# positions[].organizations[].parent[].label
Texas A&M Engineering Experiment Station (TEES)

# overview
The fundamentally interesting and challenging chemistry associated with carbon dioxide, coupled with its high potential as a source of chemical carbon, provides adequate justification for comprehensive investigations in this area. In our research program we have attempted to establish a clearer mechanistic view of carbon-hydrogen, carbon-carbon, and carbon-oxygen bond forming processes resulting from carbon dioxide insertion into M-H, M-C, and M-O bonds.

Relevant to the latter process our research has addressed the utilization of carbon dioxide in the development of improved synthetic routes for the production of polycarbonates. The hazardous and expensive production process currently in place industrially for these materials involves the interfacial polycondensation of phosgene and diols, accentuates the need for these studies. Although we and others have made significant advances in the synthesis of these useful thermoplastics from carbon dioxide and epoxides much of the fundamental knowledge concerning the reaction kinetics of these processes is lacking, due in part to the practical challenges associated with sampling and analyzing systems at elevated temperatures and pressures. This information is needed for making this process applicable to the synthesis of a variety of copolymers possessing a range of properties and uses. Our studies are examining in detail the mechanistic aspects of metal catalyzed carbon dioxide/epoxide coupling reactions employing in situ spectroscopy methods. For this purpose Fourier-transform infrared attenuated total refluctance (FTIR/ATR) spectroscopy is being utilized. Other related investigations involve the development of structural and reactivity models for the industrially prevalent double metal cyanide catalysts(DMC) used in polyethers and polycarbonate synthesis from epoxides or CO2/epoxides, respectively.

# keywords[]
0307 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
4007 Control Engineering, Mechatronics And Robotics

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# educationAndTraining[].organization.label
University of Illinois at Urbana Champaign - (Urbana, Illinois, United States)

# educationAndTraining[].organization.label
California State University Los Angeles - (Los Angeles, California, United States)

# awardsAndHonors[].label
Association of Former Students University-Level Distinguished Achievement Award, The

# awardsAndHonors[].label
College of Science Undergraduate Research Mentoring Award

# awardsAndHonors[].label
Association of Former Students College-Level Teaching Distinguished Achievement Award, The

# publications[].label
An experimental and theoretical investigation of the carbon dioxide insertion process into the tungsten-nitrogen bond of an anionic W(0) complex.

# publications[].label
THE IMPORTANCE OF REACTIONS OF OXYGEN BASES WITH METAL-CARBONYL DERIVATIVES IN CATALYSIS

# publications[].label
Bifunctional organoboron-phosphonium catalysts for coupling reactions of CO2 and epoxides.

# publications[].label
Effective, selective coupling of propylene oxide and carbon dioxide to poly(propylene carbonate) using (salen)CrN3 catalysts.

# publications[].label
ROLE OF THE METAL CENTER IN THE HOMOGENEOUS CATALYTIC DECARBOXYLATION OF SELECT CARBOXYLIC-ACIDS - COPPER(I) AND ZINC(II) DERIVATIVES

# publications[].label
MetalTemplated, Tight Loop Conformation of a CysXCys Biomimetic Assembles a Dimanganese Complex

# publications[].label
INTRAMOLECULAR LIGAND REARRANGEMENTS IN ANIONIC GROUP-6 METAL PENTACARBONYL HYDRIDE DERIVATIVES

# publications[].label
Analysis of bridgehead effects on [FeFe]-hydrogenase active site models: Steric bulk at nitrogen vs. carbon

# publications[].label
Reactions of transition-metal carbonyls with organolithium compounds. III. Synthesis of tetracarbonyl (tertiary phosphite) oxy- and amino-carbene complexes of the group VIB metals

# publications[].label
Mechanistic Insights into Water-Mediated Tandem Catalysis of Metal-Coordination CO2/Epoxide Copolymerization and Organocatalytic Ring-Opening Polymerization: One-Pot, Two Steps, and Three Catalysis Cycles for Triblock Copolymers Synthesis

# publications[].label
INFRARED DETERMINATION OF STEREOCHEMISTRY IN METAL COMPLEXES . AN APPLICATION OF GROUP THEORY

# publications[].label
EVIDENCE FOR FLUXIONALITY AND STRUCTURE IN SOLUTION OF INTERMEDIATES OF TYPE W(CO)4(L) (L=LEWIS BASE)

# publications[].label
PI ACIDITY OF TRIS(2-CYANOETHYL)PHOSPHINE - X-RAY STRUCTURAL STUDIES OF M(CO)5P(CH2CH2CN)3(M=CR,MO) AND MO(CO)5P(C6H5)3

# publications[].label
METAL-INDUCED TRANSFORMATIONS OF CARBON-DIOXIDE - CARBON CARBON BOND FORMING PROCESSES INVOLVING ANIONIC GROUP 6B METAL DERIVATIVES AND THE X-RAY STRUCTURE OF [PNP][CIS-CH3W(CO)4P(CH3)3]

# publications[].label
IDENTIFICATION OF THE VARIOUS MODES OF CARBOXYLATE BINDING TO METAL CENTERS BY INFRARED-SPECTROSCOPY

# publications[].label
ELECTROCHEMICAL STUDY OF THE OXIDATION CHEMISTRY OF CHROMIUM CARBONYL THIOLATES RSCR(CO)5- AND RSCR2(CO)10-

# publications[].label
Mossbauer studies of model complexes for the H-cluster in [Fe-Fe]-hydrogenases: Electronic structure of mixed-valence complexes containing low-spin Fe-(I)

# publications[].label
MECHANISTIC PATHWAYS FOR LIGAND SUBSTITUTION PROCESSES IN METAL-CARBONYLS

# publications[].label
STERIC CONTRIBUTIONS TO LIGAND SUBSTITUTION PROCESSES IN IR4(CO)12-3-[PR3]N, IR4(CO)12-4-[PR3]N DERIVATIVES

# publications[].label
Carbon dioxide-epoxide copolymerization: Kinetics of metal-bound enchainment and degradation reactions

# publications[].label
Carbon dioxide/epoxide coupling reactions utilizing Lewis base adducts of zinc halides as catalysts. Cyclic carbonate versus polycarbonate production.

# publications[].label
CHEMISTRY OF ZERO-VALENT TUNGSTEN ALKOXIDES - SYNTHESIS, X-RAY STRUCTURE, AND REACTIVITY TOWARD CARBON-DIOXIDE

# publications[].label
CATALYTIC ACTIVITY OF ZINC(II) PHENOXIDES WHICH POSSESS READILY ACCESSIBLE COORDINATION SITES - COPOLYMERIZATION AND TERPOLYMERIZATION OF EPOXIDES AND CARBON-DIOXIDE

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR CARBONYL CLUSTERS .9. REACTIONS OF CO4(CO)9(TRIPOD), TRIPOD = HC(PPH2)3, AND ITS DERIVATIVES

# publications[].label
The preparation and characterization of a series of catalytically active Zn(II)phenoxides.

# publications[].label
Chromium, molybdenum and tungsten annual servey covering the year 1973

# publications[].label
REACTIONS OF GRIGNARD REAGENTS WITH METAL CARBONYLS - INOR

# publications[].label
SOLUTION PHOTOCHEMISTRY OF ANIONIC METAL-CARBONYL HYDRIDE DERIVATIVES - SUBSTITUTION AND DIMER DISRUPTION PROCESSES IN MU-H[M(CO)5]2-(M=CR AND W)

# publications[].label
REACTION OF CATIONIC GROUP 7B METAL-CARBONYL DERIVATIVES WITH SODIUM HYDROGEN-SULFIDE - PRODUCTION OF METAL-HYDRIDES

# publications[].label
SYNTHESIS, REACTIVITY, AND X-RAY STRUCTURE OF FAC-W(CO)3(DPPM)(CH3CN) - STEREOSELECTIVE PREPARATION OF FAC-W(CO)3(CO)-C-13)(DPPM) AND SUBSEQUENT INTRAMOLECULAR REARRANGEMENT PROCESSES

# publications[].label
Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase

# publications[].label
Depolymerization of poly(indene carbonate) produced from CO2 and indene oxide to generate monomeric materials

# publications[].publisher
International Union of Crystallography (IUCr)

# publications[].label
Synthesis and characterization of novel zinc phenoxide phosphine complexes.

# publications[].label
X-RAY STRUCTURAL STUDIES OF CIS-MO(CO)4(PR3)2 (R=ME,ET,N-BU) DERIVATIVES AND THEIR RELATIONSHIP TO SOLUTION ISOMERIZATION PROCESSES IN THESE OCTAHEDRAL SPECIES

# publications[].label
Photochemistry of CpM(CO)(2)Cl [M = Fe, Ru] complexes: A time-resolved infrared study

# publications[].label
SYNTHESIS OF METAL-CARBONYL-COMPLEXES HIGHLY ENRICHED IN C-13 - UTILIZATION OF THE CO-LABILIZING ABILITY OF (N-BU)3P=O

# publications[].label
Homogenous zinc carboxylates as CO2/epoxide copolymerization catalysts

# publications[].label
INOR 831-Kinetic and mechanistic studies into the copolymerization of carbon dioxide and epoxides via fluorinated manganese (III) acacen complexes

# publications[].label
Synthesis of poly(indene carbonate) from indene oxide and carbon dioxide: A polycarbonate with a rigid backbone

# publications[].label
Switchable catalytic processes involving the copolymerization of epoxides and carbon dioxide for the preparation of block polymers

# publications[].label
ISOLATION OF PENTAMETHYLCYCLOPENTADIENYLCHROMIUM TRICARBONYL DIMER BY 2 METHODS - X-RAY CRYSTAL STRUCTURAL STUDY OF 2 POLYMORPHS

# publications[].label
Comments on the depolymerization of polycarbonates derived from epoxides and carbon dioxide: A mini review

# publications[].label
Organometallic complexes of uracil and orotic acid derivatives: Coordination mode, structure, and reactivity

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR METAL-CARBONYL CLUSTERS .1. CO4(CO)9(MU-2-CO)3 DERIVATIVES

# publications[].label
CHROMIUM, MOLYBDENUM AND TUNGSTEN - ANNUAL SURVEY COVERING YEAR 1974

# publications[].label
THE ACTIVATION OF CARBON-DIOXIDE BY METAL-COMPLEXES

# publications[].label
INTERMEDIATES IN THE REACTION OF TRANS-CR(CO)4(PPH3)2 WITH CO-13 AND FLUXIONALITY IN OCTAHEDRAL GROUP 6B METAL-CARBONYLS VIA A NON-DISSOCIATIVE MECHANISM

# publications[].label
INTRAMOLECULAR AND INTERMOLECULAR HYDROGEN-BONDING IN TRIPHENYLPHOSPHINE DERIVATIVES OF COPPER(I) CARBOXYLATES, (PH(3)P)(2)CUO2C(CH2)(N)COOH - ROLE OF COPPER(I) IN THE DECARBOXYLATION OF MALONIC-ACID AND ITS DERIVATIVES

# publications[].label
Rich man's proton: Triphenylphosphinegold as probe of hydride positions in organo- and bioorgano-metallic complexes

# publications[].label
Solution and solid-state structures of phosphine adducts of monomeric zinc bisphenoxide complexes. Importance of these derivatives in CO2/epoxide copolymerization processes.

# publications[].label
What is the real steric impact of triphenylphosphite? Solid-state and solution structural studies of cis- and trans-isomers of M(CO)(4)[P(OPh)(3)](2) (M = Mo and W)

# publications[].label
SUPERCRITICAL CARBON-DIOXIDE AS SOLVENT FOR THE COPOLYMERIZATION OF CARBON-DIOXIDE AND PROPYLENE-OXIDE USING A HETEROGENEOUS ZINC CARBOXYLATE CATALYST

# publications[].label
FT-IR, PHOTOACOUSTIC AND MICRO-RAMAN SPECTRA OF THE DODECACARBONYLTRIRUTHENIUM(0) COMPLEXES (RU3CO12)-C-13 AND RU3(CO)12

# publications[].label
METAL INDUCED TRANSFORMATIONS OF CARBON-DIOXIDE

# publications[].label
3D Printed CO2 -Based Triblock Copolymers and Post-Printing Modification.

# publications[].label
Kinetic and Computational Analysis of CO Substitution in a Dinuclear Osmium Carbonyl Complex: Intersection between Dissociative and Dissociative-Interchange Mechanisms.

# publications[].label
Kinetics and mechanism of CO2 insertion into Ru-C and Ru-H bonds

# publications[].label
Copolymerization of Carbon Dioxide and Cyclohexene Oxide Catalyzed by Chromium Complexes Bearing Semirigid [ONSO]-Type Ligands

# publications[].label
Syntheses and Structures of [CH2(NCnH2n)(2)]Mo(CO)(4) (n=4,5) Complexes with Bis(cycloamine) Ligands Easily Prepared from CH2Cl2

# publications[].label
Acrylic acid derivatives of group 8 metal carbonyls: a structural and kinetic study.

# publications[].label
PHOTOCHEMISTRY OF PIPERIDINE PENTACARBONYL COMPLEXES OF THE GROUP-6B METALS ISOLATED IN AN ARGON MATRIX AT 10 K

# publications[].label
OXYGEN-EXCHANGE REACTIONS OF H2O-O-18 WITH HEXACARBONYL CATIONS OF MANGANESE AND RHENIUM

# publications[].label
DECARBOXYLATION REACTIONS INVOLVING COPPER(I) COMPLEXES DERIVED FROM CU-CO DIMERS

# publications[].label
3D Printed CO2Based Triblock Copolymers and PostPrinting Modification

# publications[].label
Chirality-Guided Isomerization of Mn2S2 Diamond Core Complexes: A Mechanistic Study.

# publications[].label
Infrared spectroscopic studies of organometallic models of the iron site in [NiFe] hydrogenases

# publications[].label
FACILE REDUCTION OF CARBON-DIOXIDE BY ANIONIC GROUP 6B METAL-HYDRIDES - CHEMISTRY RELEVANT TO CATALYSIS OF THE WATER-GAS SHIFT REACTION

# publications[].label
Development of nickel dithiolate complexes as chemical sensors for SO2: Characteristics and structures of NiN2S2/SO2 adducts.

