# positions[].organizations[].parent[].label
Texas A&M Engineering Experiment Station (TEES)

# overview
Bio-inspired Catalysts for Hydrogen Production: The ultimate, home-run, goal of our work is to synthesize and develop a robust, highly active hydrogen-producing catalyst comprised of earth-abundant transition metals within a ligand environment that is inspired by the biological Figure 3hydrogenase (H2ase) enzyme active sites. Progress in precise structural modeling of the illusive "rotated" structure displayed in the as-isolated, mixed-valent FeIIFe state in the past decade has permitted in depth analysis of electronic structure by Mo ssbauer, EPR (ENDOR), and computational chemistry.  New electrocatalysts for hydrogen production: The connection between the Fe(NO)2 unit and the Fe(CX)3 (X = O or N) unit found in hydrogenase enzyme active sites offers opportunity for design of new catalysts, one of which is shown. In this regard we explore the ability of N2S2 metal complexes to bind as metallodithiolate ligands to various metal acceptors. The properties of such complexes vary The connection of these to light harvesting molecules for dye sensitized, sacrificial electron donor, hydrogen production is also of interest.  When Iron Meets Nitric Oxide: Good Chemistry, Intriguing Biology. The affinity of iron for diatomic molecules, O2, CO, N2, and NO, is central to the most important of life processes, including those of human physiology. Figure 6In this research area we target synthetic chemistry involving dinitrosyl iron complexes (DNICs) that serve as biomimetics of products of FeS cluster degradation by excesses of NO, or as derived from the chelatable iron pool (CIP) in cells. The electronic ambivalence of the DNIC unit is expressed in the ease with which it interconverts between oxidized and reduced forms, {Fe(NO)2}9 and {Fe(NO)2}10, respectively (Enemark/Feltham notation), and serves as impetus to explore analogous reactions known to involve the CuII/CuI redox couple. The accessory ligands which stabilize one redox level over the other, including N-heterocyclic carb

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0303 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3407 Theoretical And Computational Chemistry

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
0502 Environmental Science And Management

# keywords[]
0306 Physical Chemistry (incl. Structural)

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3403 Macromolecular And Materials Chemistry

# keywords[]
3407 Theoretical And Computational Chemistry

# educationAndTraining[].organization.label
University of Illinois at Urbana Champaign - (Urbana, Illinois, United States)

# educationAndTraining[].organization.label
Union College - (Barbourville, Kentucky, United States)

# awardsAndHonors[].label
Association of Former Students University-Level Distinguished Achievement Award, The

# awardsAndHonors[].label
Association of Former Students University-Level Distinguished Achievement Award, The

# awardsAndHonors[].label
Fred Basolo Medal for Outstanding Research in Inorganic Chemistry

# awardsAndHonors[].label
College of Science Undergraduate Research Mentoring Award

# awardsAndHonors[].label
Association of Former Students College-Level Teaching Distinguished Achievement Award, The

# awardsAndHonors[].label
ACS Award for Distinguished Service in the Advancement of Inorganic Chemistry

# publications[].label
Sensing of sulfur dioxide by base metal thiolates: structures and properties of molecular NiN2S2/SO2 adducts.

# publications[].label
TRANSITION-METAL HYDRIDE REDUCTION OF ACID-CHLORIDES TO ALDEHYDES AND ALDEHYDES TO ALCOHOLS

# publications[].label
Zinc thiotropolone combinations as inhibitors of the SARS-CoV-2 main protease.

# publications[].label
INTRAMOLECULAR LIGAND REARRANGEMENTS IN ANIONIC GROUP-6 METAL PENTACARBONYL HYDRIDE DERIVATIVES

# publications[].label
MetalTemplated, Tight Loop Conformation of a CysXCys Biomimetic Assembles a Dimanganese Complex

# publications[].label
COMPARISONS OF THE HETEROBIMETALLIC AND HETEROTRIMETALLIC ANIONS - HFEW(CO)9- AND PH3PAUFEW(CO)9-

# publications[].label
Analysis of bridgehead effects on [FeFe]-hydrogenase active site models: Steric bulk at nitrogen vs. carbon

# publications[].label
INFRARED DETERMINATION OF STEREOCHEMISTRY IN METAL COMPLEXES . AN APPLICATION OF GROUP THEORY

# publications[].label
Simple techniques can give pleasurable results

# publications[].label
A mixed-valent, Fe(II)Fe(I), diiron complex reproduces the unique rotated state of the [FeFe]hydrogenase active site.

# publications[].label
A cyclodextrin host/guest approach to a hydrogenase active site biomimetic cavity.

# publications[].label
SULFUR SITE ADDUCTS OF SULFUR-DIOXIDE IN NICKEL-BOUND THIOLATES AND THEIR CONVERSION TO SULFATE

# publications[].label
ELECTROCHEMICAL STUDY OF THE OXIDATION CHEMISTRY OF CHROMIUM CARBONYL THIOLATES RSCR(CO)5- AND RSCR2(CO)10-

# publications[].label
Mossbauer studies of model complexes for the H-cluster in [Fe-Fe]-hydrogenases: Electronic structure of mixed-valence complexes containing low-spin Fe-(I)

# publications[].label
The roles of chalcogenides in O2 protection of H2ase active sites.

# publications[].label
METAL DONOR-]METAL ACCEPTOR COMPLEXES - FE(CO)42- HFE(CO)4-, AND TRANS-HFE(CO)3P(OME)3- AS ANIONIC LIGANDS TO CR(CO)50, W(CO)50

# publications[].label
Oxygen-Tolerant H2 Production by [FeFe]-H2ase Active Site Mimics Aided by Second Sphere Proton Shuttle.

# publications[].label
Structural and Electronic Responses to the Three Redox Levels of Fe(NO)N2 S2 -Fe(NO)2.

# publications[].label
DEPROTONATION OF [HMO(CO)2(PP)2]BF4 COMPLEXES - HARD ANIONS AS PROTON CARRIERS

# publications[].label
Chromium, molybdenum and tungsten annual servey covering the year 1973

# publications[].label
ISOTOPIC LABELING INVESTIGATION OF THE OXYGENATION OF NICKEL-BOUND THIOLATES BY MOLECULAR-OXYGEN

# publications[].label
REACTIONS OF GRIGNARD REAGENTS WITH METAL CARBONYLS - INOR

# publications[].label
STRUCTURAL AND CHEMICAL CHARACTERIZATION OF A PHOSPHINE BOUND M-H-M BRIDGED CARBONYLATE - ET4N+(MU-H)[MO2(CO)9PPH3]-

# publications[].label
Sulfur K-edge XAS and DFT studies on NiII complexes with oxidized thiolate ligands: implications for the roles of oxidized thiolates in the active sites of Fe and Co nitrile hydratase.

# publications[].label
How nitrosyls soften first row transition metals for hydrogenase-inspired HER electrocatalysis: Mechanistic and computational studies

# publications[].label
Ligand-assisted proton delivery in diiron complexes as electrocatalysts for H-2 production: Ligand and complex synthesis

# publications[].label
Methylation of Tethered Thiolates in [(bme-daco)Zn](2) and [(bme-daco)Cd](2) as a Model of Zinc Sulfur-Methylation Proteins.

# publications[].label
Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase

# publications[].label
cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(-SR)4[Fe(NO)2]3.

# publications[].label
Correction for Quiroz et al., Cooperative redox and spin activity from three redox congeners of sulfur-bridged iron nitrosyl and nickel dithiolene complexes.

# publications[].publisher
Proceedings of the National Academy of Sciences

# publications[].label
Synthetic advances inspired by the bioactive dinitrosyl iron unit.

# publications[].label
Chemical studies of diiron(I) organometallic complexes

# publications[].label
Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (111)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM

# publications[].label
The vapochromic behavior, desulfoxidation and structural characterization of the SO2 adducts of Ni(BME-DACH) from powder data

# publications[].label
SYNTHESIS OF METAL-CARBONYL-COMPLEXES HIGHLY ENRICHED IN C-13 - UTILIZATION OF THE CO-LABILIZING ABILITY OF (N-BU)3P=O

# publications[].label
Development of five-coordinate zinc mono- and dithiolates as S-donor metalloligands: formation of a Zn-W coordination polymer.

# publications[].label
Tetradentate N2S2 vanadyl(IV) coordination complexes: synthesis, characterization, and reactivity studies.

# publications[].label
Sulfur Site Iodine Adduct of a Nickel Thiolate Complex.

# publications[].label
De novo design of synthetic di-iron(I) complexes as structural models of the reduced form of iron-iron hydrogenase.

# publications[].label
CHED 1195-Models of nitrogen/sulfur containing copper enzymes through synthetic bioinorganic chemistry

# publications[].label
The modular assembly of clusters is the natural synthetic strategy for the active site of [FeFe] hydrogenase.

# publications[].label
The Bioorganometallic Chemistry of Hydrogenase

# publications[].label
CHROMIUM, MOLYBDENUM AND TUNGSTEN - ANNUAL SURVEY COVERING YEAR 1974

# publications[].label
Chemical issues addressing the construction of the distal Ni[cysteine-glycine-cysteine]2- site of acetyl CoA synthase: why not copper?

