013-12). Diphosphine Dioxide Cages and Hydrogen Peroxide Adducts of Phosphine Oxides: Syntheses and Applications in Surface Science. Doctoral Dissertation.

# etdChairOf[].label
Baranova, Zuzana (2017-09). Studies of Rotaxanes Consisting of 1,10-Phenanthroline-Based Macrocycles and Platinum-Capped Polyynediyl Complexes: a Steric and Dynamic Approach to Insulated Molecular Wires. Doctoral Dissertation.

# etdChairOf[].label
Kharel, Sugam (2018-07). Topologically Novel Phosphorus Compounds and Metal Complexes. Doctoral Dissertation.

# etdChairOf[].label
Zhang, Tianyi (2017-02). Research on Diplatinum Polyyne Complexes:  Atropisomerism and Bottom-Up Syntheses of Graphene. Doctoral Dissertation.