# publications[].label
N2S2Ni metallothiolates as a class of ligands that support organometallic and bioorganometallic reactivity.

# publications[].label
Poly(trimethylene monothiocarbonate) from the Alternating Copolymerization of COS and Oxetane: A Semicrystalline Copolymer

# publications[].label
Salen metal complexes as catalysts for the synthesis of polycarbonates from cyclic ethers and carbon dioxide

# publications[].label
LIGAND ADDITIVITY IN THE VALENCE PHOTOELECTRON-SPECTROSCOPY OF PHOSPHINE-SUBSTITUTED MOLYBDENUM CARBONYLS

# publications[].label
CRYSTAL-STRUCTURE AND REACTIVITY OF [CU(DMPE)2][CU(CO(CO)4)2] (DMPE = 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE) - STAGGERED AND ECLIPSED CONFORMATIONS OF [(CO)4COCUCO(CO)4]- ANIONS

# publications[].label
Kinetic Studies of the Alternating Copolymerization of Cyclic Acid Anhydrides and Epoxides, and the Terpolymerization of Cyclic Acid Anhydrides, Epoxides, and CO2 Catalyzed by (salen)(CrCl)-Cl-III

# publications[].label
Metal(0) carbonyl complexes of uracil derivatives: Examination of the pi-donating ability of pseudo amido groups.

# publications[].label
Coordination Chemistry, Structure, and Reactivity of Thiouracil Derivatives of Tungsten(0) Hexacarbonyl: A Theoretical and Experimental Investigation into the Chelation/Dechelation of Thiouracil via CO Loss and Addition.

# publications[].label
CD-113 SHIELDING TENSORS OF MONOMERIC CADMIUM COMPOUNDS CONTAINING NITROGEN DONOR ATOMS .2. SYNTHESES, CRYSTAL-STRUCTURES, AND CD-113 NMR-SPECTROSCOPY OF THE 6-COORDINATE COMPLEXES [HB(PZ)(3)]2CD, [HB(3-PHPZ)(3)]2CD, AND [B(PZ)(4)]CD[HB(3-PHPZ)(3)] (PZ=PYRAZOLYL)

# publications[].label
Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Dimanganese Complex.

# publications[].label
Copolymerization of cyclopentene oxide with CO2 utilizing bifunctional cobalt(III)- and chromium(III)-salen catalysts

# publications[].label
SOLUTION PHOTOSUBSTITUTION CHEMISTRY OF AMINE PENTACARBONYL DERIVATIVES OF GROUP 6B METALS IN PRESENCE OF CO-13 - EXAMPLE OF STEREOSPECIFIC INCORPORATION OF CO-13

# publications[].label
Photochemically Generated Transients from kappa(2)- and kappa(3)-Triphos Derivatives of Group 6 Metal Carbonyls and Their Reactivity with Olefins

# publications[].label
Synthesis of CO2-Derived Poly(indene carbonate) from Indene Oxide Utilizing Bifunctional Cobalt(III) Catalysts

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR CARBONYL CLUSTERS .6. STERIC CONTRIBUTION TO LIGAND DISSOCIATION IN MULTI-SUBSTITUTED IR4(CO)12 DERIVATIVES

# publications[].label
PREPARATION OF ISOTOPICALLY LABELED GROUP VIIB CARBONYL DERIVATIVES

# publications[].label
THE CATALYTIC DECARBOXYLATION OF CYANOACETIC ACID - ANIONIC TUNGSTEN CARBOXYLATES AS HOMOGENEOUS CATALYSTS

# publications[].label
LIGAND MIGRATION IN SULFUR-CAPPED GROUP-VI METAL-CLUSTERS

# publications[].label
Synthetic Metallodithiolato Ligands as Pendant Bases in [FeIFeI], [FeI[Fe(NO)]II], and [(-H)FeIIFeII] Complexes.

# publications[].label
One-pot switchable catalytic processes involving the copolymerization of epoxides and carbon dioxide

# publications[].label
Solution and solid-state structural studies of epoxide adducts of cadmium phenoxides. Chemistry relevant to epoxide activation for ring-opening reactions.

# publications[].label
A phase separable polycarbonate polymerization catalyst.

# publications[].label
MECHANISTIC INVESTIGATIONS INTO THE ACTIVATION OF CARBON-DIOXIDE BY TRANSITION-METAL OXYGEN BONDS - SYNTHESIS AND CHARACTERIZATION OF GROUP-6 ARYL- AND ALKOXIDE CARBONYL-COMPLEXES

# publications[].label
Production of poly(lactide) using chiral zinc complexes

# publications[].label
Ring opening polymerization of trimethylene carbonate using metal salen catalysts

# publications[].label
Five-coordinate Schiff base complexes of gallium. Potential catalysts for the copolymerization of carbon dioxide and epoxides

# publications[].label
Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Ni, Fe, Co) as metallodithiolate ligands

# publications[].label
Infrared intesities of the carbonyl stretching modes in bipyramidal cobalt and iron tetracarbonyl compounds

# publications[].label
INOR 694-Redox active ligands as related to the active site of [FeFe]-hydrogenase

# publications[].label
CONCOMITANT BOND FORMATION AND BOND FISSION IN THE MASS-SPECTRAL FRAGMENTATION OF AN ORGANOMETALLIC MOLECULE

# publications[].label
METHANATION OF CO2 USING INTRAZEOLITE RUTHENIUM CARBONYL CATALYSTS

# publications[].label
Low valent group 6 metal carbonyl complexes containing ligands capable of pi-donation: Creating and stabilizing "16-electron" unsaturated metal complexes.

# publications[].label
Facile Synthesis of Well-Defined Branched Sulfur-Containing Copolymers: One-Pot Copolymerization of Carbonyl Sulfide and Epoxide.

# publications[].label
CO-LABILIZING ABILITY OF THE FLUORIDE LIGAND IN TUNGSTEN(0) CARBONYL FLUORIDES - X-RAY STRUCTURE OF [ET(4)N](3)[W-2(CO)(6)F-3]

# publications[].label
Amino Acid Complexes of Metal Carbonyls: Mechanistic Aspects of the CO-Labilizing Ability of Glycinate Ligands in Zero-Valent Chromium and Tungsten Derivatives.

# publications[].label
Biomimetic study of a polymeric composite material for joint repair applications

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR METAL-CARBONYL CLUSTERS .1. CO4(CO)9 (MU2-CO)3 DERIVATIVES

# publications[].label
Copolymerization of CO2 and epoxides catalyzed by metal salen complexes.

# publications[].label
Depolymerization of Poly(indene carbonate). A Unique Degradation Pathway

# publications[].label
ARYLOXIDE AND ALKOXIDE DERIVATIVES OF METAL-CLUSTERS - SYNTHESES, STRUCTURES, AND REACTIVITIES OF THE MU-OXO-BRIDGED TRIRUTHENIUM CLUSTERS RU3(CO)8(MU-ETA-2-OC6H4CL)2 AND RU3(CO)8(MU-ETA-2-OCH2C5H4N)2

# publications[].label
THE SODIUM-SALT OF TRI(M-SULFONATOPHENYL) PHOSPHINE AS A WATER SOLUBILIZING LIGAND FOR TUNGSTEN AND IRON CARBONYL, AND CARBONYL HYDRIDE COMPLEXES

# publications[].label
CHROMIUM TRICARBONYL CATECHOLATE DERIVATIVES - STRUCTURAL AND REACTIVITY STUDIES OF 16-ELECTRON COMPLEXES

# publications[].label
Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides by MetalFree Lewis Pairs

# publications[].label
Availability of Other Aliphatic Polycarbonates Derived from Geometric Isomers of Butene Oxide and Carbon Dioxide Coupling Reactions

# publications[].label
Investigation of unique dissymmetric model complexes of the [FeFe]-hydrogenase active site

# publications[].label
Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes

# publications[].label
RELATIVE IMPORTANCE OF SIGMA AND PI BONDING OF N2 AND CO TO TRANSITION METALS

# publications[].label
AEI 50-Synergy between experiment and theory: Iron-catalyzed dihydrogen production and copper-catalyzed C-N bond formation

# publications[].label
CONVENIENT SYNTHESIS OF CIS-MO(CO)4L2 DERIVATIVES (L = GROUP 5A LIGAND) AND A QUALITATIVE STUDY OF THEIR THERMAL REACTIVITY TOWARD LIGAND DISSOCIATION

# publications[].label
PREPARATION AND STRUCTURE OF W(CO)5OPPH2NPPH3, A NOVEL COMPLEX CONTAINING A LIGAND DERIVED FROM THE "BIS(TRIPHENYLPHOSPHINE)NITROGEN(1+) CATION

# publications[].label
A MECHANISTIC STUDY OF LIGAND SUBSTITUTION-REACTIONS OF W(CO)5O2CCH3- AND RELEVANCE TOWARD OLEFIN INSERTION PROCESSES

# publications[].label
ANIONIC GROUP-6B METAL-CARBONYL HYDRIDES AND FORMATES - CHEMISTRY RELEVANT TO CATALYSIS OF THE WATER GAS SHIFT REACTION BY GROUP-6B METAL HEXACARBONYLS

# publications[].label
MECHANISM OF DIOXYGEN ADDITION TO NICKEL-BOUND THIOLATES

# publications[].label
OXYGEN-EXCHANGE REACTIONS OF CATIONIC CARBONYL DERIVATIVES OF MANGANESE AND RHENIUM WITH H-2 O-18 AND RELATED PROCESSES

# publications[].label
5-Hydroxymethylfurfural Derived Epoxy Monomers Reactions With COS: Synthesis of Polymeric Thiocarbonates with Pendant Aldehyde or Vinyl Groups.

# publications[].label
Aliphatic Polycarbonates Produced from the Coupling of Carbon Dioxide and Oxetanes and Their Depolymerization via Cyclic Carbonate Formation

# publications[].label
Light enhanced displacement of methylacrylate from iron carbonyl: Investigation of the reactive intermediate via rapid-scan FTIR and computational studies

# publications[].label
INOR 519-Copper binding to cysteine-containing peptides that are potential models for copper proteins with sulfur and nitrogen donors in the active site

# publications[].label
Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst.

# publications[].label
One-Pot Synthesis of Ion-Containing CO2-Based Polycarbonates Using Protic Ionic Liquids as Chain Transfer Agents

# publications[].label
INSERTION REACTIONS OF CARBON-DIOXIDE WITH SQUARE-PLANAR RHODIUM AND NICKEL-COMPLEXES

# publications[].label
ANIONIC GROUP-6B METAL-CARBONYLS AS HOMOGENEOUS CATALYSTS FOR CARBON-DIOXIDE HYDROGEN ACTIVATION - THE PRODUCTION OF ALKYL FORMATES

# publications[].label
Catalytic Coupling of Cyclopentene Oxide and CO2 Utilizing Bifunctional (salen)Co(III) and (salen)Cr(III) Catalysts: Comparative Processes Involving Binary (salen)Cr(III) Analogs

# publications[].label
Zinc catalysts for the copolymerization of epoxides and carbon dioxide to polycarbonates

# publications[].label
Copolymerization of propylene oxide and (CO2)-C-13 to afford completely alternating regioregular C-13-labeled Poly(propylene carbonate)

# publications[].label
DECARBOXYLATION REACTIONS OF CHROMIUM AND NICKEL FORMATES - CHEMISTRY RELEVANT TO CARBON-DIOXIDE ACTIVATION

# publications[].label
Metallo-N2S2 complexes as S-donor and M-tunable ligands in the design of heteropolymetallic coordination complexes

# publications[].label
The nature of binuclear dinitrogen complexes of rhenium(I) and rhenium(V) in solution

# publications[].label
SPECTROSCOPIC STUDIES OF SOME CARBENE PENTACARBONYL COMPLEXES OF CHROMIUM(0) AND TUNGSTEN(0)

# publications[].label
CHEMICAL AND IR SPECTRAL DETAILS OF REACTIONS INVOLVING STEREOSPECIFIC INCORPORATION OF O-18 INTO SUBSTITUTED MANGANESE AND RHENIUM CARBONYL DERIVATIVES VIA EXCHANGE-REACTIONS WITH H2O-18

# publications[].label
Structures of mixed-metal complexes bridged by cyanide groups.

# publications[].label
THE NATURE OF THE ALKOXYCARBONYL LIGAND IN CH3OC(O)CO(CO)3L

# publications[].label
CLUSTER SYNTHESIS VIA AGGREGATION - SYNTHESIS AND SOLUTION AND SOLID-STATE CHARACTERIZATION OF SULFUR-CAPPED GROUP-6 METAL-CARBONYL CLUSTERS

# publications[].label
KINETIC-STUDIES OF LIGAND SUBSTITUTION-REACTIONS AND GENERAL-BASE CATALYSIS IN AMINE-LIGAND EXCHANGE PROCESSES FOR GROUP-6B METAL-CARBONYL AMINE DERIVATIVES - KINETIC AND SPECTROSCOPIC EVIDENCE FOR HYDROGEN-BONDED INTERMEDIATES

# publications[].label
N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H(2)ase enzyme active site

# publications[].label
INFRARED INTENSITIES OF CARBONYL STRETCHING VIBRATIONS IN CYCLOPENTADIENYLIRON DICARBONYL DERIVATIVES

# publications[].label
Environmentally Benign CO2-Based Copolymers: Degradable Polycarbonates Derived from Dihydroxybutyric Acid and Their Platinum-Polymer Conjugates.