# publications[].label
Computational study of quinone reduction with hydrogen catalyzed by a mono-Fe hydrogenase biomimetic

# publications[].label
HETEROLYTIC ACTIVATION OF DIHYDROGEN VIA M(CO)5B- (M = CR, MO, W, B = BRONSTED BASE)

# publications[].label
Rich man's proton: Triphenylphosphinegold as probe of hydride positions in organo- and bioorgano-metallic complexes

# publications[].label
INOR 94-Mimicking the entatic effect of the enzyme in small molecule models of [FeFe]-hydrogenase

# publications[].label
Metallodithiolates as ligands in coordination, bioinorganic, and organometallic chemistry.

# publications[].label
Electronic effects of (N2S2)M(NO) complexes (M = Fe, Co) as metallodithiolate ligands.

# publications[].label
The bio-organometallic chemistry of active site iron in hydrogenases

# publications[].label
Influence of sulf-oxygenation on CO/L substitution and Fe(CO)3 rotation in thiolate-bridged diiron complexes.

# publications[].label
Extending the roles for the pendant base in [FeFe]-Hydrogenase active site mimics

# publications[].label
Chirality-Guided Isomerization of Mn2S2 Diamond Core Complexes: A Mechanistic Study.

# publications[].label
THE SYNTHESIS AND MOLECULAR-STRUCTURE OF (PH3PAU)2FE(CO)3P(OET)3 - A TRIANGULAR AU2FE CLUSTER

# publications[].label
Sulfur oxygenates of biomimetics of the diiron subsite of the [FeFe] hydrogenase active site: Structures, reactivity and oxygen damage repair possibilities

# publications[].label
Infrared spectroscopic studies of organometallic models of the iron site in [NiFe] hydrogenases

# publications[].label
FACILE REDUCTION OF CARBON-DIOXIDE BY ANIONIC GROUP 6B METAL-HYDRIDES - CHEMISTRY RELEVANT TO CATALYSIS OF THE WATER-GAS SHIFT REACTION

# publications[].label
N2S2Ni metallothiolates as a class of ligands that support organometallic and bioorganometallic reactivity.

# publications[].label
Development of nickel dithiolate complexes as chemical sensors for SO2: Characteristics and structures of NiN2S2/SO2 adducts.

# publications[].label
Sulfoxygenation of Active Site Models of [NiFe] and [FeFe] Hydrogenases - A Commentary on Possible Chemical Models of Hydrogenase Enzyme Oxygen Sensitivity

# publications[].label
The Halpern Files: Publications from Jack Halpern that guide organometallic chemistry education and research

# publications[].label
Thiolate-bridged heterodinuclear platinum-zinc chelates as models for ternary platinum-DNA-protein complexes and zinc ejection from zinc fingers. Evidence from studies using ESI-mass spectrometry.

# publications[].label
Sulfur Lone Pairs Control Topology in Heterotrimetallic Complexes: An Experimental and Theoretical Study.

# publications[].label
Characteristics of nickel(0), nickel(I), and nickel(II) in phosphino thioether complexes: Molecular structure and S-dealkylation of (Ph(2)P(o-C6H4)SCH3)(2)Ni-0

# publications[].label
Diiron hydrogenase active site models outfitted with pendant redox-active units

# publications[].label
INOR 1210-Diiron model complexes related to Fe-only hydrogenase: Understanding key differences from the enzyme active site

# publications[].label
Influence of sulfur metallation on the accessibility of the Ni-II/I couple in [N,N'bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II).

# publications[].label
Structures and energetics of models for the active site of acetyl-coenzyme a synthase: role of distal and proximal metals in catalysis.

# publications[].label
HETEROBINUCLEAR NONACARBONYL COMPLEXES AND HYDRIDE COMPLEXES OF IRON CHROMIUM, IRON MOLYBDENUM, AND IRON TUNGSTEN

# publications[].label
Self-assembly of dinitrosyl iron units into imidazolate-edge-bridged molecular squares: characterization including Mssbauer spectroscopy.

# publications[].label
Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Dimanganese Complex.

# publications[].label
SYNTHESIS, CHARACTERIZATION, AND REACTION CHEMISTRY OF THE HETEROBIMETALLIC BRIDGING HYDRIDES - MU-H[FE(CO)4][M(CO)5]- (M = CR, MO, W)

# publications[].label
Intramolecular iron-mediated C-H bond heterolysis with an assist of pendant base in a [FeFe]-hydrogenase model.

# publications[].label
The Bioorganometallic Chemistry of Hydrogenase

# publications[].label
Synthetic Metallodithiolato Ligands as Pendant Bases in [FeIFeI], [FeI[Fe(NO)]II], and [(-H)FeIIFeII] Complexes.

# publications[].label
The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (mu-SCH2CR2CH2S)[Fe(CO)(3)][Fe(CO)(2)L] complexes

# publications[].label
REACTIVITY STUDIES OF NICKEL (II) HYDRIDES - (R3P)ZNI(ME)H, (R3P)ZNI(OAC)H, (R3P)ZNI(O2CH)H, (R3P)ZNI(SR)H

# publications[].label
KINETIC-STUDIES OF REACTIONS OF TRANSITION-METAL CARBONYL ANION WITH ALLYL HALIDES

# publications[].label
S K-edge XAS and DFT calculations on square-planar NiII-thiolate complexes: effects of active and passive H-bonding.

# publications[].label
ANIONIC METAL ALKYLS IN CARBON-CARBON COUPLING REACTIONS

# publications[].label
Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Ni, Fe, Co) as metallodithiolate ligands

# publications[].label
RELATIVE REACTIVITY AND MECHANISTIC STUDIES OF THE HYDRIDE-TRANSFER REAGENTS HM(CO)4L- (M = CR, W - L = CO, PR3)

# publications[].label
Thiolate bridged nickel-iron complexes containing both iron(0) and iron(II) carbonyls

# publications[].label
SPECTROSCOPIC AND CHEMICAL STUDIES OF NICKEL(II) HYDRIDES

# publications[].label
INOR 694-Redox active ligands as related to the active site of [FeFe]-hydrogenase

# publications[].label
Mechanistic insight of M(N2S2) metalloligand in Re-based electro-catalysts for CO2 reduction

# publications[].label
Synthesis of nitrosolated metal dithiolates and bis-phosphine ligands as bridges in quadruply bonded dimolybdenum complexes

# publications[].label
Versatile N2S2 nickel-dithiolates as mono- and bridging bidentate, S-donor ligands to gold(I).

# publications[].label
Award Address (ACS Award in Organometallic Chemistry sponsored by The Dow Chemical Company Foundation). Hydrogenase- and ACS-inspired bioorganometallic chemistry

# publications[].label
ORGANOMETALLIC CHEMISTRY OF SULFUR PHOSPHORUS DONOR LIGAND COMPLEXES OF NICKEL(II) AND NICKEL(0)

# publications[].label
Investigation of unique dissymmetric model complexes of the [FeFe]-hydrogenase active site

# publications[].label
A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand.

# publications[].label
CORRELATION OF SOLUTION CONDUCTANCE STUDIES WITH CHEMICAL REACTIVITY OF SOME ORGANOMETALLIC SALTS

# publications[].label
Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes

# publications[].label
Alkylation-induced O-atom rearrangement in nickel S-oxygenates, (vol 17, pg 4821, 1998)

# publications[].label
SITE OF CHARGE LOCALIZATION IN SUBSTITUTED IRON CARBONYL ACYLATES

# publications[].label
Immobilization-Enabled Proton Reduction Catalysis by a Di-iron Hydrogenase Mimic

# publications[].label
AEI 50-Synergy between experiment and theory: Iron-catalyzed dihydrogen production and copper-catalyzed C-N bond formation

# publications[].label
A nickel tripeptide as a metallodithiolate ligand anchor for resin-bound organometallics.

# publications[].label
MECHANISM OF DIOXYGEN ADDITION TO NICKEL-BOUND THIOLATES

# publications[].label
COMPARISON OF THE LIGATING ABILITY OF ANONIC TRANSITION-METAL COMPLEX (MN(CO)5-), TRANSITION-METAL HYDRIDES (HCR(CO)5-, HW(CO)5-, CIS-HW(CO)4P(OME)3-, HFE(CO)4-, TRANS-HFE(CO)3P(OME)3-), AND TRADITIONAL LIGANDS (BR-, P(C6H5)3) TO M(CO)5(0) (M = CR, W)

# publications[].label
Bond Trading: Intramolecular Metal and Ligand Exchange within a NO/Ni/Co Complex.

# publications[].label
INOR 519-Copper binding to cysteine-containing peptides that are potential models for copper proteins with sulfur and nitrogen donors in the active site

# publications[].label
PROPERTIES AND X-RAY STRUCTURE OF PPN+ CIS-HFE(CO)3P(OPH)3- - AN UNEXPECTED ISOMER

# publications[].label
Copolymerization of propylene oxide and (CO2)-C-13 to afford completely alternating regioregular C-13-labeled Poly(propylene carbonate)

# publications[].label
EFFECTS OF SULFUR SITE MODIFICATION ON THE REDOX POTENTIALS OF DERIVATIVES OF [N,N'-BIS(2-MERCAPTOETHYL)-1,5-DIAZACYCLOOCTANATO]NICKEL(II)

# publications[].label
HYDROGEN-DEUTERIUM EXCHANGE OF THE ANIONIC GROUP-6B TRANSITION-METAL HYDRIDES - CONVENIENT, INSITU DEUTERIUM TRANSFER REAGENTS

# publications[].label
Metallo-N2S2 complexes as S-donor and M-tunable ligands in the design of heteropolymetallic coordination complexes

# publications[].label
SPECTROSCOPIC STUDIES OF SOME CARBENE PENTACARBONYL COMPLEXES OF CHROMIUM(0) AND TUNGSTEN(0)

# publications[].label
Redox active iron nitrosyl units in proton reduction electrocatalysis.

# publications[].label
Bifunctional metalloligands in MN2S2 circle Re/Mn(CO)3X complexes designed for CO2 reduction catalysts

# publications[].label
Bioinorganic chemistry: Enzymes activated by synthetic components.

# publications[].label
Synthesis of biomimetics of hydrogenases: Synergy with computational modeling

# publications[].label
N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H(2)ase enzyme active site

# publications[].label
Correction: Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic NiII, PdII and PtII tetrathiolate bridges.

# publications[].label
DIRECT SYNTHESIS OF MIXED METAL SULFIDE CATALYSTS AND THEIR HYDRODENITROGENATION ACTIVITY

# publications[].label
Modeling structures and vibrational frequencies for dinitrosyl iron complexes (DNICs) with density functional theory.

# publications[].label
PROMOTION OF ME/CO MIGRATORY INSERTION BY TRANSITION-METAL LEWIS-ACIDS - SYNTHESIS AND REACTIVITY OF A TRANSITION-METAL HETEROBIMETALLIC CARBONYL ALKYL ANION, MEFEW(CO)9-

# publications[].label
Bridging cyanides from cyanoiron metalloligands to redox-active dinitrosyl iron units.

# publications[].label
Cooperative redox and spin activity from three redox congeners of sulfur-bridged iron nitrosyl and nickel dithiolene complexes.

# publications[].publisher
Proceedings of the National Academy of Sciences

# publications[].label
KINETIC STUDY OF REACTION OF NAMN(CO)4L (L=CO, PHOSPHINE) WITH ALKYL-HALIDES

# publications[].label
INOR 32-Mixed valent, Fe(II)Fe(I), diiron complexes reproduce the unique rotated state of the [FeFe]Hydrogenase active site

# publications[].label
Syntheses and reactivity of a novel (mu-oxo)diiron(III) complex.

# publications[].label
Synthetic chemistry: making a natural fuel cell.

# publications[].label
SYNTHESIS AND SPECTRAL PROPERTIES OF MANGANESE PENTACARBONYL PHOSPHINE AND PHOSPHITE CATION DERIVATIVES AND RELATED COMPLEXES

# publications[].label
The Construction of (N<inf>2</inf>S<inf>2</inf>)Ni-Pd Clusters: A Slant-Chair, a Basket and a C<inf>4</inf>-Paddlewheel Structure

# publications[].label
A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion.

# publications[].label
Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates.

# publications[].label
PROPERTIES AND X-RAY STRUCTURE OF PPN+[CIS-HFE(CO)3P(OPH)3]- - AN UNEXPECTED STRUCTURAL ISOMER

# publications[].label
Subtle bite-angle influences on N(2)S(2)Ni complexes.

# publications[].label
THE NATURE OF ALKALI CATION CONTACT ION-PAIRS WITH ANIONIC TRANSITION-METAL HYDRIDES HM(CO)4L-(M=CR, W - L = CO, PR3)

# publications[].label
Metallodithiolates as S-donor ligands to palladium and their function as C-C cross coupling catalysts

# publications[].label
Synergy between theory and experiment as applied to H/D exchange activity assays in [Fe]H₂ase active site models

# publications[].label
Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships

# publications[].label
The construction of (N2S2)Ni-Pd clusters: A slant-chair, a basket and a C-4-paddlewheel structure

# publications[].label
Origin of Stabilization of Ligand-Centered Mixed Valence Ruthenium Azopyridine Complexes: DFT Insights for Neuromorphic Applications.

# publications[].label
Cis-NiN2S2 metallodithiolates as mono- and bidentate S-donors to gold (I)

# publications[].label
Synthesis and molecular structures of mononitrosyl (N2S2)M(NO) complexes (M = Fe, Co).

# publications[].label
Self-Assembled Nickel-4 Supramolecular Squares and Assays for HER Electrocatalysts Derived Therefrom.

# publications[].label
Heterobimetallics of nickel-iron dinitrosyl: electronic control by chelate and diatomic ligands.

# publications[].label
Synthesis of heterometallic dinuclear nitrosyl compounds and their roles as electrocatalysts for H+ reduction and H-2 evolution

# publications[].label
Synthesis and properties of water soluble N-heterocyclic carbene dinitrosyl iron complexes

# publications[].label
INOR 541-Construction of polymetallic paddlewheel complexes from (N2S2)Ni and (N2S2)Fe(NO) paddles and M-M axles: A tribute to F. Albert Cotton, Alfred Werner and New Orleans

# publications[].label
Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT.

# publications[].label
Template effect for O-2 addition across cis-sulfur sites in nickel dithiolates

# publications[].label
SYNTHESIS, PROPERTIES AND REACTIVITY OF [PPN][RSCR(CO)5] (R=ET, PRI, BUT, PH)

# publications[].label
Immobilization-Enabled Proton-Reduction Catalysis by a Di-iron Hydrogenase Mimic (vol 5, pg 5, 2014)

# publications[].label
SOLUTION STRUCTURE AND REACTIVITY OF HYDRIDO-IRON TETRACARBONYL ANION, [HFE(CO)4]-

# publications[].label
PROTONATION SITES IN THIOLATO IRON CARBONYLATES - EVIDENCE FOR AN ARRESTED FE(RS-H) OXIDATIVE ADDITION

# publications[].label
Reactions of palladium and gold complexes with zinc-thiolate chelates using electrospray mass spectrometry and X-ray diffraction: molecular identification of [Pd(bme-dach)], [Au(bme-dach]+ and [ZnCl(bme-dach)]2Pd.

# publications[].label
A REACTIVITY STUDY OF ADDITION OF ORGANIC HALIDES TO CPMO(CO)3- - COUNTERION AND RX DEPENDENCES

# publications[].label
CO and ethylene migratory insertion reactions and copolymerization involving palladium complexes of a NiN2S2 metallodithiolate ligand

# publications[].label
REACTIONS OF TRANSITION METAL CARBONYLS WITH ORGANOLITHIUM COMPOUNDS .2. PREDICTION OF NUCLEOPHILIC ATTACK AT CARBON AND RESULTING STEREOCHEMISTRY

# publications[].label
Ambidentate thiocyanate and cyanate ligands in dinitrosyl iron complexes.

# publications[].label
Structural and electrochemical comparison of NIII in an N2S2 with two, and no axial and of a five coordinate nickel(II) complex

# publications[].label
Paramagnetic transition metal ions in N2S2 coordination

# publications[].label
STRUCTURE/FUNCTION RELATIONSHIPS IN LIGAND-BASED SO2/O-2 CONVERSION TO SULFATE AS PROMOTED BY NICKEL AND PALLADIUM THIOLATES

# publications[].label
NORM's and effects of exogenous agents: Copper promoted NO release from sugar appended thiol DNIC's

# publications[].label
The acetyl CoA synthase paradigm for hybrid bio-organometallics: Quantitative measures for resin-bound Ni-Rh complexes

# publications[].label
ELECTRONIC AND STERIC CONTROL OF REACTIONS OF BENZYLMAGNESIUM CHLORIDE WITH SUBSTITUTED METAL-CARBONYLS

# publications[].label
STRUCTURAL MODIFICATIONS OF CARBONYL METALLATES BY INTERACTING CATIONS - EFFECTS ON LIGAND-EXCHANGE AND OXIDATIVE ADDITION-REACTIONS

# publications[].label
METAL-COMPLEXES CONTAINING N2S2O2 AND N2S2O DONOR LIGANDS

# publications[].label
CYCLOHEPTATRIENE CHROMIUM TRICARBONYL EXCHANGE-REACTIONS WITH ARENES - KINETICS AND MECHANISMS

# publications[].label
Resolving the Roles of Dissimilar Irons in a Proton Reduction Electrocatalyst: [(NO)Fe(N2S2)Fe(NO)(2)](+) and Its Reduced Analogue

# publications[].label
Thiolate bridging and metal exchange in adducts of a zinc finger model and Pt(II) complexes: biomimetic studies of protein/Pt/DNA interactions.

# publications[].label
Effect of inclusion in cyclodextrin on small molecule models of [FeFe]-hydrogenase

# publications[].label
Responses of the Fe(CN)(2)(CO) unit to electronic changes as related to its role in [NiFe]hydrogenase

# publications[].label
MECHANISM OF O2 ADDITION TO NICKEL-BOUND THIOLATES

# publications[].label
Mechanism of electrocatalytic hydrogen production by a di-iron model of iron-iron hydrogenase: a density functional theory study of proton dissociation constants and electrode reduction potentials.

# publications[].label
THE HYDROGENATION OF ANIONIC METAL ALKYLS - FORMAL H-/R- EXCHANGE IN RCR(CO)5-, RW(CO)5- AND RFE(CO)4-

# publications[].label
A reduced 2Fe2S cluster probe of sulfur-hydrogen versus sulfur-gold interactions.

# publications[].label
Magnetic and EPR Spectroscopic Studies of Thiolate Bridged Divalent Ni, Pd, and Pt Ions Capped with VO(N2S2) Metalloligands.