# publications[].label
Award Address (ACS Award in Inorganic Chemistry Sponsored by Aldrich Chemical Company, Inc.). Making plastics from carbon dioxide

# publications[].label
Mechanistic studies of the copolymerization reaction of oxetane and carbon dioxide to provide aliphatic polycarbonates catalyzed by (Salen)CrX complexes.

# publications[].label
Current status of copolymerization reactions of carbon dioxide and epoxides

# publications[].label
A MORE INTIMATE EXAMINATION OF THE ROLE OF COPPER(I) IN THE DECARBOXYLATION OF DERIVATIVES OF MALONIC-ACID - COMPARISONS WITH ZINC(II) ANALOGS

# publications[].label
INFRARED INTENSITY AND BAND SHAPE ANALYSIS IN DISUBSTITUTED TUNGSTEN HEXACARBONYL COMPOUNDS

# publications[].label
Organometallic derivatives of orotic acid. CO-labilizing ability of the amido group in chromium and tungsten carbonyl complexes

# publications[].label
Light-enhanced displacement of methyl acrylate from iron carbonyl: investigation of the reactive intermediate via rapid-scan Fourier transform infrared and computational studies.

# publications[].label
Synthesis and structural characterization of potassium salts of phosphane-substituted (cyclopentadienyl)iron dicyanides, and their use as bridging ligands for copper(I) phosphane derivatives

# publications[].label
REDUCTION OF CARBON-DIOXIDE AND CARBONYL SULFIDE BY ANIONIC GROUP 6B METAL-HYDRIDES AND ALKYLS - CARBON-HYDROGEN AND CARBON-CARBON BOND FORMATION PROCESSES AND THE STRUCTURE OF [PNP][CR(CO)5SC(O)H]

# publications[].label
KINETIC STUDY OF REACTION OF NAMN(CO)4L (L=CO, PHOSPHINE) WITH ALKYL-HALIDES

# publications[].label
Metal catalyzed formation of aliphatic polycarbonates involving oxetane and carbon dioxide as monomers

# publications[].label
HOMOGENEOUS CATALYTIC SYNTHESIS OF FORMALDEHYDE USING THE TUNGSTEN CARBONYL COMPLEX [(CO)5WCL]- IN THE PRESENCE OF SODIUM METHOXIDE

# publications[].label
Organometallic derivatives or orotic acid with group vi metal carbonyls.

# publications[].label
Coupling of cyclohexadiene oxide and CO2 via metal catalysts

# publications[].label
Synthetic chemistry: making a natural fuel cell.

# publications[].label
SYNTHESIS AND SPECTRAL PROPERTIES OF MANGANESE PENTACARBONYL PHOSPHINE AND PHOSPHITE CATION DERIVATIVES AND RELATED COMPLEXES

# publications[].label
Copolymerization and terpolymerization of CO2 and epoxides using a soluble zinc crotonate catalyst precursor

# publications[].label
HOMOGENEOUS CATALYSTS FOR CARBON-DIOXIDE HYDROGEN ACTIVATION - ALKYL FORMATE PRODUCTION USING ANIONIC RUTHENIUM CARBONYL CLUSTERS AS CATALYSTS

# publications[].label
MECHANISTIC ASPECTS OF CATALYTIC CARBON DIOXIDE METHANATION

# publications[].label
Cobalt catalysts for the coupling of CO2 and epoxides to provide polycarbonates and cyclic carbonates.

# publications[].label
A LINEAR, MONOMERIC COPPER(I) ACETATE DERIVATIVE, [CU(PHEN)2]2[CU(O2CCH3)2].(O2CCH3)2H - AN EFFECTIVE CATALYST FOR THE DECARBOXYLATION OF CARBOXYLIC-ACIDS

# publications[].label
MECHANISTIC ASPECTS OF CO2 EPOXIDE COUPLING REACTIONS - FORMATION OF POLYCARBONATES

# publications[].label
ELECTROCHEMICAL INVESTIGATIONS OF COMPOUNDS HAVING ISOMERIC FORMS WITH SIMILAR STANDARD REDOX POTENTIALS - OXIDATION OF BIS(TRI-NORMAL-BUTYLPHOSPHINE)MOLYBDENUM TETRACARBONYL AND RELATED COMPLEXES

# publications[].label
Role of the cocatalyst in the copolymerization of CO2 and cyclohexene oxide utilizing chromium salen complexes (vol 127, pg 14026, 2005)

# publications[].label
INTRA-MOLECULAR HYDROGEN-BONDING IMPLICATIONS ON THE LABILITY OF THE MOLYBDENUM-PIPERIDINE BOND - KINETIC AND MECHANISTIC STUDIES OF THE REACTION OF CIS-MO(CO)4[P(OCH3)3]NHC5H10 WITH CARBON-MONOXIDE

# publications[].label
Enabling New Approaches: Recent Advances in Processing Aliphatic Polycarbonate-Based Materials.

# publications[].label
SOLID-STATE AND SOLUTION STRUCTURES OF [PNP][W(CO)5O2CCH3] AND [PNP][W(CO)4(PET3)O2CCH3] AND THE CO-LABILIZING ABILITY OF THE ACETATO LIGAND IN THESE ANIONIC DERIVATIVES

# publications[].label
INSERTION REACTIONS OF CARBON-DIOXIDE WITH SQUARE-PLANAR RHODIUM ALKYL AND ARYL COMPLEXES

# publications[].label
Progress in the catalytic reactions of CO2 and epoxides to selectively provide cyclic or polymeric carbonates

# publications[].label
Cis-NiN2S2 metallodithiolates as mono- and bidentate S-donors to gold (I)

# publications[].label
Crystal structures of aryloxide complexes of zinc embracing sodium aryl group interactions: Na[Zn(2,6-diphenylphenoxide)(3)(H2O)] and Na[Zn-2(2,6-diisopropylphenoxide)(4)Cl]center dot 3THF

# publications[].label
Zwitterionic Alternating Polymerization to Generate Semicrystalline and Recyclable Cyclic Polythiourethanes.

# publications[].label
Studies of the carbon dioxide and epoxide coupling reaction in the presence of fluorinated manganese(III) acacen complexes: kinetics of epoxide ring-opening.

# publications[].label
INOR 541-Construction of polymetallic paddlewheel complexes from (N2S2)Ni and (N2S2)Fe(NO) paddles and M-M axles: A tribute to F. Albert Cotton, Alfred Werner and New Orleans

# publications[].label
PHOTOCHEMICAL SUBSTITUTION-REACTION OF SUBSTITUTED GROUP VI B CARBONYLS WITH CO-13

# publications[].label
Relative basicities of cyclic ethers and esters. Chemistry of importance to ring-opening co- and terpolymerization reactions

# publications[].label
DETAILED ANALYSIS OF CO STRETCHING VIBRATIONS IN AXIAL AND EQUATORIAL SUBSTITUTED IRON TETRACARBONYL COMPOUNDS

# publications[].label
INVESTIGATIONS INTO THE STERIC INFLUENCES ON THE REACTION-MECHANISM OF CO2 INSERTION INTO METAL OXYGEN BONDS - COS ACTIVATION AS A MODEL FOR CO2

# publications[].label
(Salen)Co(II)/n-Bu4NX Catalysts for the Coupling of CO2 and Oxetane: Selectivity for Cyclic Carbonate Formation in the Production of Poly(trimethylene carbonate)

# publications[].label
SOLUTION STRUCTURE AND REACTIVITY OF HYDRIDO-IRON TETRACARBONYL ANION, [HFE(CO)4]-

# publications[].label
Approach for Introducing a Single Metal Complex into a Polymer Chain: Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes

# publications[].label
THE ORGANOMETALLIC CHEMISTRY OF CARBON-DIOXIDE PERTINENT TO CATALYSIS

# publications[].label
Construction of Versatile and Functional Nanostructures Derived from CO2 -based Polycarbonates.

# publications[].label
INSERTION OF CARBON-DIOXIDE INTO METAL ALKOXIDE BONDS - SYNTHESIS AND STRUCTURE OF TUNGSTEN TETRACARBONYL CARBONATE

# publications[].label
STRUCTURAL AND REACTIVITY STUDIES OF A CYANOACETIC ACID-DERIVATIVE OF TUNGSTEN PENTACARBONYL - X-RAY STRUCTURE OF W(CO)5NCCH2COOH

# publications[].label
CATALYTIC DECARBOXYLATION OF CYANOACETIC ACID BY ANIONIC TUNGSTEN(0) COMPLEXES

# publications[].label
Hydrophilic polycarbonates derived from coupling of cyclohexadiene and CO2 utilizing metal salen catalysts

# publications[].label
REACTIONS OF TRANSITION METAL CARBONYLS WITH ORGANOLITHIUM COMPOUNDS .2. PREDICTION OF NUCLEOPHILIC ATTACK AT CARBON AND RESULTING STEREOCHEMISTRY

# publications[].label
Highly Selective and Reactive (salan)CrCl Catalyst for the Copolymerization and Block Copolymerization of Epoxides with Carbon Dioxide

# publications[].label
Facile synthesis of polycarbonates from biomass-based eugenol: catalyst optimization for selective copolymerization of CO 2 and eugenol to achieve polycarbonates

# publications[].label
Paramagnetic transition metal ions in N2S2 coordination

# publications[].label
Aluminum salen complexes and tetrabutylammonium salts: a binary catalytic system for production of polycarbonates from CO2 and cyclohexene oxide.

# publications[].label
INOR 145-(Tetramethyltetraazaannulene)chromium chloride: A highly active catalyst for the copolymerization of epoxides and carbon dioxide

# publications[].label
HOMOGENEOUS CATALYSIS OF METHYL FORMATE PRODUCTION FROM CARBON-MONOXIDE AND METHANOL IN THE PRESENCE OF METAL-CARBONYL CATALYSTS

# publications[].label
TEMPO Containing Radical Polymonothiocarbonate Polymers with Regio and StereoRegularities: Synthesis, Characterization, and Electrical Conductivity Studies

# publications[].label
SELECTIVE HOMOGENEOUS PRODUCTION OF ALKYL FORMATE FROM CO AND ALCOHOL USING METAL-CARBONYL ALKOXIDE CATALYST SYSTEMS

# publications[].label
ELECTRONIC AND STERIC CONTROL OF REACTIONS OF BENZYLMAGNESIUM CHLORIDE WITH SUBSTITUTED METAL-CARBONYLS

# publications[].label
The reduction of group 10 metals in the presence of 1,3,5-triaza-7-phosphaadamantane (PTA) and water.

# publications[].label
Perfectly alternating copolymerization of CO2 and epichlorohydrin using cobalt(III)-based catalyst systems.

# publications[].label
Mechanistic aspects of the copolymerization of CO2 and epoxides by soluble zinc bis(phenoxide) catalysts as revealed by their cadmium analogues

# publications[].label
Randomly Distributed Sulfur Atoms in the Main Chains of CO2 -Based Polycarbonates: Enhanced Optical Properties.

# publications[].label
STERIC CONTRIBUTIONS TO THE SOLUTION DYNAMICS INVOLVING PHOSPHORUS LIGAND DISSOCIATION IN SUBSTITUTED DERIVATIVES OF MOLYBDENUM HEXACARBONYL

# publications[].label
Catalysis of carbon dioxide and oxetanes to produce aliphatic polycarbonates

# publications[].label
CYCLOHEPTATRIENE CHROMIUM TRICARBONYL EXCHANGE-REACTIONS WITH ARENES - KINETICS AND MECHANISMS

# publications[].label
Mixed metal cyanide complexes derived from the CpCo(CN)(3)over-bar anion

# publications[].label
Resolving the Roles of Dissimilar Irons in a Proton Reduction Electrocatalyst: [(NO)Fe(N2S2)Fe(NO)(2)](+) and Its Reduced Analogue

# publications[].label
Bis 2,6-difluorophenoxide dimeric complexes of zinc and cadmium and their phosphine adducts: Lessons learned relative to carbon dioxide/cyclohexene oxide alternating copolymerization processes catalyzed by zinc phenoxides

# publications[].label
Amphiphilic Polycarbonate Micellar Rhenium Catalysts for Efficient Photocatalytic CO2 Reduction in Aqueous Media.

# publications[].label
Responses of the Fe(CN)(2)(CO) unit to electronic changes as related to its role in [NiFe]hydrogenase

# publications[].label
Synthesis of terpyridine-containing polycarbonates with post polymerization providing water-soluble and micellar polymers and their metal complexes

# publications[].label
Structural Diversity in Monomeric Cadmium Phenoxides.

# publications[].label
Biometal derivatives as catalysts for the ring-opening polymerization of trimethylene carbonate. Optimization of the Ca(II) salen catalyst system

# publications[].label
Explorations into the sustainable synthesis of cyclic and polymeric carbonates and thiocarbonates from eugenol-derived monomers and their reactions with CO2, COS, or CS2

# publications[].label
Synthesis and structures of (dialkylamino)ethylcyclopentadienyl derivatives of zinc

# publications[].label
CARBON-MONOXIDE SUBSTITUTIONAL PROCESSES IN TETRANUCLEAR COBALT CARBONYL PHOSPHINE DERIVATIVES

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF POLYNUCLEAR CHROMIUM CARBONYL TETRAANIONS

# publications[].label
Investigation into the coupling of cyclohexene oxide and carbon disulfide catalyzed by Cr(salen) Cl

# publications[].label
INOR 622-Computational explorations of M(N2S2) [M = Ni, Cu, Zn] complexes as models for Acetyl Coenzyme A Synthase

# publications[].label
Determination of the binding parameters of epoxide substrates to Fe/Cd double-metal cyanide complexes

# publications[].label
SYNTHESIS, SPECTRAL PROPERTIES, AND REACTIONS OF MANGANESE AND RHENIUM PENTACARBONYL PHOSPHINE AND PHOSPHITE CATION DERIVATIVES AND RELATED COMPLEXES

# publications[].label
INFRARED AND KINETIC STUDIES OF GROUP-VI METAL PENTACARBONYL AMINE COMPOUNDS

# publications[].label
The reaction of electrophiles with models of iron-iron hydrogenase: A switch in regioselectivity

# publications[].label
Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes

# publications[].label
Binucleating coordination of N,N '-ethylenebis(salicylideneamine) (H(2)salen) to low-valent group 6 carbonyl complexes

# publications[].label
CHROMIUM, MOLYBDENUM, AND TUNGSTEN ANNUAL SURVEY COVERING THE YEAR 1976

# publications[].label
Personal Adventures in the Synthesis of Copolymers from Carbon Dioxide and Cyclic Ethers

# publications[].label
Amphiphilic Polycarbonate Micellar Rhenium Catalysts for Efficient Photocatalytic CO2 Reduction in Aqueous Media

# publications[].label
Ligand Displacement from TpMn(CO)(2)L Complexes: A Large Rate Enhancement in Comparison to the CpMn(CO)(2)L Analogues

# publications[].label
Base initiated depolymerization of polycarbonates to epoxide and carbon dioxide co-monomers: a computational study

# publications[].label
Intermolecular hydrogen-bonding in the solid-state structure of CpFe(CN)(2)(PTAH) - Structural and spectral comparisons with its [K][CpFe(CN)(2)PTA] salt

# publications[].label
Sustainable synthesis of CO2-derived polycarbonates from d-xylose

# publications[].label
NUCLEOPHILIC-ADDITION OF A WATER-SOLUBLE PHOSPHINE TO ALDEHYDES - ISOLATION OF (1-HYDROXYALKYL)PHOSPHONIUM SALTS AND THE CRYSTAL-STRUCTURE OF THE (1-METHOXY-1-BENZYL)-(M-SULFONATOPHENYL)DIPHENYLPHOSPHONIUM SALT

# publications[].label
Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides by Metal-Free Lewis Pairs.

# publications[].label
STEREOSPECIFIC LABELING OF SUBSTITUTED METAL-CARBONYL DERIVATIVES WITH CO-13 AND CO-18

# publications[].label
LENGTH OF A TUNGSTEN-PHOSPHINE BOND FREE OF EXCESSIVE STERIC INTERACTIONS - CRYSTAL-STRUCTURE OF W(CO)5P(CH3)3

# publications[].label
Mechanistic Study of Regio-Defects in the Copolymerization of Propylene Oxide/Carbonyl Sulfide Catalyzed by (Salen)CrX Complexes

# publications[].label
Requirements for functional models of the iron hydrogenase active site: D2/H2O exchange activity in ((mu-SMe)(mu-pdt)[Fe(CO)2(PMe3)]2+)[BF4-].

# publications[].label
Water Splitting Using Synthetic Functional Models of [Fe-Fe]-Hydrogenase: Thermodynamic and Kinetic Role of the Bridge Head Nitrogen Atom

# publications[].label
WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .5. THE REGIOSELECTIVE CATALYTIC-HYDROGENATION OF UNSATURATED ALDEHYDES TO SATURATED ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEXES OF RHODIUM

# publications[].label
Development of metal dithiolate complexes as bidentate ligands for organometallic chemistry inspired by acetyl coenzyme A synthase.

# publications[].label
Plastics recycling: Monomer regenerations of polycarbonates made from CO2 and oxiranes

# publications[].label
Synthesis and structural characterization of iron(III) salen complexes possessing appended anionic oxygen donor ligands

# publications[].label
MULTINUCLEAR METAL-CARBONYL ALKOXIDE AND ARYLOXIDE DERIVATIVES AS MODELS FOR METAL-CARBONYLS ADSORBED ON METAL-OXIDE SUPPORTS

# publications[].label
Ring-opening polymerization of cyclic esters and trimethylene carbonate catalyzed by aluminum half-salen complexes.

# publications[].label
KINETICS OF THERMAL DECOMPOSITION AND SUBSTITUTION REACTIONS OF MOLYBDENUM PENTACARBONYL AMINE COMPOUNDS

# publications[].label
STEREOSPECIFIC INTRODUCTION OF CARBON-MONOXIDE INTO METAL-CARBONYL CHELATE COMPLEXES

# publications[].label
Polymers from Carbon Dioxide: Polycarbonates, Polythiocarbonates, and Polyurethanes

# publications[].label
Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC)

# publications[].label
The synthesis of CO2-based polycarbonates with functionalities

# publications[].label
A concise review of computational studies of the carbon dioxide-epoxide copolymerization reactions

# publications[].label
Chain transfer agents utilized in epoxide and CO2 copolymerization processes

# publications[].label
CATION-ANION INTERACTION IN THE [NA-KRYPTOFIX-221][W(CO)5O2CH] DERIVATIVE AND ITS RELEVANCE IN CARBON-DIOXIDE REDUCTION PROCESSES

# publications[].label
INOR 803-The interactions of zinc finger models and exogenous metal complexes: Thiolate bridging and metal exchange

# publications[].label
Ring-opening polymerization of trimethylene carbonate using aluminum(III) and Tin(IV) salen chloride catalysts (vol 38, pg 5406, 2005)

# publications[].label
Directed Self-Assembly of Polystyrene-b-poly(propylene carbonate) on Chemical Patterns via Thermal Annealing for Next Generation Lithography.

# publications[].label
COMPARATIVE REACTIVITIES OF ANIONIC GROUP-6 ALKYL, SILYL, AND STANNYL PENTACARBONYL METALATES TOWARD CARBON-DIOXIDE AND SULFUR-DIOXIDE - CRYSTAL-STRUCTURE OF [PPN][W(CO)5SI(CH3)3]

# publications[].label
ANIONIC GROUP-6 HYDRIDES AND CARBOXYLATES AS HOMOGENEOUS CATALYSTS FOR REDUCTION OF ALDEHYDES AND KETONES

# publications[].label
THE X-RAY STRUCTURAL CHARACTERIZATION OF A TETRAMERIC BINUCLEAR BIS(MU-OXO) MOLYBDENUM(V) COMPOUND BRIDGED BY METHOXIDE LIGANDS

# publications[].label
KINETIC STUDIES OF THERMAL-DECOMPOSITION AND SUBSTITUTION-REACTIONS OF CIS-MO(CO)4[P(C6H5)3](AMINE) COMPOUNDS - COMPETITIVE STUDY OF LEWIS BASES FOR INTERMEDIATE [MO(CO)4P(C6H5)3]

# publications[].label
When iron meets nitric oxide: Good chemistry, intriguing biology

# publications[].label
A one-pot synthesis of a triblock copolymer from propylene oxide/carbon dioxide and lactide: intermediacy of polyol initiators.

# publications[].label
PHOTOCHEMICAL SUBSTITUTION REACTIONS OF SUBSTITUTED GROUP VI METAL-CARBONYLS

# publications[].label
REACTIONS OF CRYPTAND-SOLUBILIZED NASH IN APROTIC-SOLVENTS WITH THE GROUP-6B METAL HEXACARBONYLS - X-RAY STRUCTURAL-ANALYSIS AND LIGAND LABILITY STUDIES OF THE ISOLATED M(CO)5SH- ANIONS

# publications[].label
MECHANISTIC STUDIES FOR THE DISPLACEMENT OF NITRILES FROM TUNGSTEN PENTACARBONYL

# publications[].label
A CONVENIENT ROUTE TO C-13-ENRICHED TRIRUTHENIUM DODECACARBONYL - CHEMISTRY RELEVANT TO METHYL FORMATE PRODUCTION FROM CARBON-MONOXIDE AND METHANOL

# publications[].label
Enabling New Approaches: Recent Advances in Processing Aliphatic PolycarbonateBased Materials

# publications[].label
Sythesis and characterization of a series of dinitrosyl iron complexes

# publications[].label
ZERO-VALENT GROUP-6 METAL CENTERS CONTAINING PI-DONATING LIGANDS

# publications[].label
REDOX PROMOTED SULFUR-OXYGEN BOND-CLEAVAGE IN NICKEL(II) SULFENATE

# publications[].label
Kinetics and thermodynamics of the decarboxylation of 1,2-glycerol carbonate to produce glycidol: computational insights

# publications[].label
CHEMICAL AND X-RAY STRUCTURAL STUDIES ON THE (ACETATO)PENTACARBONYLMETALATES AND (TRIFLUOROACETATO)PENTACARBONYLMETALATES OF CHROMIUM AND MOLYBDENUM

# publications[].label
Ring-Opening Polymerization of L-Lactide and epsilon-Caprolactone Utilizing Biocompatible Zinc Catalysts. Random Copolymerization of L-Lactide and epsilon-Caprolactone

# publications[].label
Mechanism of CO Displacement from an Unusually Labile Rhenium Complex: An Experimental and Theoretical Investigation

# publications[].label
Copolymerization of Epoxides and CO2: Polymer Chemistry for Incorporation in Undergraduate Inorganic Chemistry

# publications[].label
Base-promoted tautomerization of imidazoles to N-heterocyclic carbenes (NHCs): Via a dinitrosyl iron scaffold

# publications[].label
Organometallic and coordination chemistry of orotic acid metal complexes.

# publications[].label
SYNTHESES AND STRUCTURES OF EPOXIDE ADDUCTS OF SOLUBLE CADMIUM(II) CARBOXYLATES - MODELS FOR THE INITIATION PROCESS IN EPOXIDE CO2 COUPLING REACTIONS

# publications[].label
SYNTHESIS AND STRUCTURE OF 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE COMPLEXES OF COPPER(I) ACETATE. CATALYSTS FOR THE DECARBOXYLATION OF CARBOXYLIC ACIDS

# publications[].label
Investigation of CO2 insertion into the tungsten-nitrogen bond of the [W(CO)(4)(NHC5H4N)](-) anion.

# publications[].label
Chemistry of carbon dioxide relevant to its utilization: a personal perspective.

# publications[].label
Catalyst-Free Construction of Versatile and Functional CS2-Based Polythioureas: Characteristics from Self-Healing to Heavy Metal Absorption

# publications[].label
REACTIONS OF PHENYLACETYLMANGANESEPENTACARBONYL WITH PHOSPHINE AND PHOSPHITE LIGANDS

# publications[].label
POLY 302-Production of aliphatic polycarbonates from carbon dioxide and oxiranes and oxetanes

# publications[].label
Solution P-31 and Cd-113 NMR studies of phosphine adducts of monomeric cadmium (bisphenoxide) complexes and the solid-state structures of (2,6-di-tert-butylphenoxide)(2)Cd(PCy3) and (2,6-di-tert-butylphenoxide)(2)Cd(PMe3)(2)

# publications[].label
SYNTHESIS AND REACTIVITY OF WATER-SOLUBLE IRIDIUM COMPLEXES ANALOGOUS TO VASKA COMPOUND

# publications[].label
STEREOCHEMICAL STUDIES OF THE CARBON-DIOXIDE INSERTION REACTIONS INTO THE TUNGSTEN ALKYL BOND

# publications[].label
EPR/ENDOR and DFT investigations of bioinspired [FeFe] hydrogenase model compounds

# publications[].publisher
International Union of Crystallography (IUCr)

# publications[].label
Probing the mechanistic aspects of the chromium salen catalyzed carbon dioxide/epoxide copolymerization process using in situ ATR/FTIR

# publications[].label
BIPHASIC ALDEHYDE HYDROGENATION USING A WATER-SOLUBLE RUTHENIUM CATALYST

# publications[].label
Diamond-shaped heterometallic complexes of Iron(II) and copper(I) bridged by cyanide groups containing monodentate or bidentate phosphanes bound to copper(I), including an alternative structure based on the nature of the bidentate phosphane ligand

# publications[].label
SEPARATION OF PURE LATERAL AND DIAGONAL ISOMERS OF CYCLOPENTADIENYLDIBROMODICARBONYLRHENIUM

# publications[].label
CHROMIUM, MOLYBDENUM AND TUNGSTEN - ANNUAL SURVEY COVERING YEAR 1971

# publications[].label
The propensity of alkoxide and aryloxide derivatives of tungsten carbonyls to aggregate in solution. Synthesis and X-ray structures of dinuclear, trinuclear and tetranuclear complexes derived from the MeOW(CO)(5)(-) anion

# publications[].label
REVERSIBLE DECARBOXYLATION OF PHOSPHINE DERIVATIVES OF CU(I) CYANOACETATE - MECHANISTIC ASPECTS GERMANE TO CATALYTIC DECARBOXYLATION OF CARBOXYLIC-ACIDS

# publications[].label
Ring-opening polymerization of cyclic monomers by biocompatible metal complexes. Production of poly(lactide), polycarbonates, and their copolymers

# publications[].label
Dramatic Behavioral Differences of the Copolymerization Reactions of 1,4-Cyclohexadiene and 1,3-Cyclohexadiene Oxides with Carbon Dioxide

# publications[].label
The copolymerization of carbon dioxide and [2-(3,4-epoxycyclohexyl)ethyl]trimethoxysilane catalyzed by (salen)CrCl. Formation of a CO2 soluble polycarbonate.