# publications[].label
INOR 622-Computational explorations of M(N2S2) [M = Ni, Cu, Zn] complexes as models for Acetyl Coenzyme A Synthase

# publications[].label
Metallodithiolato ligands as bridges in multiply bonded dimolybdenum complexes.

# publications[].label
STUDY OF SULFINATE AND SULFENATE COMPLEXES DERIVED FROM THE OXYGENATION OF THIOLATE SULFUR IN [1,5-BIS(2-MERCAPTO-2 METHYLPROPYL)-1,5-DIAZACYCLOOCTANATO(2-)]NICKEL(II)

# publications[].label
SYNTHESIS, SPECTRAL PROPERTIES, AND REACTIONS OF MANGANESE AND RHENIUM PENTACARBONYL PHOSPHINE AND PHOSPHITE CATION DERIVATIVES AND RELATED COMPLEXES

# publications[].label
Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes

# publications[].label
The reaction of electrophiles with models of iron-iron hydrogenase: A switch in regioselectivity

# publications[].label
CHROMIUM, MOLYBDENUM, AND TUNGSTEN ANNUAL SURVEY COVERING THE YEAR 1976

# publications[].label
Models for terminal Ni(S-cysteine) modification in [NiFe]hydrogenases by iodoacetamide and iodoacetate

# publications[].label
Structural and spectroscopic features of mixed valent Fe(II)Fe(I) complexes and factors related to the rotated configuration of diiron hydrogenase.

# publications[].label
SYNTHESIS, STRUCTURE, AND REACTIVITY OF TRANSITION-METAL HETEROBIMETALLIC CARBONYL ALKYL ANIONS

# publications[].label
Organometallic models for the binuclear active site of Fe-only hydrogenase.

# publications[].label
Capture of Ni(II), Cu(I) and Z(II) by thiolate sulfurs of an N2S2Ni complex: a role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site.

# publications[].label
Water Splitting Using Synthetic Functional Models of [Fe-Fe]-Hydrogenase: Thermodynamic and Kinetic Role of the Bridge Head Nitrogen Atom

# publications[].label
SPECTROSCOPIC AND CHEMICAL STUDIES OF NICKEL(II) HYDRIDES

# publications[].label
Requirements for functional models of the iron hydrogenase active site: D2/H2O exchange activity in ((mu-SMe)(mu-pdt)[Fe(CO)2(PMe3)]2+)[BF4-].

# publications[].label
Development of metal dithiolate complexes as bidentate ligands for organometallic chemistry inspired by acetyl coenzyme A synthase.

# publications[].label
Catalysis of H(2)/D(2) scrambling and other H/D exchange processes by [Fe]-hydrogenase model complexes.

# publications[].label
ODD ELECTRON INTERMEDIATES IN THE OXIDATION OF ANIONIC METAL-HYDRIDES, ALKYLS AND ACYLS

# publications[].label
Structural and Electronic Complexities of a Sulfur-Bridged Di-Iron Complex Composed of Mono- and Di-Nitrosyl Units.

# publications[].label
Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC)

# publications[].label
SOLVENT EFFECTS ON SOLUTION STRUCTURE AND CHEMICAL PROPERTIES OF LITHIUM AND MAGNESIUM SALTS OF TRANS-PHENYLACYLTRICARBONYL(TRIPHENYLPHOSPHINE)IRON(-I)

# publications[].label
RELATIVE REACTIVITIES OF ANIONIC TRANSITION-METAL HYDRIDES - REDUCTION OF ALKYL-HALIDES

# publications[].label
THIOLATE, THIOETHER, AND THIOL DERIVATIVES OF IRON(0) CARBONYLS

# publications[].label
INOR 803-The interactions of zinc finger models and exogenous metal complexes: Thiolate bridging and metal exchange

# publications[].label
Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site

# publications[].label
ANIONIC GROUP-6 HYDRIDES AND CARBOXYLATES AS HOMOGENEOUS CATALYSTS FOR REDUCTION OF ALDEHYDES AND KETONES

# publications[].label
ACID-BASE INTERACTIONS OF METALLOARENE AND METALLOCENE COMPLEXES

# publications[].label
When iron meets nitric oxide: Good chemistry, intriguing biology

# publications[].label
PHOTOCHEMICAL SUBSTITUTION REACTIONS OF SUBSTITUTED GROUP VI METAL-CARBONYLS

# publications[].label
Sythesis and characterization of a series of dinitrosyl iron complexes

# publications[].label
Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic NiII, PdII and PtII tetrathiolate bridges.

# publications[].label
REDOX PROMOTED SULFUR-OXYGEN BOND-CLEAVAGE IN NICKEL(II) SULFENATE

# publications[].label
THE USE OF ION-PAIRING PHENOMENA IN THE ASSIGNMENT OF NU-(CO) IR BANDS OF PV(CO)5-

# publications[].label
From [2Mn2S] Diamond Cores to Butterfly Rhombs: Transformations That Highlight Alternating Peptide Binding Sites.

# publications[].label
Structural analysis of heteropolymetallic complexes: A chiral pinwheel {Cr [Ni(N2S2)](3)}(3+) and the {trans-(MeCN)Cr(NO)[Ni(N2S2)](2)}(2+) basket

# publications[].label
Base-promoted tautomerization of imidazoles to N-heterocyclic carbenes (NHCs): Via a dinitrosyl iron scaffold

# publications[].label
SOLUTION AND SOLID-STATE STRUCTURES OF SALTS OF TRANS-HFE(CO)3PR3- INCLUDING A STUDY OF ALKALI CATION CONTACT ION-PAIRING

# publications[].label
CHEMISTRY OF HYDRIDO CARBONYL-6B METALATES SUBSTITUTED BY P-DONOR LIGANDS - HW(CO)4PME3- HW(CO)4POME3- HW(CO)4PPH3- AND MU-H[WM(CO)10-X(P(OME)3)X] (M=CR,W - X=1,2)

# publications[].label
REACTIONS OF PHENYLACETYLMANGANESEPENTACARBONYL WITH PHOSPHINE AND PHOSPHITE LIGANDS

# publications[].label
Activation of carbon dioxide through thiolate-bridged heterobimetallic complexes

# publications[].label
Biomimetic chemistry: Merging the old with the new.

# publications[].label
NICKEL-COMPLEXES CONTAINING N-DONOR, S-DONOR, AND O-DONOR LIGANDS

# publications[].label
EXTENT OF ASSOCIATION OF BIS(TRIPHENYLPHOSPHINE)IMINIUM CATION WITH ORGANOMETALLIC ANIONS IN TETRAHYDROFURAN SOLUTION

# publications[].label
EPR/ENDOR and DFT investigations of bioinspired [FeFe] hydrogenase model compounds

# publications[].label
THE MU-H[MO(CO)4PMEPH2]2- ANION - AN EXAMPLE OF PHOSPHINE ENHANCEMENT OF METAL-METAL INTERACTION

# publications[].label
METAL-BASED VS LIGAND BASED REACTIVITY IN PROTONATION REACTIONS OF ANIONIC IRONTHIOLATE AND SELENATE COMPLEXES - REFE(CO)3L

# publications[].label
Sulfonated diiron complexes as water-soluble models of the [Fe-Fe]-hydrogenase enzyme active site.

# publications[].label
DIVERGENT PATHWAYS FOR THE ADDITION OF DIOXYGEN TO SULFUR IN NICKEL CIS-DITHIOLATES - AN ISOTOPOMERIC ANALYSIS

# publications[].label
Comparisons of MN2S2vs. bipyridine as redox-active ligands to manganese and rhenium in (L-L)M'(CO)3Cl complexes.

# publications[].label
Mossbauer spectroscopic insights into the electronic structure and mechanism of bio-inspired iron complexes

# publications[].label
REACTIONS OF ORGANOLITHIUM AND GRIGNARD-REAGENTS WITH CYCLOPENTADIENYLIRON TRICARBONYL CATION AND ITS DERIVATIVES

# publications[].label
NIP2S2 COMPLEXES - S-ALKYLATON AND FORMATION OF NI-H, NI-CH3 AND NI-C(O)CH3 SPECIES

# publications[].label
Design of stereoselective oxygen uptake at thiolate sulfur: Step 1, a nickel thiolate template.

# publications[].label
CO-migration in the ligand substitution process of the chelating diphosphite diiron complex (mu-pdt)[Fe(CO)3][Fe(CO){(EtO)2PN(Me)P(OEt)2}].

# publications[].label
Fundamental properties of small molecule models of Fe-only hydrogenase: computations relative to the definition of an entatic state in the active site (vol 238, pg 255, 2003)

# publications[].label
Conformational Mobility and Pendent Base Effects on Electrochemistry of Synthetic Analogues of the [FeFe]-Hydrogenase Active Site

# publications[].label
Proton affinity studies of nickel N2S2 complexes and control of aggregation.

# publications[].label
Low-cost calculation and analysis of 2D IR spectra of model diiron trinitrosyl complexes in the NO stretch region with vibrational perturbation theory.

# publications[].label
Analysis of hexa- and penta-coordinate iron(II) carbonyl complexes as analogs of the [Fe]-H(2)ase (or Hmd) active site

# publications[].label
THE STRUCTURES AND REACTIONS OF BINUCLEAR MOLYBDENUM CARBONYLS BRIDGED BOTH BY HYDRIDE AND BIDENTATE PHOSPHINE-LIGANDS

# publications[].label
Fundamental properties of organometallic analogues of the 2Fe2S active site in Fe-only hydrogenase

# publications[].label
Carbon monoxide and cyanide ligands in a classical organometallic complex model for Fe-only hydrogenase

# publications[].label
The organometallic active site of [Fe]hydrogenase: models and entatic states.

# publications[].publisher
Proceedings of the National Academy of Sciences

# publications[].label
SYNTHESIS AND SPECTRAL PROPERTIES OF METAL-CARBONYL DERIVATIVES OF TETRABASIC, NONCHELATING PHOSPHATRIAZAADAMANTANE LIGAND

# publications[].label
INOR 521-Immobilized metallodithiolate ligand supports for construction of bioinorganic model complexes

# publications[].label
Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligands.

# publications[].label
Reactions of sulfur in nickel- and palladium-bound thiolates with ((1)delta)O-2: Production of metallosulfoxides and metallosulfones.