# publications[].label
Mechanistic insight into the initiation step of the coupling reaction of oxetane or epoxides and CO2 catalyzed by (salen)CrX complexes.

# publications[].label
Thermodynamics of the Carbon Dioxide-Epoxide Copolymerization and Kinetics of the Metal-Free Degradation: A Computational Study

# publications[].label
Ladder-type 1D coordination polymer of Dy( iii ): synthesis and investigation of magnetic behaviour

# publications[].label
AMINO AND PHOSPHINO DERIVATIVES OF COPPER(I) ACETATE - CATALYTIC DECARBOXYLATION OF NCCH2CO2H AND HO2CCH2CO2H

# publications[].label
Kinetic study of the insertion and deinsertion of carbon dioxide into fac-(CO)(3)(dppe)MnOR derivatives

# publications[].label
ZINC CARBOXYLATES AS DECARBOXYLATION CATALYSTS

# publications[].label
STEREOSPECIFIC INCORPORATION OF O-18 INTO MANGANESE AND RHENIUM PENTACARBONYL DERIVATIVES VIA EXCHANGE-REACTIONS WITH H218O

# publications[].label
PREPARATION AND SOLID-STATE STRUCTURE OF A NOVEL CARBOXYLATE DERIVATIVE OF COPPER(I), (PH3P)2CU(O2CCH2CN)2H

# publications[].label
Copolymerization of CO2 and dihydronaphthalene oxide with Cr(III) and Co(III) catalysts

# publications[].label
Water-soluble organometallic compounds. 7. Further studies of 1,3,5-triaza-7-phosphaadamantane derivatives of group 10 metals, including metal carbonyls and hydrides

# publications[].label
Salen Metal Complexes as Catalysts for the Synthesis of Polycarbonates from Cyclic Ethers and Carbon Dioxide

# publications[].label
INOR 521-Immobilized metallodithiolate ligand supports for construction of bioinorganic model complexes

# publications[].label
Mechanism of CO displacement from an unusually labile rhenium complex: an experimental and theoretical investigation.

# publications[].label
INTENSITIES OF CO STRETCHING MODES IN INFRARED SPECTRA OF ADSORBED CO AND METAL CARBONYLS

# publications[].label
Pressure dependence of the carbon dioxide/cyclohexene oxide coupling reaction catalyzed by chromium salen complexes. Optimization of the comonomer-alternating enchainment pathway

# publications[].label
CHROMIUM, MOLYBDENUM AND TUNGSTEN - ANNUAL SURVEY COVERING YEAR 1972

# publications[].label
INFRARED INTENSITIES AND CALCULATION OF INFRARED BAND SHAPES OF NU(CO) AND NU(C=C) VIBRATIONAL MODES IN GROUP-6B - (NORBORNADIENE)TETRACARBONYLMETAL DERIVATIVES

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Evaluation of manganese (III) Schiff base complexes for the copolymerization of carbon dioxide and cyclohexene oxide

# publications[].label
Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligands.

# publications[].label
Highly Selective Synthesis of CO2 Copolymer from Styrene Oxide

# publications[].label
STERIC CONTRIBUTIONS TO THE SOLID-STATE STRUCTURES OF BIS(PHOSPHINE) DERIVATIVES OF MOLYBDENUM CARBONYL - X-RAY STRUCTURAL STUDIES OF CIS-MO(CO)4(PPH3-OMEO)2, CIS-MO(CO)4PPH3-1ME1)2, CIS-MO(CO)4(PPH3-2ME2)2

# publications[].label
Tagging alcohols onto polycarbonates derived from carbon dioxide and 3,4-epoxy-tert-butylbutanoate

# publications[].label
METHANATION OF CARBON-DIOXIDE BY ALUMINA-SUPPORTED TRIRUTHENIUM, TETRARUTHENIUM, AND HEXARUTHENIUM CLUSTERS

# publications[].label
LIGAND-SUBSTITUTION PROCESSES IN TETRANUCLEAR CARBONYL CLUSTERS .5. A KINETIC AND INFRARED INVESTIGATION OF 13CO INCORPORATION INTO CO4(CO)9(MU-CO)3 AND ITS MONOSUBSTITUTED DERIVATIVES

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THE EFFECT OF PHOSPHONIUM SALT FORMATION ON THE KINETICS OF HOMOGENEOUS HYDROGENATIONS IN WATER UTILIZING A RHODIUM META-SULFONATOPHENYL-DIPHENYLPHOSPHINE COMPLEX

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PHOTOCHEMICALLY ENHANCED CARBON CARBON BOND-FORMING REACTION BETWEEN CS2 AND [W(CO)5CH3]- - X-RAY STRUCTURE OF [PPN][W(CO)4(ETA-2-S2CCH3)]

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CARBON-MONOXIDE LIGAND SUBSTITUTIONAL PROCESSES INVOLVING ANIONIC GROUP 6 METAL CARBOXYLATES AND THEIR RELEVANCE TO DECARBOXYLATION MECHANISMS

# publications[].label
Sustainable Synthesis of CO2-Derived Polycarbonates from the Natural Product, Eugenol: Terpolymerization with Propylene Oxide

# publications[].label
Copolymerization of epoxides and carbon dioxide. Evidence supporting the lack of dual catalysis at a single metal site.

# publications[].label
CORRELATION BETWEEN STRETCHING FREQUENCY AND ABSOLUTE INFRARED INTENSITY OF DINITROGEN LIGAND IN ISOELECTRONIC TRANSITION-METAL COMPOUNDS

# publications[].label
EVIDENCE FOR HYDROGEN-BONDED INTERMEDIATES IN AMINE SUBSTITUTION-REACTIONS INVOLVING GROUP 6B METAL PENTACARBONYL AMINE DERIVATIVES WITH PHOSPHINES

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Synthesis and structural characterization of double metal cyanides of iron and zinc: catalyst precursors for the copolymerization of carbon dioxide and epoxides.

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF SULFUR-CAPPED TRINUCLEAR GROUP-6B METAL-CLUSTERS

# publications[].label
Calcium complexes for stereoregular ring-opening polymerization of lactide

# publications[].label
Depolymerization of Polycarbonates Derived from Carbon Dioxide and Epoxides to Provide Cyclic Carbonates. A Kinetic Study

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR CARBONYL CLUSTERS .4. MOLECULAR-STRUCTURE AND REACTIVITY OF IR4(CO)8[P(CH3)3]4

# publications[].label
FORMATO-DERIVATIVES AND THIOFORMATO-DERIVATIVES OF THE GROUP-6B METAL-CARBONYLS - CHEMISTRY RELEVANT TO CATALYSIS OF THE WATER-GAS SHIFT REACTION

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WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .3. KINETIC INVESTIGATIONS OF DISSOCIATIVE PHOSPHINE SUBSTITUTION PROCESSES INVOLVING WATER-SOLUBLE GROUP-6 METAL DERIVATIVES IN MISCIBLE AQUEOUS ORGANIC MEDIA

# publications[].label
Investigations on the use of aluminum(III)salen complexes as catalysts for the copolymerization of Co-2 and epoxides.

# publications[].label
Synthesis and physical characterization of poly(cyclohexane carbonate), synthesized from CO2 and cyclohexene oxide

# publications[].label
Water-soluble organometallic compounds. 9. Catalytic hydrogenation and selective isomerization of olefins by water-soluble analogues of Vaska's complex

# publications[].label
Tandem metal-coordination copolymerization and organocatalytic ring-opening polymerization via water to synthesize diblock copolymers of styrene oxide/CO2 and lactide.

# publications[].label
INFRARED INTENSITIES OF CARBONYL STRETCHING MODES AND ELECTRONIC SPECTRA OF SUBSTITUTED MOLYBDENUM CARBONYLS

# publications[].label
Metal salen derivatives as catalysts for the alternating copolymerization of oxetanes and carbon dioxide to afford polycarbonates.

# publications[].label
Structural and Spectroscopic Studies of 16-Electron, Unsaturated Derivatives of Low-Valent, Group 6 Carbonyl Complexes Containing pi-Donor Ligands.

# publications[].label
Critical precursors to biomimetics of the diiron hydrogenase enzyme active site: Carbon monoxide mobilized 2Fe2S carbonyl clusters

# publications[].label
PHOTOCHEMICAL SUBSTITUTION-REACTIONS OF GROUP-6B METAL TETRACARBONYL NORBORNADIENE COMPLEXES WITH (CO)-C-13, KINETICS OF SUBSEQUENT THERMAL REARRANGEMENTS IN STEREOSPECIFICALLY LABELED SPECIES, AND RELATIONSHIP OF THESE RESULTS TO PHOTOINDUCED HYDROGENATION PROCESS

# publications[].label
An Efficient Method of Depolymerization of Poly(cyclopentene carbonate) to Its Comonomers: Cyclopentene Oxide and Carbon Dioxide

# publications[].label
Displacement Kinetics of eta(2)-Bound Furan and 2,3-Dihydrofuran from Mn and Cr Centers: Evidence for the Partial Dearomatization of the Furan Ligand

# publications[].label
FURTHER-STUDIES OF THE UNUSUAL NATURE OF TRIS(BETA-CYANOETHYL)PHOSPHINE - STRUCTURES OF THE PHOSPHINE AND THE PHOSPHINE OXIDE

# publications[].label
SOLVENT EFFECTS ON THE OXYGENATION OF NI-BOUND THIOLATES

# publications[].label
Recent advances in the synthesis of copolymers from oxiranes and carbon dioxide

# publications[].label
Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by pi-Donating Amido Ligands.

# publications[].label
A TOPICAL RESEARCH APPROACH TO THE INORGANIC SYNTHESIS LABORATORY

# publications[].label
Teaching polymer chemistry in green chemistry: An inorganic approach

# publications[].label
Cd-113 NMR determination of the binding parameters of alicyclic epoxides to [hydrotris(3-phenylpyrazol-1-yl)borate]Cd(II) acetate

# publications[].label
Synthesis of CO2-Based Block Copolymers via Chain Transfer Polymerization Using Macroinitiators: Activity, Blocking Efficiency, and Nanostructure

# publications[].label
Further studies related to the copolymerization of cyclohexene oxide and carbon dioxide catalyzed by chromium Schiff base complexes. Crystal structures of two mu-hydroxo-bridged Schiff base dimers of chromium(III)

# publications[].label
Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/Thiolate Dinitrosyl Iron Complex (DNIC)

# publications[].label
MECHANISTIC ASPECTS OF DECARBOXYLATION REACTIONS OF GROUP-10 (PCY3)2M(H)O2CH DERIVATIVES

# publications[].label
Thermal and photochemical reactivity of manganese tricarbonyl and tetracarbonyl complexes with a bulky diazabutadiene ligand.

# publications[].label
X-Ray crystal structures of five-coordinate (salen)MnN3 derivatives and their binding abilities towards epoxides: chemistry relevant to the epoxide-CO2 copolymerization process.

# publications[].label
INFRARED INTENSITIES OF MOLECULAR NITROGEN AND CARBONYL STRETCHING VIBRATIONS IN IRIDIUM(I) COMPLEXES

# publications[].label
Diamond-shaped heterometallic complexes of Iron(II) and Copper(I) bridged by cyanide groups

# publications[].label
CHEMICAL AND STRUCTURAL CHARACTERIZATION OF W(CO)5OPPH2NPPH3 - A NOVEL COMPLEX CONTAINING A PHOSPHINE OXIDE LIGAND DERIVED FROM THE BIS(TRIPHENYLPHOSPHINE)NITROGEN(1+) CATION

# publications[].label
CYANOMETAL-SUBSTITUTED DERIVATIVES OF THE Fe(4)S(4) CLUSTER CORE

# publications[].label
Axial Carbonate-Bridged Dy2 Complexes Having Rigid N3O2 Equatorial Planes: Stepwise Boosting and Tuning of the Zero-Field SMM Behavior

# publications[].label
CARBON-MONOXIDE LIGAND SUBSTITUTIONAL PROCESSES INVOLVING ANIONIC GROUP-6 METAL CARBOXYLATES AND THEIR RELEVANCE TO DECARBOXYLATION MECHANISMS

# publications[].label
WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .2. CATALYTIC-HYDROGENATION OF ALDEHYDES AND OLEFINS BY NEW WATER-SOLUBLE 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEXES OF RUTHENIUM AND RHODIUM

# publications[].label
CARBON-DIOXIDE INSERTION AND DEINSERTION PROCESSES INVOLVING METAL-CARBON BONDS - SOLID-STATE STRUCTURE OF [PPN][W(CO)5CH2CN]

# publications[].label
Facile Synthesis of WellDefined Branched SulfurContaining Copolymers: OnePot Copolymerization of Carbonyl Sulfide and Epoxide

# publications[].label
Cyanide in the hydrogenase enzymes' active sites: A tribute to the detective powers of Albracht, Bagley, and W. Woodward.

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR CARBONYL CLUSTERS .8. REACTIONS OF CO4[(CO)-C-12]12/CO4[(CO)-C13]12 WITH PHOSPHORUS DONOR LIGAND SUBSTITUTION PROCESSES

# publications[].label
Structural characterization of several (CO)(3)(dppp)MnX derivatives, dppp=1,3-bis(diphenylphosphino)propane and X = H, OTs, OC2H5, Cl, Br, or N-3. An assessment of their efficacy for catalyzing the coupling of carbon dioxide and epoxides

# publications[].label
Oxygen atom exchange in rhenium bipyridine and phenanthroline tetracarbonyl cations with (H2O)-O-18

# publications[].label
Synthesis of bifunctional catalyst and its application in CO2/epoxide copolymerization

# publications[].label
ANIONIC GROUP-6 HYDRIDES AND CARBOXYLATES AS HOMOGENEOUS CATALYSTS FOR REDUCTION OF ALDEHYDES AND KETONES

# publications[].label
INOR 83-Studies related to the copolymerization of oxetane and carbon dioxide catalyzed by (salen)Cr(X) complexes: Insights into the initiation step of the coupling reaction

# publications[].label
Role of the cocatalyst in the copolymerization of CO2 and cyclohexene oxide utilizing chromium salen complexes.

# publications[].label
Time resolved infrared spectroscopy: kinetic studies of weakly binding ligands in an iron-iron hydrogenase model compound.

# publications[].label
INFRARED INTENSITY MEASUREMENTS OF PT-H STRETCHING VIBRATION IN PT(II) COMPLEXES AND THEIR RELATIONSHIP TO SIMILAR MEASUREMENTS FOR HYDROGEN CHEMISORBED ON PLATINUM

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A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide

# publications[].label
LACK OF INTRAMOLECULAR CARBONYL LIGAND REARRANGEMENT IN STEREOSPECIFICALLY CO-13 LABELED (DIAMINE) MOLYBDENUM TETRACARBONYL DERIVATIVES

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INOR 711-Synthesis, molecular structure, and characterization of an S=3/2 trigonal paddlewheel complex: {[(C9H18N2S2)Fe(NO)]Ag-2}(BF4)(2)

# publications[].label
SOLID-STATE AND SOLUTION STRUCTURE OF (BPY)CUCO(CO)4 (BPY = 2,2'-BIPYRIDINE)

# publications[].label
CATALYTIC CARBON-DIOXIDE METHANATION BY ALUMINA-SUPPORTED MONONUCLEAR AND POLYNUCLEAR RUTHENIUM CARBONYLS

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ORIGIN OF THE STRUCTURE IN M-H-M VIBRATIONAL-MODES OF HW2(CO)10-

# publications[].label
Sequestering CO2 for Short-Term Storage in MOFs: Copolymer Synthesis with Oxiranes

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CARBON-DIOXIDE INSERTION PROCESSES INVOLVING METAL-CARBON BONDS - SOLID-STATE AND SOLUTION STRUCTURE OF [NA(18-CROWN-6)][W(CO)5CH3]

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CYLINDRICAL INTERNAL-REFLECTION FOR THE STUDY OF ORGANOMETALLIC REACTIONS UNDER HIGH-PRESSURE OR LOW-TEMPERATURES

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Coupling of epoxides and carbon dioxide in the presence of homogeneous transition-metal catalysts. Production of polycabonates vs cyclic carbonates

# publications[].label
Placing Single-Metal Complexes into the Backbone of CO2-Based Polycarbonate Chains, Construction of Nanostructures for Prospective Micellar Catalysis

# publications[].label
Studies of the coupling reactions of carbonyl sulfide (COS) and epoxides. Formation of cyclic- and poly(thiocarbonates)

# publications[].label
Ambidentate thiocyanate ligand in dinitrosyl iron complexes

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THE REACTION OF (CY3P)2NI(H)(CH3) WITH CARBON-DIOXIDE - FORMATION OF A HYDRIDONICKEL FORMATE COMPLEX, HNI(O2CH)(CY3P)2

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Investigation into the mechanism of the copolymerization of propylene oxide and CO2 using (salen)CRN3 catalysts.

# publications[].label
REACTIONS OF MO2CL4(PR3)4 AND W2CL4(PR3)4 WITH CARBON-MONOXIDE

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SYNTHESIS AND STRUCTURE OF SOME ANIONIC PI-ALLYL TUNGSTEN(II) CARBONYL DIMERS

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Comparative kinetic studies of the copolymerization of cyclohexene oxide and propylene oxide with carbon dioxide in the presence of chromium salen derivatives. In situ FTIR measurements of copolymer vs cyclic carbonate production.

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PHOTOCHEMICAL REACTIONS OF TRANSITION-METAL DINITROGEN COMPOUNDS IN PRESENCE OF CARBON-MONOXIDE

# publications[].label
Electronic and molecular structures of active sites in [FeFe] hydrogenase and biomimetic model complexes

# publications[].label
Terpolymerization of propylene oxide and vinyl oxides with CO2: copolymer cross-linking and surface modification via thiol-ene click chemistry

# publications[].label
STEREOCHEMICAL COURSE OF REACTIONS LEADING TO FORMATION OF MONO-LIGATED (PHENYLACETYL)MANGANESE TETRACARBONYL COMPOUNDS

# publications[].label
An exploration of the coupling reactions of epoxides and carbon dioxide catalyzed by tetramethyltetraazaannulene chromium(III) derivatives: formation of copolymers versus cyclic carbonates.

# publications[].label
PREPARATION OF A STEREOSPECIFICALLY CO-13-LABELED [(MU-H)[MO(CO)5]2]- SPECIES AND ANALYSIS OF ITS CO STRETCHING VIBRATIONAL MODES

# publications[].label
GROUP-6 METAL ARYL-OXIDE AND ALKYLOXIDE COMPLEXES AND THEIR REACTIVITY TOWARD CARBON-DIOXIDE

# publications[].label
Randomly Distributed Sulfur Atoms in the Main Chains of CO2Based Polycarbonates: Enhanced Optical Properties

# publications[].label
Cd (II) bis- and tris(phenoxides) analogous to Zn(II) CO2/epoxide copolymerization catalysts.

# publications[].label
Oxygen/Sulfur Scrambling During the Copolymerization of Cyclopentene Oxide and Carbon Disulfide: Selectivity for Copolymer vs Cyclic [Thio]carbonates

# publications[].label
SYNTHESIS, REACTIVITY, AND X-RAY CRYSTAL-STRUCTURES OF ZERO-VALENT TUNGSTEN CARBONYL ARYLOXIDES

# publications[].label
Sustainable Synthesis of Polycarbonates and Polythiocarbonates from Biomass-Based Eugenol-Furoic Acid-Derived Monomer and CO2 and COS: Computational Insights

# publications[].label
SYNTHESIS AND REACTIVITY OF TUNGSTEN CARBONYL PHENOXIDE COMPLEXES - FORMATION OF METAL CARBONATES VIA INSERTION OF CO2

# publications[].label
Molecular constructs as [FeFe]-H(2)ase enzyme active site: Biomimetics for proton reduction

# publications[].label
STERIC CONTRIBUTIONS TO THE SOLUTION DYNAMICS INVOLVING PHOSPHORUS LIGAND DISSOCIATION IN SUBSTITUTED DERIVATIVES OF MOLYBDENUM HEXACARBONYL

# publications[].label
Carbon dioxide-based functional polycarbonates: Metal catalyzed copolymerization of CO2 and epoxides

# publications[].label
USES OF METAL-CLUSTERS IN HOMOGENEOUS AND HETEROGENEOUS CATALYSIS

# publications[].label
SELECTIVE HOMOGENEOUS PRODUCTION OF ALKYL FORMATE FROM CO AND ALCOHOL USING METAL-CARBONYL ALKOXIDE CATALYST SYSTEMS

# publications[].label
Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination.

# publications[].label
DECARBOXYLATION REACTIONS INVOLVING COPPER(I) COMPLEXES DERIVED FROM CU-CO DIMERS

# publications[].label
Catalytic coupling of carbon dioxide and 2,3-epoxy-1,2,3,4-tetrahydronaphthalene in the presence of a (Salen)(CrCl)-Cl-III derivative

# publications[].label
Synthesis of poly(indene carbonate) from indene oxide and carbon dioxide--a polycarbonate with a rigid backbone.

# publications[].label
Labile Copper (I) Chloride Complexes: Preparation and Handling

# publications[].label
THERMAL ROUTE TO STEREOSPECIFICALLY (CO)-C-13 LABELED GROUP VIB METAL PENTACARBONYL AMINE DERIVATIVES

# publications[].label
A kinetic study of the ring-opening process in tungsten carbonyl complexes containing hemilabile metallodithiolate ligands.

# publications[].label
Use of coordination complexes as catalysts for the synthesis of polycarbonates from CO2 and cyclic ethers

# publications[].label
Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides Coupling Reactions Efficiently Catalyzed by Robust, Recyclable One-Component Aluminum-Salen Complexes

# publications[].label
INOR 590-Metal complexes of siloxy and silane substituted salen ligands for the copolymerization of carbon dioxide and epoxides

# publications[].label
Selectivity origins for the coupling of CO2 and epoxides

# publications[].label
Carboxylic acid functionalized polycarbonates from CO2: A versatile platform for the synthesis of functional polycarbonates

# publications[].label
An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane

# publications[].label
METAL INDUCED TRANSFORMATIONS OF CARBON-DIOXIDE

# publications[].label
Synthesis of carbene ligands from amino acids and attachment to various small-molecule analogs of iron biomolecules

# publications[].label
Ligand substitution from the (eta5-DMP)Mn(CO)2(Solv) [DMP = 2,5-dimethylpyrrole, Solv = solvent] complexes: to ring slip or not to ring slip?

# publications[].label
(Salen)CrIIIX catalysts for the copolymerization of carbon dioxide and epoxides: role of the initiator and cocatalyst.

# publications[].label
HOMOGENEOUS CATALYTIC SYNTHESIS OF ALKYL FORMATES FROM THE REACTION OF ALKYL-HALIDES, CO2 AND H2 IN THE PRESENCE OF ANIONIC GROUP-6 CARBONYL CATALYSTS AND SODIUM-SALTS

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HOMOGENEOUS CATALYTIC SYNTHESIS OF ALKYL FORMATES FROM THE REACTION OF ALKYL-HALIDES, CO2, AND H-2 IN THE PRESENCE OF ANIONIC GROUP-6 CARBONYL CATALYSTS AND SODIUM-SALTS

# publications[].label
Metal salen derivatives as catalysts for the copolymerization of oxetane and carbon dioxide to afford polycarbonates

# publications[].label
NATURE OF INTERMEDIATE PROCREATED IN SUBSTITUTION REACTIONS OF GROUP-VI METAL CARBONYLS

# publications[].label
INFRARED DETERMINATION OF STEREOCHEMISTRY IN METAL-COMPLEXES - DETERMINATION OF SYMMETRY COORDINATES

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ON THE USE OF C-13-C-13 COUPLING IN ESTABLISHING INTRAMOLECULAR VERSUS INTERMOLECULAR CO LIGAND REARRANGEMENT PROCESSES IN METAL-CARBONYL DERIVATIVES

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PHASE-TRANSFER CATALYZED O-18 LABELING STUDIES OF CARBONYL LIGANDS IN NEUTRAL METAL-CARBONYL DERIVATIVES

# publications[].label
CATECHOLATES AS SIGMA-DONATING AND PI-DONATING LIGANDS - THE SYNTHESIS AND STRUCTURE OF (ET4N)2[W(CO)4(O2C6H4)] AND THE 16 ELECTRON ANALOG RESULTING FROM CO DISSOCIATION

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Water-soluble organometallic compounds. 8. Synthesis, spectral properties, and crystal structures of 1,3,5-triaza-7-phosphaadamantane (PTA) derivatives of metal carbonyl clusters: Ru-3(CO)(9)(PTA)(3) and Ir-4(CO)(7)(PTA)(5)

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SYNTHESIS AND REACTIVITY OF LOW-VALENT METAL ALKOXO- OR ALKYLTHIODERIVATIVES - REACTIONS WITH CARBONYL OXIDES AND SULFIDES

# publications[].label
Hyperfine Structure of Monovalent Iron in Hydrogenase Models: Mossbauer and Density Functional Studies

# publications[].label
Design of Betaine Functional Catalyst for Efficient Copolymerization of Oxirane and CO2

# publications[].label
Copolymerization and Cycloaddition Products Derived from Coupling Reactions of 1,2-Epoxy-4-cyclohexene and Carbon Dioxide. Postpolymerization Functionalization via Thiol-Ene Click Reactions

# publications[].label
Water-soluble organometallic compounds. 7. Further studies of 1,3,5-triaza-7-phosphaadamantane derivatives of group 10 metals, including metal carbonyls and hydrides (vol 38, pg 2479, 1999)

# publications[].label
RATIONAL SYNTHESIS OF DINUCLEAR MIXED-VALENCE CU(I)/CU(II) CARBOXYLATE DERIVATIVES - STERIC INFLUENCE OF PHOSPHINE-LIGANDS ON THE STRUCTURES OF THE COMPLEXES

# publications[].label
Tuning the Selectivity of the Oxetane and CO2 Coupling Process Catalyzed by (Salen)CrCl/n-Bu4NX: Cyclic Carbonate Formation vs Aliphatic Polycarbonate Production

# publications[].label
What's new with CO2? Recent advances in its copolymerization with oxiranes

# publications[].label
Mechanistic aspects of the CO-labilizing ability of the glycinate ligands in zero valent chromium and tungsten derivatives.