# publications[].label
S K-edge XAS and DFT calculations on Fe(III) and Ni(II) thiolate complexes: Effects of H-bonding on metal-sulfur Bond covalency

# publications[].label
A sulfur-templated Ni-Ni' coordination polymer that relies on a polarizable nickel nitrosyl hub.

# publications[].label
Ligand Displacement Reaction Paths in a Diiron Hydrogenase Active Site Model Complex.

# publications[].label
Synthesis of carboxylic acid-modified [FeFe]-hydrogenase model complexes amenable to surface immobilization

# publications[].label
ANION-ASSISTED TRANSFER OF A STERICALLY CONSTRAINED PROTON - MOLECULAR-STRUCTURE OF HMO(CO)2(PH2PCH2CH2PPH2)2+ALCL4-

# publications[].label
ELECTROCHEMICAL PROPERTIES OF MACROCYCLIC N2S2 COMPLEXES OF NI(0), (I), (II) AND (III)

# publications[].label
HYDROGENASE ACTIVE SITES: A NEW PARADIGM FOR NATURAL PRODUCT-INSPIRED SYNTHESIS BASED ON ORGANOMETALLIC CHEMISTRY

# publications[].label
Vapochromic behaviour of the solid Ni(BME-DACH) in the presence of SO2 : Structural characterization by single crystal and powder diffraction.

# publications[].publisher
International Union of Crystallography (IUCr)

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF PHOSPHINE SUBSTITUTED DERIVATIVES OF HMO2 (CO)10- AND THEIR LIGAND SUBSTITUTION-REACTION

# publications[].label
Solvo-Thermal Application for the Synthesis of [Et4N][(mu-H)Mo-2(CO)(10)] and its Bidentate Phosphine Derivatives and the X-ray Structure of (mu-Ph2P(CH2)(2)PPh2) [Mo (CO)(4)(NCCH3)]

# publications[].label
Molecular assemblies as mimics of the complete H-cluster in diiron hydrogenase

# publications[].label
Macrocylization, sulfenation, and computation explorations of the thiolate carboxyamido NiN2S2 complex Ni(ema)2-

# publications[].label
Metallodithiolate ligands as pendant base in [FeIFeI], [FeI[Fe(NO)]II] and [(mu-H)FeIIFeII] systems

# publications[].label
Linear and Bent Nitric Oxide Ligand Binding in an Asymmetric Butterfly Complex: CoMoCo'.

# publications[].label
The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N2S2O2 complexes.

# publications[].label
Models for the new bioorganometallic chemistry: molecular construction of Fe-only hydrogenase active sites

# publications[].label
Mossbauer studies of mixed-valence Fe-(II) Fe-(I) and Fe-(I) Fe-(I) model complexes illustrating states of the H-cluster in [Fe-Fe]-hydrogenases

# publications[].label
SELECTIVE REDUCTION OF ACYL CHLORIDES TO ALDEHYDES BY ANIONIC-6B TRANSITION-METAL HYDRIDES

# publications[].label
Hemilabile Bridging Thiolates as Proton Shuttles in Bioinspired H2 Production Electrocatalysts.

# publications[].label
Iron(0) mediated C-H activation of 1-hexyne: a mechanistic study using time-resolved infrared spectroscopy.

# publications[].label
TEMPERATURE AND SOLVENT DEPENDENCE OF SCALAR COUPLING-CONSTANTS IN SALTS OF TRANS-HFE(CO)3PR3-

# publications[].label
SODIUM AND LITHIUM ION ASSISTED LABILIZATION OF THE METAL HYDROGEN-BOND IN ANIONIC TRANSITION-METAL ANIONS, HW(CO)4L- (L = CO, P(OME)3)

# publications[].label
GROUP VIB ANIONIC METAL DEUTERIDES - H/D EXCHANGE AND H(D) TRANSFER-REACTIONS

# publications[].label
ALKYLATION AND SUBSTITUTION-REACTIONS OF METAL-CARBONYL ACYLATE AND CARBENE COMPLEXES

# publications[].label
REDOX BEHAVIOR OF NI(II) IN SULFUR LIGATION

# publications[].label
Nickel mediated sulfur-selenium and sulfur-sulfur bond formation

# publications[].label
Preface for Small Molecule Activation: From Biological Principles to Energy Applications. Part 3: Small Molecules Related to (Artificial) Photosynthesis.

# publications[].label
ARENE-TRANSITION METAL CHEMISTRY .2. HYDROGENATION OF METAL-ARENE AND ALLYLMETAL-ARENE COMPLEXES

# publications[].label
Critical precursors to biomimetics of the diiron hydrogenase enzyme active site: Carbon monoxide mobilized 2Fe2S carbonyl clusters

# publications[].label
MECHANISMS OF GROUP TRANSFER IN ANIONIC TRANSITION-METAL HYDRIDES AND ALKYLS

# publications[].label
SOLVENT EFFECTS ON THE OXYGENATION OF NI-BOUND THIOLATES

# publications[].label
Interplay of hemilability and redox activity in models of hydrogenase active sites.

# publications[].publisher
Proceedings of the National Academy of Sciences

# publications[].label
A TOPICAL RESEARCH APPROACH TO THE INORGANIC SYNTHESIS LABORATORY

# publications[].label
A {Fe(NO)3}10 trinitrosyliron complex stabilized by an n-heterocyclic carbene and the cationic and neutral {Fe(NO)2}(9/10) products of its NO release.

# publications[].label
SYNTHESIS OF NITROGEN AND SULFUR-CONTAINING NICKEL MACROCYCLES - POTENTIAL

# publications[].label
COMPETING NUCLEOPHILIC DISPLACEMENT AND RADICAL CHAIN REDUCTION IN REACTIONS OF TRANSITION-METAL HYDRIDE ANIONS WITH ALKYL BROMIDES

# publications[].label
Carbon Monoxide Induced Reductive Elimination of Disulfide in an N-Heterocyclic Carbene (NHC)/Thiolate Dinitrosyl Iron Complex (DNIC)

# publications[].label
RHODIUM(I) AND IRIDIUM(I) CARBONYL COMPLEXES

# publications[].label
Synthesis, structures, and electrochemical properties of nickel complexes of macrocyclic N2S2 aminothioethers

# publications[].label
Complexes of MN2S2Fe(5-C5R5)(CO) as platform for exploring cooperative heterobimetallic effects in HER electrocatalysis.

# publications[].label
Zinc/metal exchange and ligand cannibalism in N2S2O1,2 donor ligand sets: A bioinorganic approach to thiolate reactivity and coordination chemistry

# publications[].label
A matrix of heterobimetallic complexes for interrogation of hydrogen evolution reaction electrocatalysts.

# publications[].label
METAL THIOLATES AS LIGANDS - STRUCTURAL STUDIES OF CP2NB(SPH)2 AND [CP2NB(MU-SPH)2MO(CO)4+]

# publications[].label
Biomimetics of the 2Fe2S subsite of the [FeFe]Hydrogenase H cluster containing redox active ligands

# publications[].label
Regioselective (12)CO/(13)CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase.

# publications[].label
Refining the active site structure of iron-iron hydrogenase using computational infrared spectroscopy.

# publications[].label
Cyanide in the hydrogenase enzymes' active sites: A tribute to the detective powers of Albracht, Bagley, and W. Woodward.

# publications[].label
Toward the Optimization of Dinitrosyl Iron Complexes as Therapeutics for Smooth Muscle Cells.

# publications[].label
ANIONIC GROUP-6 HYDRIDES AND CARBOXYLATES AS HOMOGENEOUS CATALYSTS FOR REDUCTION OF ALDEHYDES AND KETONES

# publications[].label
Time resolved infrared spectroscopy: kinetic studies of weakly binding ligands in an iron-iron hydrogenase model compound.

# publications[].label
Organometallics in biology: Mossbauer spectroscopy of iron models for the active site of the hydrogenase

# publications[].label
Oxidative addition of phosphine-tethered thiols to iron carbonyl: binuclear phosphinothiolate complexes, (mu-SCH(2)CH(2)PPh(2))(2)Fe(2)(CO)(4), and hydride derivatives.