# publications[].label
Switchable-polarity solvents prepared with a single liquid component.

# publications[].label
Synthesis and characterization of a monocyanide-bridged bimetallic iron(II) and copper(I) complex.

# publications[].label
Investigation into the chelation/dechelation of thiouracilate derivatives of tungsten(0) carbonyl via CO loss and addition.

# publications[].label
Deciphering the mechanism of carbon monoxide induced elimination of disulfide from a dinitrosyl iron complex: Hammett correlations of a series of para substituted (NHC)(SPhX) Fe(NO)(2) compounds

# publications[].label
Bio-mimetic study of novel materials for joint replacements

# publications[].label
REACTION OF IRON PENTACARBONYL WITH OXYGEN-18-ENRICHED HYDROXIDE - DECARBOXYLATION VS OXYGEN-EXCHANGE IN THE [FE(COOH]) INTERMEDIATE

# publications[].label
INFRARED, CONDUCTANCE, AND KINETIC EVIDENCE FOR ALKALI-METAL ION INTERACTIONS WITH DERIVATIVES OF MANGANESE CARBONYLATES

# publications[].label
Ring-opening polymerization of cyclic monomers by complexes derived from biocompatible metals. Production of poly(lactide), poly(trimethylene carbonate), and their copolymers

# publications[].label
Hydrogenase/epoxide-CO2 catalysis: Killing two birds with one cat

# publications[].label
SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF ZEROVALENT TUNGSTEN ARYLOXIDE DIMERS

# publications[].label
RingOpening Polymerization of Renewable SixMembered Cyclic Carbonates. Monomer Synthesis and Catalysis

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF ZEROVALENT GROUP-6 METAL PENTACARBONYL ARYL OXIDE COMPLEXES - REACTIONS WITH CARBON-DIOXIDE

# publications[].label
Syntheses, Structures, and Binding Constants of Cyclic Ether and Thioether Adducts of Soluble Cadmium(II) Carboxylates. Intermediates in the Homopolymerization of Oxiranes and Thiiranes and in Carbon Dioxide Coupling Processes.

# publications[].label
Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether

# publications[].label
STEREOCHEMICAL NONRIGIDITY IN 6-COORDINATE GROUP-6B METAL-CARBONYL DERIVATIVES VIA A NONDISSOCIATIVE PATHWAY

# publications[].label
TEMPO Containing Radical Polymonothiocarbonate Polymers with Regio‐ and Stereo‐Regularities: Synthesis, Characterization, and Electrical Conductivity Studies

# publications[].label
AMINO-ACID DERIVATIVES OF TUNGSTEN CARBONYL - STRUCTURE AND REACTIVITY INVESTIGATIONS OF ZEROVALENT TUNGSTEN GLYCINE DERIVATIVES

# publications[].label
Ring-opening polymerization of lactides catalyzed by natural amino-acid based zinc catalysts.

# publications[].label
THE SYNTHESIS AND X-RAY STRUCTURE OF A PHENOXIDE-BRIDGED HETEROBIMETALLIC ANION, W(CO)5OPH(CR(CO)3)-, AND ITS REACTIVITY WITH CARBON-DIOXIDE AND CARBONYL SULFIDE

# publications[].label
FURTHER-STUDIES ON THE ROLE OF NEIGHBORING GROUP PARTICIPATION IN CO SUBSTITUTION-REACTIONS OF GROUP-6 METAL CARBOXYLATES

# publications[].label
Mechanistic studies of the copolymerization reaction of aziridines and carbon monoxide to produce poly-beta-peptoids.

# publications[].label
SOLUTION BEHAVIOR OF UNSATURATED MOLYBDENUM CARBONYL SPECIES AS EVIDENCED VIA STEREOSPECIFIC CO-13 LABELING STUDIES

# publications[].label
RELATIVE IMPORTANCE OF SIGMA-BONDING AND PI-BONDING OF MOLECULAR NITROGEN AND CARBONYL IN OSMIUM(II) COMPLEXES AS DETERMINED BY INFRARED INTENSITIES OF MOLECULAR NITROGEN AND CARBONYL STRETCHING VIBRATIONS

# publications[].label
Non-Isocyanate and Catalyst-Free Synthesis of a Recyclable Polythiourethane with Cyclic Structure

# publications[].label
STEREOSPECIFIC PHOTOCHEMICAL REACTIONS OF GROUP VIB METAL TETRACARBONYL NORBORNADIENE COMPLEXES WITH CO-13

# publications[].label
From the WGSR to copolymers from cyclic ethers: Chemistry of carbon dioxide

# publications[].label
Organometallic models of the iron site in [NiFe] hydrogenases

# publications[].label
Electronic effects of metallodithiolate ligands on [FeFe]-H(2)ase active site model compounds

# publications[].label
Formation of polycarbonates and cyclic carbonates from the reaction of CO2 and epoxides catalyzed by Zn-II-phenoxides.

# publications[].label
Aminophosphine tungsten carbonyls as potential scaffolds for CO2/olefin coupling

# publications[].publisher
International Union of Crystallography (IUCr)

# publications[].label
The use of 1,3,5-triaza-7-phosphaadamantane (PTA), a water-soluble, air stable ligand, in organometallic chemistry and catalysis

# publications[].label
FACILE LIGAND SUBSTITUTIONAL PROCESSES IN (ACETATO)PENTACARBONYL-METALATES AND RELATED COMPLEXES OF THE GROUP-6B METALS

# publications[].label
Ring-opening polymerization of trimethylene carbonate using aluminum(III) and tin(IV) salen chloride catalysts

# publications[].label
Manganese(III) Schiff base complexes: chemistry relevant to the copolymerization of epoxides and carbon dioxide.

# publications[].label
INOR 104-Imidazole-containing Ni(N3S) complexes: Structural and electronic comparisons to the NiSOD active site

# publications[].label
Solid-state structures of zinc(II) benzoate complexes. Catalyst precursors for the coupling of carbon dioxide and epoxides.

# publications[].label
Catalysts for the reactions of epoxides and carbon dioxide

# publications[].label
Water-soluble organometallic compounds .6. Synthesis, spectral properties, and crystal structures of complexes of 1,3,5-triaza-7-phosphaadamantane with group 10 metals

# publications[].label
Kinetics and thermodynamics of the decarboxylation of glycerol carbonate to produce glycidol: Computational insights

# publications[].label
STEREOSPECIFIC INCORPORATION OF OXYGEN-18 INTO MANGANESE AND RHENIUM PENTACARBONYL DERIVATIVES VIA EXCHANGE-REACTIONS WITH H2O-18

# publications[].label
Coupling reactions of epoxides and CO2: Origin of selectivity for copolymer vs. cyclic carbonate formation

# publications[].label
CHROMIUM, MOLYBDENUM AND TUNGSTEN ANNUAL SURVEY COVERING YEAR 1973

# publications[].label
Cyanide-bridged heterobimetallic complexes of the group 6 metal carbonyls and copper(I). X-ray structures of (CO)(5)MCNCu(PPh(3))(3) (M=Cr, W) derivatives

# publications[].label
FUEL 115-Mechanistic studies of the copolymerization reaction of oxetane and carbon dioxide to aliphatic polycarbonates: Optimization of the Cr(III) salen catalyst system

# publications[].label
Reactions of transition metal carbonyls with nucleophilic reagents: reactivity and bonding

# publications[].label
Construction of Autonomic Self-Healing CO2-Based Polycarbonates via One-Pot Tandem Synthetic Strategy

# publications[].label
Construction of Versatile and Functional Nanostructures Derived from CO2-based Polycarbonates

# publications[].label
A KINETIC INVESTIGATION OF CARBON-DIOXIDE INSERTION PROCESSES INVOLVING ANIONIC TUNGSTEN ALKYL AND TUNGSTEN ARYL DERIVATIVES - EFFECTS OF CO2 PRESSURE, COUNTERIONS, AND ANCILLARY LIGANDS - COMPARISONS WITH MIGRATORY CARBON-MONOXIDE INSERTION PROCESSES

# publications[].label
The Reversible Insertion Reaction of Carbon Dioxide with the W(CO)(5)OH(-) Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO)(5)O(2)COH].

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF SULFUR-CAPPED TRINUCLEAR GROUP-6B METAL-CLUSTERS

# publications[].label
Synthesis and structural characterization of heteronuclear clusters comprised of nickel and copper bridged by thiolates

# publications[].label
MECHANISTIC STUDIES OF CARBON-DIOXIDE INSERTION INTO METAL-HYDRIDES AND EXTRUSION FROM THE CORRESPONDING METAL FORMATES UTILIZING GROUP-6 METAL-CARBONYL DERIVATIVES AS REACTION PROBES

# publications[].label
Stereoselective Ring-Opening Polymerization of rac-Lactides Catalyzed by Chiral and Achiral Aluminum Half-Salen Complexes

# publications[].label
WATER-SOLUBLE ORGANOMETALLIC COMPOUNDS .4. CATALYTIC-HYDROGENATION OF ALDEHYDES IN AN AQUEOUS 2-PHASE SOLVENT SYSTEM USING A 1,3,5-TRIAZA-7-PHOSPHAADAMANTANE COMPLEX OF RUTHENIUM

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR METAL-CARBONYL CLUSTERS .2. CO4(CO)9(MU-CO)3 DERIVATIVES

# publications[].label
Time-Resolved Infrared Spectroscopy Studies of Olefin Binding in Photogeneratecl CpRu(CO)X (X = Cl, I) Transients

# publications[].label
Binding studies of epoxides to five-coordinate cadmium tris(3-phenylpyrazolyl)-hydroborate: Models for the initiation process in epoxide/carbon dioxide coupling reactions

# publications[].label
Displacement kinetics of eta(2)-bound furan and 2,3-dihydrofuran from Mn and Cr centers: evidence for the partial dearomatization of the furan ligand.

# publications[].label
Synthesis and structures of nickel and palladium salicylaldiminato 1,3,5-triaza-7-phosphaadamantane (PTA) complexes.

# publications[].label
The catalytic activity of a series of Zn(II) phenoxides for the copolymerization of epoxides and carbon dioxide.

# publications[].label
Ring-opening polymerization of cyclic monomers by biocompatible metal complexes: Production of poly(lactide) and polycarbonates

# publications[].label
Synthesis and crystal structure of [H2B(3-Phpz)(2)](2)Zn

# publications[].label
STEREOSPECIFIC INCORPORATION OF CO-13 INTO OLEFINIC SUBSTITUTED METAL-CARBONYL COMPOUNDS

# publications[].label
Carbon Dioxide Copolymerization Study with a Sterically Encumbering Naphthalene-Derived Oxide

# publications[].label
Poly(monothiocarbonate)s from the Alternating and Regioselective Copolymerization of Carbonyl Sulfide with Epoxides.

# publications[].label
The synthesis and characterization of iron cyanide building blocks: [K](2)[CpFe(CN)(3)] and its pentamethylcyclopentadienyl (Cp*) analog

# publications[].label
Bis-salicylaldiminato complexes of zinc. Examination of the catalyzed Epoxide/CO2 copolymerization

# publications[].label
Synthesis and characterization of group 10 water-soluble complexes.

# publications[].label
Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides

# publications[].label
Sustainable Synthesis of CO2-Derived Polycarbonates from the Natural Product, Eugenol: Terpolymerization with Propylene Oxide

# publications[].label
Estimating the strength of the M-H-B interaction: a kinetic approach.

# publications[].label
Carbon monoxide induced elimination of disulfide from dinitrosyl iron complexes: Hammett correlations of para-substituted [(NHC)Fe(NO)(2)S(p-PhX)] compounds

# publications[].label
O-18 ISOTOPE SHIFTS ON THE C-13 NUCLEAR MAGNETIC-RESONANCE OF METAL-CARBONYL DERIVATIVES

# publications[].label
SYNTHESIS AND REACTIVITY OF TUNGSTEN PENTACARBONYL HYDROXO AND BICARBONATO COMPLEXES - MOLECULAR-STRUCTURE OF [PPN][W(CO)5HCO3], AN ORGANOMETALLIC ANALOG FOR CARBONIC-ANHYDRASE

# publications[].label
(Tetramethyltetraazaannulene)chromium chloride: a highly active catalyst for the alternating copolymerization of epoxides and carbon dioxide.