# publications[].label
A single carbon atom controls the geometry and reactivity of CoII(N2S2) complexes.

# publications[].label
INOR 711-Synthesis, molecular structure, and characterization of an S=3/2 trigonal paddlewheel complex: {[(C9H18N2S2)Fe(NO)]Ag-2}(BF4)(2)

# publications[].label
Triplet, high-spin, linear {Fe(NO)} 8: Redox feature of a stable diiron trinitrosyl complex

# publications[].label
NiN(2)S(2) complexes as metallodithiolate ligands to Rh(I), Rh(II) and Rh(III).

# publications[].label
Mossbauer spectroscopy and electronic structure of bimetallic iron-nitrosyl complexes

# publications[].label
Synthetic support of de novo design: sterically bulky [FeFe]-hydrogenase models.

# publications[].label
Ambidentate thiocyanate ligand in dinitrosyl iron complexes

# publications[].label
SYNTHESIS OF GROUP V SUBSTITUTED DERIVATIVES OF IRON PENTACARBONYL IN HIGH-YIELD

# publications[].label
Heterogenization of a Water-Insoluble Molecular Complex for Catalysis of the Proton-Reduction Reaction in Highly Acidic Aqueous Solutions

# publications[].label
THE REACTION OF (CY3P)2NI(H)(CH3) WITH CARBON-DIOXIDE - FORMATION OF A HYDRIDONICKEL FORMATE COMPLEX, HNI(O2CH)(CY3P)2

# publications[].label
ANIONIC GROUP-6 TRANSITION-METAL CARBONYL HYDRIDES AS REDUCING AGENTS - KETONES, ALDEHYDES, AND EPOXIDES

# publications[].label
METAL-CARBON BONDS IN ENZYMES AND COFACTORS, vol 6

# publications[].label
HYDRIDE THIOLATE DERIVATIVES OF LOW VALENT IRON COMPLEXES

# publications[].label
Modeling geometries and infrared spectroscopic properties of iron dinitrosyl iron complexes (DNICs): Determining a methodology via functional and basis set

# publications[].label
Discrete Air-Stable Nickel(II) Palladium(II) Complexes as Catalysts for Suzuki-Miyaura Reactions

# publications[].label
Electronic and molecular structures of active sites in [FeFe] hydrogenase and biomimetic model complexes

# publications[].label
LIGAND BASED REACTIVITY IN OXYGENATION DEOXYGENATION OF NICKEL THIOLATES

# publications[].label
STEREOCHEMICAL COURSE OF REACTIONS LEADING TO FORMATION OF MONO-LIGATED (PHENYLACETYL)MANGANESE TETRACARBONYL COMPOUNDS

# publications[].label
PREPARATION OF A STEREOSPECIFICALLY CO-13-LABELED [(MU-H)[MO(CO)5]2]- SPECIES AND ANALYSIS OF ITS CO STRETCHING VIBRATIONAL MODES

# publications[].label
Sustainable Synthesis of Polycarbonates and Polythiocarbonates from Biomass-Based Eugenol-Furoic Acid-Derived Monomer and CO2 and COS: Computational Insights

# publications[].label
Better than platinum? Fuel cells energized by enzymes.

# publications[].publisher
Proceedings of the National Academy of Sciences

# publications[].label
Molecular constructs as [FeFe]-H(2)ase enzyme active site: Biomimetics for proton reduction

# publications[].label
INSERTION OF ACRYLONITRILE INTO ANIONIC TRANSITION-METAL HYDRIDE BONDS - A MODEL FOR HOMOGENEOUS OLEFIN PROCESSES

# publications[].label
THE HYDRIDE TRANSFER ABILITY OF A NEUTRAL HYDRIDE (ETA-5-C5H5)2NB(H)CO

# publications[].label
Structural and electrochemical comparison of Ni-II in an N2S2 plane with two, one and no axial ligands: Isolation and characterization of a five-coordinate nickel(II) complex

# publications[].label
Cyano[tri(cyclohexyl)phosphino]gold(I), [Au(CN){(C<inf>6</inf>H<inf>11</inf>)<inf>3</inf>P}]

# publications[].label
H-2 uptake and H-2 production catalysis by organometallic models of the active site of [Fe]-H(2)ase.

# publications[].label
CARBONYL LIGAND LABILITY IN MU-H[CR(CO)5]2(-) ANION

# publications[].label
Synthesis, structure and reactivity of thiolate-bridged {Fe(NO)2}9 dimers with a pendant thiol

# publications[].label
Connecting Main-Group Metals (Al, Ga, In) and Tungsten(0) Carbonyls via the N2S2 Metallo-Ligand Strategy

# publications[].label
Controlling O2 Reactivity in Synthetic Analogues of [NiFeS]- and [NiFeSe]-Hydrogenase Active Sites.

# publications[].label
Activation of alkenes and H2 by [Fe]-H2ase model complexes.

# publications[].label
A kinetic study of the ring-opening process in tungsten carbonyl complexes containing hemilabile metallodithiolate ligands.

# publications[].label
Catalysis and Mechanism of H2 Release from Amine-Boranes by Diiron Complexes.

# publications[].label
Mossbauer studies of multimetallic assemblies of complexes with different spin states

# publications[].label
Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni

# publications[].label
Heterolytic and homolytic S-C bond cleavage reactions in nickel thioether complexes.

# publications[].label
Synthesis of carbene ligands from amino acids and attachment to various small-molecule analogs of iron biomolecules

# publications[].label
REACTIVITY, STRUCTURE, AND STABILITY STUDIES OF CP2NB(SR)2, CP2V(SR)2, CP2TI(SR)2 COMPLEXES

# publications[].label
Computational definition of a mixed valent Fe(II)Fe(I) model of the [FeFe]hydrogenase active site resting state.

# publications[].label
Structure/function analysis of a series of bimetallic, hydrogenase-inspired, HER electrocatalysts

# publications[].publisher
International Union of Crystallography (IUCr)

# publications[].label
NATURE OF INTERMEDIATE PROCREATED IN SUBSTITUTION REACTIONS OF GROUP-VI METAL CARBONYLS

# publications[].label
INFRARED DETERMINATION OF STEREOCHEMISTRY IN METAL-COMPLEXES - DETERMINATION OF SYMMETRY COORDINATES

# publications[].label
N,N-Bis(Mercaptoethyl)-1,4-Diazacycloheptane (H₂BME-DACH) and its Nickel Complex: A Model for Bioinorganic Chemistry

# publications[].label
INTERACTIONS OF CPM'(CO)3-(M' = CR, MO, W) WITH CATIONS - EFFECTS ON CO EXCHANGE AND RX ADDITION-REACTIONS

# publications[].label
ELECTRON-PARAMAGNETIC-RES SPECTRUM OF THE ION-PAIR [CR(CO)5-]2 IN IRRADIATED CRYSTALS OF PPH4 + HCR(CO)5-

# publications[].label
Sulfur oxygenates of biomimetics of the diiron subsite of the [FeFe]-hydrogenase active site: properties and oxygen damage repair possibilities.

# publications[].label
The hydrophilic phosphatriazaadamantane ligand in the development of H2 production electrocatalysts: iron hydrogenase model complexes.

# publications[].label
Hyperfine Structure of Monovalent Iron in Hydrogenase Models: Mossbauer and Density Functional Studies

# publications[].label
Correlation between computed gas-phase and experimentally determined solution-phase infrared spectra: models of the iron-iron hydrogenase enzyme active site.

# publications[].label
SYNTHESIS AND REACTIVITY OF THIOLATE DERIVATIVES OF ANIONIC IRON CARBONYLS, RSFE(CO)4-

# publications[].label
Synthesis and Mssbauer characterization of octahedral iron(II) carbonyl complexes FeI2(CO)3L and FeI2(CO)2L2: developing models of the [Fe]-H(2)ase active site.

# publications[].label
Regioselectivity in ligand substitution reactions on diiron complexes governed by nucleophilic and electrophilic ligand properties.

# publications[].label
H/D exchange reactions in dinuclear iron thiolates as activity assay models of Fe-H2ase.

# publications[].label
Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites.

# publications[].label
Models for metal-bound cysteine modification by iodoacetamide and iodoacetic acid.

# publications[].label
COMPLEXATION OF ORGANOTIN HALIDES WITH AMBIDENTATE, S, N, AND O DONOR LIGANDS

# publications[].label
Deciphering the mechanism of carbon monoxide induced elimination of disulfide from a dinitrosyl iron complex: Hammett correlations of a series of para substituted (NHC)(SPhX) Fe(NO)(2) compounds

# publications[].label
Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M = Fe, Co) as metallodithiolate ligands

# publications[].label
INFRARED, CONDUCTANCE, AND KINETIC EVIDENCE FOR ALKALI-METAL ION INTERACTIONS WITH DERIVATIVES OF MANGANESE CARBONYLATES

# publications[].label
REACTION OF IRON PENTACARBONYL WITH OXYGEN-18-ENRICHED HYDROXIDE - DECARBOXYLATION VS OXYGEN-EXCHANGE IN THE [FE(COOH]) INTERMEDIATE

# publications[].label
Comparisons of zinc with cadmium in N2S2 coordination and as S-bonded adducts to tungsten carbonyls.

# publications[].label
Synthesis and dimer cleavage reactions of the N<inf>2</inf>S thiolate bridged dimer [(mmp-dach)<inf>2</inf>Ni<inf>2</inf>]Cl<inf>2</inf>

# publications[].label
COMPARISONS OF THE HETEROBIMETALLIC AND HETEROTRIMETALLIC ANIONS HFEW(CO)9- AND PH3PAUFEW(CO)9-

# publications[].label
MONONUCLEAR PENTACARBONYL HYDRIDES OF CHROMIUM, MOLYBDENUM, AND TUNGSTEN

# publications[].label
Ion Pairing Effects on Transition Metal Carbonyl Anions

# publications[].label
SOLUTION AND SOLID-STATE STRUCTURES OF SALTS OF TRANS-HFE(CO)3PR3- INCLUDING A STUDY OF ALKALI CATION CONTACT ION-PAIRING

# publications[].label
N-heterocyclic carbene ligands as mimics of imidazoles/histidine for the stabilization of di- and trinitrosyl iron complexes.

# publications[].label
TRANSITION-METAL COMPLEXES OF PENDANT ARM DERIVATIVES OF 1,5-DIAZACYCLOOCTANE

# publications[].label
ISOLATION OF CHROMIUM(0) THIOLS - MOLECULAR-STRUCTURE OF (BUTSH)CR(CO)5

# publications[].label
Iron nitrosyl complexes as models for biological nitric oxide transfer reagents.

# publications[].label
Control of S-based aggregation: designed synthesis of NiM2 and Ni2M trinuclear complexes.

# publications[].label
ELECTRON-PARAMAGNETIC RESONANCE AND ELECTROCHEMICAL STUDY OF THE OXIDATION CHEMISTRY OF MONONUCLEAR AND BINUCLEAR CHROMIUM CARBONYL THIOLATES

# publications[].label
Oxygen capture by sulfur in nickel thiolates

# publications[].label
Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity.

# publications[].label
Synthesis and Dimer Cleavage Reactions of the N(2)S Thiolate Bridged Dimer [(mmp-dach)(2)Ni(2)]Cl(2).

# publications[].label
Organometallic models of the iron site in [NiFe] hydrogenases

# publications[].label
Nitric oxide transfer between nominal Fe and Co biomimetics of the nitrile hydratase active site.

# publications[].label
Models of sulfur reactivity in [NiFe] and [FeFe] hydrogenases

# publications[].label
Electronic effects of metallodithiolate ligands on [FeFe]-H(2)ase active site model compounds

# publications[].label
Analysis of a pentacoordinate iron dicarbonyl as synthetic analogue of the Hmd or mono-iron hydrogenase active site.

# publications[].label
Development of (NO)Fe(N2S2) as a Metallodithiolate Spin Probe Ligand: A Case Study Approach.

# publications[].label
An experimental and computational study of sulfur-modified nucleophilicity in a dianionic NiN2S2 complex.

# publications[].label
N2S2Ni metallodithiolate complexes as ligands: structural and aqueous solution quantitative studies of the ability of metal ions to form M-S-Ni bridges to mercapto groups coordinated to nickel(II). implications for acetyl coenzyme A synthase.

# publications[].label
CONFORMATIONS OF (ETA-5-C5H5)2NB(S-P-C6H4X)2(0,1) - RESPONSIVENESS TO PARA-SUBSTITUENTS ON ARYL GROUPS AND TO D-ELECTRON COUNT

# publications[].label
INOR 104-Imidazole-containing Ni(N3S) complexes: Structural and electronic comparisons to the NiSOD active site

# publications[].label
Adamantane-like cluster complexes of mixed-valent copper-copper and nickel-copper thiolates.

# publications[].label
Dinitrosyl iron complexes (DNICs) as inhibitors of the SARS-CoV-2 main protease.

# publications[].label
CHROMIUM, MOLYBDENUM AND TUNGSTEN ANNUAL SURVEY COVERING YEAR 1973

# publications[].label
Electrocatalytic O reduction by [Fe-Fe]-hydrogenase active site models.

# publications[].label
Organometallic exchange reactions. X. Cross-association of tert butyllithium. Kinetics of tert butyllithium dissociation

# publications[].label
OLEFIN ISOMERIZATION CATALYSIS BY HETEROBIMETALLIC HYDRIDES, HFEM(CO)8L- (M = CR, MO, W-L = CO, PR3)

# publications[].label
X-ray structure of [Nb(eta(5) -C5H5)(2)(SCH2CH2CH2S]. ECP quantum chemistry of niobium five and six metallacycle complexes

# publications[].label
BINUCLEAR REDUCTIVE ELIMINATION OF WATER - NEW ROUTE TO THE (TRIPHENYLSTANNYL)PENTACARBONYLTUNGSTEN ANION, PH3SNW(CO)5-

# publications[].label
Reactions of transition metal carbonyls with nucleophilic reagents: reactivity and bonding

# publications[].label
MAKING THE RIGHT CHOICES-OR, THE CHOICES RIGHT

# publications[].label
Electronic effects of a bridging FeII-Cyanide on {Fe(NO)2}9/10 scaffolds for possible linkage isomerization

# publications[].label
Synthesis and structural characterization of heteronuclear clusters comprised of nickel and copper bridged by thiolates

# publications[].label
STRUCTURAL CHARACTERIZATIONS OF SALTS OF HCR(CO)5- AND (MU-H)2BH2CR(CO)4- AND STUDIES OF THEIR INTERCONVERSIONS

# publications[].label
Zinc/nickel exchange and ligand cannibalism in N2S2O(1,2) donor ligand sets.

# publications[].label
Approaches to quantifying the electronic and steric properties of metallodithiolates as ligands in coordination chemistry

# publications[].label
Unmasking the interplay of redox-active and hemi-labile ligands in proton reduction electrocatalysis: Synthesis and characterization of a matrix of MN2S2-M' complexes

# publications[].label
Accommodation of the irregular coordination geometry of lead(II) by a square planar N2S2 ligand and its preference for zinc(II).

# publications[].label
Mixed signals from the black box of an enzyme active site: Small molecule models for (NiFe)hydrogenase

# publications[].label
Unique reactivity of a tetradentate N(2)S(2) complex of nickel: intermediates in the production of sulfur oxygenates.

# publications[].label
ALTERNATE SYNTHETIC ROUTES TO THE MONONUCLEAR PENTACARBONYL HYDRIDES OF CR, MO, AND W

# publications[].label
Bidentate dithiolato-dinitrosyl iron complexes: More diatomic ligands in biology.

# publications[].label
Coordination sphere flexibility of active-site models for Fe-only hydrogenase: studies in intra- and intermolecular diatomic ligand exchange.

# publications[].label
Carbon monoxide induced elimination of disulfide from dinitrosyl iron complexes: Hammett correlations of para-substituted [(NHC)Fe(NO)(2)S(p-PhX)] compounds

# publications[].label
A REACTIVITY STUDY OF ANIONIC TRANSITION-METAL HYDRIDES, HCR(CO)5-, HW(CO)5-, CIS-HW(CO)4P(OME)3- - THE HYDRIDE HALIDE DISPLACEMENT REACTION

# publications[].label
PREPARATIONS AND STRUCTURES OF A ZINC(II) DIMER AND ZINC(II) NICKEL(II) PENTANUCLEAR DERIVATIVES OF N,N'-BIS(MERCAPTOETHYL)-1,5-DIAZACYCLOOCTANE - [(BME-DACO)ZN]2 AND ([(BME-DACO)NI]3[ZNCL]2)(BF4)2

# publications[].label
A new macrocyclic N3S2 ligand and its nickel(II), cobalt(II), rhodium(III)-103, and rhodium(III)-105 complexes

# publications[].label
Series of mixed valent Fe(II)Fe(I) complexes that model the Hox state of [FeFe]hydrogenase: redox properties, density-functional theory investigation, and reactivities with extrinsic CO.

# publications[].label
STUDY OF SULFINATE AND SULFENATE COMPLEXES DERIVED FROM THE OXYGENATION OF THIOLATE SULFUR IN [1,5-BIS(2-MERCAPTO-2-METHYLPROPYL)-1,5-DIAZATYCLOOCTANATO(2-)]NICKEL(II) (VOL 117, PG 963, 1995)

# publications[].label
Analysis of an organometallic iron site model for the heterodimetallic unit of [NiFe]hydrogenase

# publications[].label
Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase.

# publications[].label
James T. Grady-James H. Stack Award for Interpreting Chemistry for the Public: Sir Martyn Poliakoff

# publications[].label
Site specific redox properties in ligand differentiated di-nickel complexes inspired by the acetyl CoA synthase active site.

# publications[].label
ADDITION OF ACRYLONITRILE TO ANIONIC TRANSITION-METAL HYDRIDES - AN IONIC MODEL FOR HOMOGENEOUS OLEFIN PROCESSES

# publications[].label
Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes.

# publications[].label
STEREOCHEMICAL NONRIGIDITY IN HETEROBIMETALLIC COMPLEXES CONTAINING THE BENT METALLOCENE THIOLATE FRAGMENT

# publications[].label
Effects of Glutathione and Histidine on NO Release from a Dimeric Dinitrosyl Iron Complex (DNIC).

# publications[].label
CONDUCTIVITY STUDIES OF ION-PAIRING IN TRANSITION-METAL ORGANICS

# publications[].label
REDUCTION-PROMOTED SULFUR-OXYGEN BOND-CLEAVAGE IN A NICKEL SULFENATE AS A MODEL FOR THE ACTIVATION OF [NIFE] HYDROGENASE

# publications[].label
A COMPARISON OF THE LEAVING GROUP ABILITY OF TRANSITION-METAL CARBONYL ANIONS VS HALIDES - REACTION OF MH- WITH M'-R (MH- = HW(CO)4P(OME)3-, HW(CO)5-, HCR(CO)5-, M'-R = CPMO(CO)3(CH3), CPMO(CO)3[CH2CH(CH2)2])

# publications[].label
Cyanide-bridged iron complexes as biomimetics of tri-iron arrangements in maturases of the H cluster of the di-iron hydrogenase.

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF A STABLE IRON(II) HYDRIDE THIOLATE COMPLEX - (PHS)FE(H)(CO)2(P(OPH)3)2

# publications[].label
S K-edge X-ray absorption spectroscopy and density functional theory studies of high and low spin {FeNO}7 thiolate complexes: exchange stabilization of electron delocalization in {FeNO}7 and {FeO2}8.

# publications[].label
Metallodithiolates as ligands to dinitrosyl iron complexes: toward the understanding of structures, equilibria, and spin coupling.

# publications[].label
Nickel-iron heterobimetallics bridged by thiolates: Prototypes for CO binding to iron(0) and iron(II) in [NiFe]H(2)ase.