# publications[].label
Theoretical studies on the mechanism of copolymerization of oxetane and carbon dioxide via (salen) chromium catalysts

# publications[].label
Kinetics of the (salen)Cr(III)- and (salen)Co(III)-catalyzed copolymerization of epoxides with CO2, and of the accompanying degradation reactions

# publications[].label
A quest for polycarbonates provided via sustainable epoxide/CO2 copolymerization processes

# publications[].label
Analysis of an organometallic iron site model for the heterodimetallic unit of [NiFe]hydrogenase

# publications[].label
Kinetic studies of thermal dissociation of carbon monoxide ligands from manganese tri- and tetra-carbonyl derivatives containing the bulky dipiperidylmethane ligand, CH(2)Pip(2)

# publications[].label
DETAILED ANALYSIS OF CARBONYL STRETCHING VIBRATIONS IN AXIAL AND EQUATORIAL SUBSTITUTED IRON CARBONYL-COMPOUNDS - ABSOLUTE INFRARED INTENSITIES AND FORCE CONSTANTS OF CARBONYL LIGANDS

# publications[].label
CO2-Based Block Copolymers: Present and Future Designs

# publications[].label
Aryloxide and alkoxide derivatives of metal clusters. Syntheses, structures, and reactivities of the mu-oxo-bridged triruthenium clusters Ru-3(CO)(8)(mu-eta(2)-OC6H4Cl)(2) and Ru-3(CO)(8)(mu-eta(2)-OCH2C6H4N)(2) (vol 33, pg 3532, 1994)

# publications[].label
Coordinatively Unsaturated Derivatives of Group 6 Metal Carbonyls Containing the pi-Donating Ligand 3,5-Di-tert-butylcatecholate.

# publications[].label
An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide

# publications[].label
Phosphine adducts of monomeric zinc(bis-phenoxides): Solution and solid-state structures of (2,6-di-tert-butylphenoxide)ZnL complexes (L = PMePh2 and PCy3)

# publications[].label
FORMATE ION AS A MONODENTATE LIGAND - SYNTHESIS, STRUCTURE, AND DECARBOXYLATION OF (ETA-5-C5H5)FE(CO)2O2CH

# publications[].label
(Salan)CrCl, An Effective Catalyst for the Copolymerization and Terpolymerization of Epoxides and Carbon Dioxide

# publications[].label
Investigations into the coupling of cyclohexene oxide and carbon disulfide catalyzed by (salen)CrCl. Selectivity for the production of copolymers vs. cyclic thiocarbonates.

# publications[].label
Inquiry into the formation of cyclic carbonates during the (salen)CrX catalyzed CO2/cyclohexene oxide copolymerization process in the presence of ionic initiators

# publications[].label
PHASE-TRANSFER-CATALYZED NUCLEOPHILIC REACTIONS OF HYDROXIDE IONS AT METAL-BOUND CARBON-MONOXIDE CENTERS

# publications[].label
PREPARATION OF DINITROGEN-RHENIUM COMPLEXES WITH TERTIARY ARSINES AS COLIGANDS - INTERACTION OF INDIUM TRICHLORIDE WITH RHENIUM(I)-DINITROGEN SPECIES

# publications[].label
PREPARATION OF OXYGEN-18-LABELED DERIVATIVES OF [MN(CO)3(DIPHOS)H] VIA REACTION OF [MN(CO)4(DIPHOS)][PF6] WITH (H-2)-O-18 IN PRESENCE OF TRIETHYLAMINE - DECARBOXYLATION OF A [MN(COOH)] INTERMEDIATE

# publications[].label
Alternating copolymerization of CO2 and styrene oxide with Co(III)-based catalyst systems: differences between styrene oxide and propylene oxide

# publications[].label
Cyclohexene oxide/CO2 copolymerization catalyzed by chromium(III) salen complexes and N-methylimidazole: effects of varying salen ligand substituents and relative cocatalyst loading.

# publications[].label
(Bis phenoxide)zinc phosphine catalysts for the copolymerization of polycarbonates from CO2 and epoxides and their cadmium analogs.

# publications[].label
SYNTHESIS AND X-RAY STRUCTURE OF AN ANIONIC CHELATING PHOSPHINE ACYL DERIVATIVE OF TUNGSTEN, [PPH4][W(CO)4C(O)CH2CH2CH2PPH2], AND THE REACTIVITY OF ITS DECARBONYLATED ANALOG WITH CARBON-DIOXIDE

# publications[].label
Metal salen complexes as catalysts for the coupling of oxetane and carbon dioxide: Selectivity for cyclic carbonate formation vs. polycarbonate production

# publications[].label
INFRARED INTENSITIES AND CALCULATION OF INFRARED BAND SHAPES OF CO STRETCHING VIBRATIONS IN SUBSTITUTED TUNGSTEN CARBONYL DERIVATIVES

# publications[].label
INTERACTION OF LEWIS BASES WITH (ACRYLIC-ACID) IRON TETRACARBONYL IN SOLUTION

# publications[].label
Synthesis, characterization and crystal structure of a zinc bis-dithiocarboxylate derivative

# publications[].publisher
International Union of Crystallography (IUCr)

# publications[].label
LIGAND SUBSTITUTION PROCESSES IN TETRANUCLEAR CARBONYL CLUSTERS .10. X-RAY STRUCTURAL CHARACTERIZATION OF PRODUCTS RESULTING FROM REACTIONS OF CO4(CO)9(HC(PPH2)3, WITH PHOSPHINE-LIGANDS

# publications[].label
Bridging polymer architecture, printability, and properties by digital light processing of block copolycarbonates.

# publications[].label
Making plastics from carbon dioxide: salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2.

# publications[].label
Preparation of polycarbonate polyols from carbon dioxide and epoxides

# publications[].label
Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC).

# publications[].label
KINETIC AMBIGUITY BETWEEN ID AND D-MECHANISMS IN LIGAND SUBSTITUTION-REACTIONS - INTIMATE MECHANISM FOR AXIAL BASE-LIGAND EXCHANGE-REACTIONS IN ALKYL(BASE)COBALOXIMES AND RELATED SPECIES

# publications[].label
Double metal cyanides as catalysts for the coupling of CO2 and epoxides to provide cyclic carbonates and polycarbonates.

# publications[].label
INTRA-MOLECULAR REARRANGEMENT OF CARBONYL LIGANDS IN THE OCTAHEDRAL COMPLEX W(CO)5P(OME)3 BY A NON-DISSOCIATIVE PROCESS - EXAMPLE OF THE UTILITY OF THE O-18 ISOTOPE SHIFT ON THE C-13 NMR OF THE CARBONYL LIGAND

# publications[].label
Catalytic activity of a series of Zn(II) phenoxides for the copolymerization of epoxides and carbon dioxide

# publications[].label
Toward the design of double metal cyanides for the copolymerization of CO(2) and epoxides.

# publications[].label
NEW METHODS FOR ACQUIRING IR SPECTRAL DATA IN ORGANOMETALLIC CHEMISTRY AND CATALYSIS

# publications[].label
Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process.

# publications[].label
Thermal Dehydrogenation of Dimethylamine Borane Catalyzed by a Bifunctional Rhenium Complex

# publications[].label
Measurements of degenerate radical ion-neutral molecule electron exchange by microsecond time-resolved CIDNP. Determination of relative hyperfine coupling constants of radical cations of chlorophylls and derivatives

# publications[].label
KINETIC STUDIES OF PHOSPHINE AND PHOSPHITE EXCHANGE-REACTIONS OF SUBSTITUTED IRON TRICARBONYL CARBENE COMPLEXES - COMPETITIVE STUDY OF LEWIS-BASES FOR INTERMEDIATE [FE(CO)3C(OC2H5)CH3]

# publications[].label
STUDIES USING (N-BU)3P=O AS A CARBON-MONOXIDE LABILIZING LIGAND IN THE SYNTHESIS OF METAL-CARBONYL-COMPLEXES HIGHLY ENRICHED IN (CO)-C-13

# publications[].label
THE STRUCTURE AND REACTIVITY OF W(CO)5OP(PH2)NPPH3

# publications[].label
Synthesis and X-ray Structure of the Novel Aluminum Complex [{eta(3)-HB(3-Phpz)(2)(5-Phpz)}(2)Al][AlCl(4)]. Catalysis of CO(2)/Propylene Oxide to Propylene Carbonate by the AlCl(4)(-) Anion.

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF [ET4N][M(CO)5SR] AND [ET4N]2[M2(CO)8(SR)2] COMPLEXES (M = CR, MO, W) - LIGAND SUBSTITUTION-REACTIONS AND X-RAY CRYSTAL-STRUCTURE OF [ET4N]2[W2(CO)8(SPH)2]

# publications[].label
Kinetic and Thermodynamic Investigations of CO2 Insertion Reactions into Ru-Me and Ru-H Bonds - An Experimental and Computational Study

# researcherOn[].label
Catalytic Studies of the Production of Biodegradable Polymeric Materials From Carbon Dioxide and Renewable Resources

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].label
Development of Polycarbonate Micelles for Encapsulation of Dinitrosyl Iron and Diiron Hydrogenase Biomimetics

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].label
CAS: Synthetic Methodologies to Harness the Chemical Diversity of Natural Products for the Sustainable Production of High Value Macromolecular Materials

# researcherOn[].awardedBy.label
Directorate for Mathematical & Physical Sciences - (Arlington, Virginia, United States)

# researcherOn[].label
SusChEM: Resourceful Polymers Derived from Polyhydroxyl Natural Products

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# streetAddress
Texas A&M University; Chemistry Department; 3255 TAMU

# organizations[]
Texas A&M Engineering Experiment Station (TEES)

# schools[]
Texas A&M Engineering Experiment Station (TEES)

# etdChairOf[].label
Moncada, Adriana I. (2010-05). Metal Catalyzed Formation of Aliphatic Polycarbonates Involving Oxetanes and Carbon Dioxide as Monomers. Doctoral Dissertation.

# etdChairOf[].label
Choi, Wonsook (2007-08). Mechanistic studies of the metal catalyzed formation of polycarbonates and their thermoplastic elastomers. Doctoral Dissertation.

# etdChairOf[].label
Phelps, Andrea Lee (2005-08). Metal catalyzed copolymerization processes involving carbon oxides as substrates. Doctoral Dissertation.

# etdChairOf[].label
Poland, Ross Rivers (2012-05). Advances in Synthesis of Co- and Ter- Polycarbonates and Polyesters from Non-Petroleum Feedstocks and Kinetic Studies of Ligand Substitution from Manganese Half-Sandwich Complexes. Doctoral Dissertation.

# etdChairOf[].label
Andreatta, Jeremy R. (2009-12). Fundamental Studies towards Transistion Metal Catalysis and Application of Chromium Salen Complexes for the Synthesis of Polymers. Doctoral Dissertation.

# etdChairOf[].label
Fitch, Shawn (2009-05). DEVELOPMENT AND MECHANISTIC STUDIES OF THE CHROMIUM TETRAMETHYLTETRAAZAANNULENE CATALYST SYSTEM FOR THE COPOLYMERIZATION OF CARBON DIOXIDE AND EPOXIDES. Doctoral Dissertation.

# etdChairOf[].label
Mackiewicz, Ryan Michael (2003-05). Structural and mechanistic studies into the copolymerization of carbon dioxide and epoxides catalyzed by chromium salen complexes. Doctoral Dissertation.

# etdChairOf[].label
Wei, Sheng-Hsuan (2013-08). The Copolymerization of CO_(2) and Cyclic Ethers and Their Degradation Pathways. Doctoral Dissertation.

# etdChairOf[].label
Ganguly, Poulomi (2006-05). Metal salen catalyzed production of polytrimethylene carbonate. Doctoral Dissertation.

# etdChairOf[].label
Chung, Wan-Chun (2015-12). Cobalt and Chromium Salen Complexes Catalyzed Copolymerization of CO2 and Epoxides: The Scope of Epoxides. Doctoral Dissertation.

# etdChairOf[].label
Billodeaux, Damon Ray (2005-05). Investigations on the use of main group metal complexes of salen ligands as catalysts for the copolymerization of CO2 and epoxides. Doctoral Dissertation.

# etdChairOf[].label
Frantz, Eric Benjamin (2008-08). Synthesis, reactivity, and coordination chemistry relevant to the copolymerization of CO2 and epoxides by first row transition metal schiff base complexes. Doctoral Dissertation.

# etdChairOf[].label
Karroonnirun, Osit (2011-05). Biometal Catalyzed Ring-Opening Polymerization of Cyclic Esters: Ligand Design, Catalyst Stereoselectivity, and Copolymer Production. Doctoral Dissertation.

# etdChairOf[].label
Wilson, Stephanie Jo (2013-08). Coupling of CO_(2) and CS_(2) with Novel Oxiranes: Polycarbonate vs. Cyclic Carbonate Production. Doctoral Dissertation.

# etdChairOf[].label
Yeung, Andrew D (2014-12). Conversion of CO2 to Polycarbonates and Other Materials: Insights through Computational Chemistry. Doctoral Dissertation.

# etdChairOf[].label
Wang, Yanyan (2018-08). Development of Functional Polycarbonate Materials from Metal-catalyzed Copolymerization of Epoxides and CO2. Doctoral Dissertation.

# etdChairOf[].label
Kyran, Samuel John (2015-12). Activation of Carbon Oxides: Chemical Reactions and Transformations Facilitated by Groups 6, 7, & 8 Metal Complexes. Doctoral Dissertation.