# publications[].label
Bismercaptoethanediazacyclooctane as a N2S2 chelating agent and Cys-X-Cys mimic for Fe(NO) and Fe(NO)2.

# publications[].label
STERICALLY PROTECTED NICKEL(II) IN A N2S2 DONOR ENVIRONMENT - 1,5-BIS(MERCAPTOETHYL)-1,5-DIAZACYCLOOCTANE AND ITS METHYLATED DERIVATIVE

# publications[].label
REACTIONS OF ANIONIC TRANSITION-METAL CARBONYL HYDRIDES WITH ELECTROPHILIC METAL-CARBONYLS - NUCLEOPHILIC-ADDITION (HYDRIDE TRANSFER) VS ELECTRON-TRANSFER MECHANISMS

# publications[].label
SYNTHESIS AND CHARACTERIZATION OF THE ELECTRON-RICH IRON HYDRIDE HFE(CO)2(P(OPH)3)2- AND ITS LIGAND-BASED REDOX SUBSTITUTION WITH THIOLATES

# publications[].label
Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC).

# publications[].label
ARENE-TRANSITION METAL CHEMISTRY - SYNTHESIS, STRUCTURE AND CATALYSIS

# publications[].label
Influence of Sulfur Metalation on the Accessibility of the Ni(II/I) Couple in [N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase.

# publications[].label
LIGAND LABILITY STUDIES IN BRIDGING HYDRIDE COMPLEXES OF GROUP 6B METAL CARBONYLATES

# publications[].label
Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process.

# publications[].label
ORGANOMETALLIC FUNCTIONALITIES AT SULFUR-BOUND NICKEL - P2S2 VS N2S2 LIGAND ENVIRONMENTS

# publications[].label
Hyperfine interactions and electron distribution in Fe(II)Fe (I) and Fe (I)Fe (I) models for the active site of the [FeFe]hydrogenases: Mssbauer spectroscopy studies of low-spin Fe(I.).

# publications[].label
APPLICATIONS OF THE N2S2 LIGAND, N,N'-BIS(MERCAPTOETHYL)-1,5-DIAZACYCLOOCTANE, TOWARD THE FORMATION OF BIMETALLICS AND HETEROMETALLICS - [(BME-DACO)FE]2 AND [(BME-DACO)NIFECL2]2

# publications[].label
Measurements of degenerate radical ion-neutral molecule electron exchange by microsecond time-resolved CIDNP. Determination of relative hyperfine coupling constants of radical cations of chlorophylls and derivatives

# publications[].label
Dual electron uptake by simultaneous iron and ligand reduction in an N-heterocyclic carbene substituted [FeFe] hydrogenase model compound.

# publications[].label
STUDIES USING (N-BU)3P=O AS A CARBON-MONOXIDE LABILIZING LIGAND IN THE SYNTHESIS OF METAL-CARBONYL-COMPLEXES HIGHLY ENRICHED IN (CO)-C-13

# publications[].label
BINUCLEAR MOLYBDENUM CARBONYLS BRIDGED BOTH BY HYDRIDE AND BY BIDENTATE PHOSPHINE-LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF SALTS OF (MU-H)(MU-PH2P(CH2)NPPH2)MO2(CO)8-(N=1-4) AND THEIR REACTIONS WITH ACIDS

# researcherOn[].label
AGEP-T: Collaborative Research: Advancing Interdisciplinary STEM Graduate Education in Energy and Sustainability Disciplines

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].label
REU Site: Sustainable Chemistry at Texas A&M University

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].label
Development of Polycarbonate Micelles for Encapsulation of Dinitrosyl Iron and Diiron Hydrogenase Biomimetics

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].label
Biomimetics of the [FeFe]-H2ase enzyme active site (EAS)

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# streetAddress
Texas A&M University; Chemistry Department; 3255 TAMU

# organizations[]
Texas A&M Engineering Experiment Station (TEES)

# schools[]
Texas A&M Engineering Experiment Station (TEES)

# inTheNews[].label
Texas A&M Chemist Karen Wooley Elected To National Academy Of Sciences

# inTheNews[].label
Research Honor Society Sigma Xi Recognizes 3 Texas A&M Faculty Members

# inTheNews[].label
Texas A&M chemists working on drugs to treat COVID-19

# etdChairOf[].label
Ghosh, Pokhraj (2017-12). Hemi-Labile, Redox Active Metallodithiolates as Ligands for Bioinspired Proton Reduction Catalysts. Doctoral Dissertation.

# etdChairOf[].label
Fitch, Shawn (2010-07). DEVELOPMENT AND MECHANISTIC STUDIES OF THE CHROMIUM TETRAMETHYLTETRAAZAANNULENE CATALYST SYSTEM FOR THE COPOLYMERIZATION OF CARBON DIOXIDE AND EPOXIDES. Doctoral Dissertation.

# etdChairOf[].label
Hess, Jennifer (2011-12). Bioinspired Synthesis and Reactivity Studies of Nitric Oxide Iron Complexes. Doctoral Dissertation.

# etdChairOf[].label
Lunsford, Allen Michael (2016-12). Bridging Thiolates in Metalloenzymes: From Model Complexes to Catalytic Small Molecule Activation. Doctoral Dissertation.

# etdChairOf[].label
Singleton, Michael Lee (2012-02). Effect of Secondary Interactions on the Fundamental Properties of Small Molecule Models of the Diiron Hydrogenase Active Site. Doctoral Dissertation.

# etdChairOf[].label
Pinder, Tiffany (2013-12). Development of Metallodithiolates as a New Class of Versatile Ligands to Transition Metals. Doctoral Dissertation.

# etdChairOf[].label
Chupik, Rachel Beth (2017-12). Developments in the Understanding of the Dinitrosyl Iron Unit: Its Stabilization, Reactivity, and Nitric Oxide Release. Doctoral Dissertation.

# etdChairOf[].label
Young, Mark D. (2010-01). Expanded Use of Bicyclic Guanidinate Ligands in Dimetal Paddlewheel Compounds. Doctoral Dissertation.

# etdChairOf[].label
Rampersad, Marilyn Vena (2005-12). The development of N2S2 metal complexes as bidentate ligands for organometallic chemistry. Doctoral Dissertation.

# etdChairOf[].label
Almaraz, Elky (2009-05). The Interactions of Zinc Thiolate Complexes and Exogenous Metal Species: Investigations of Thiolate Bridging and Metal Exchange. Doctoral Dissertation.

# etdChairOf[].label
Jenkins, Roxanne Michelle (2010-05). Studies in Bioinorganic Chemistry: Synthesis and Reactivity of Nickel and Vanadyl NxSy Complexes. Doctoral Dissertation.

# etdChairOf[].label
Pulukkody, Randara (2015-08). Synthetic Analogues of Dinitrosyl Iron Complexes: Reactivity Studies and Improvements towards Therapeutic Applications. Doctoral Dissertation.

# etdChairOf[].label
Foley, William (2011-02). The Interactions and Exchanges of Metal-bound Sulfur Containing Ligands with Various Transition Metals. Master's Thesis.

# etdChairOf[].label
Chiang, Chao-Yi (2003-05). N2s2 chelating agents as cys-x-cys biomimics for fe(no) and fe(no)2 complexes. Doctoral Dissertation.

# etdChairOf[].label
Green, Kayla Nalynn (2007-12). Immobilized metallodithiolate ligand supports for construction of bioinorganic model complexes. Doctoral Dissertation.

# etdChairOf[].label
Tye, Jesse Wayne (2009-05). Explorations of iron-iron hydrogenase active site models by experiment and theory. Doctoral Dissertation.

# etdChairOf[].label
Crouthers, Danielle Jerine (2015-08). Synthetic Analogues of the Diiron Hydrogenase Enzyme Active Site and Possible Primordial H2-Producing Catalysts. Doctoral Dissertation.

# etdChairOf[].label
Bethel, Ryan D (2014-12). The Bioorganometallic Chemistry of Iron and the Diatomic Ligands CO and NO as Related to Hydrogenase Active Sites and Dinitrosyl Iron Complexes. Doctoral Dissertation.

# etdChairOf[].label
Brothers, Scott Michael (2011-12). Computational Benchmarking in Biomimetic Nickel, Copper, and Iron Complexes. Doctoral Dissertation.

# etdChairOf[].label
Denny, Jason Adam (2015-06). The Uptake, Transport, and Storage of Nickel in Cells: A Modeling Study of MN2S2 Complexes and Their Derivatives. Doctoral Dissertation.

# etdChairOf[].label
Liu, Tianbiao (2009-12). Organometallic Complexes that Model the Active Sites of the [FeFe]- and [Fe]-Hydrogenases. Doctoral Dissertation.

# etdChairOf[].label
Mejia Rodriguez, Ma. del Rosario (2005-05). Ligand effects on bioinspired iron complexes. Doctoral Dissertation.

# etdChairOf[].label
Ding, Shengda (2017-12). The Computational Modeling of Organometallic Compounds and Reactions Inspired By Hydrogenases. Doctoral Dissertation.

# etdChairOf[].label
Jeffery, Stephen Paul (2006-05). Metallodithiolate ligands as building blocks for molecular constructions. Doctoral Dissertation.

# etdChairOf[].label
Zhao, Qinliang (2009-05). Conformation and electronic configuration of complexes with multiple dimetal units. Doctoral Dissertation.

# etdChairOf[].label
Golden, Melissa Lynn (2002-05). The bioinorganic chemistry of N2S2 metal complexes: reactivity and ligating ability. Doctoral Dissertation.