# positions[].organizations[].parent[].label
Texas A&M Engineering Experiment Station (TEES)

# overview
Our research focuses on inorganic molecular approaches to contribute to the development of novel systems for solar to energy conversion, small molecule activation, and molecules for information storage. Synthetic methods build the foundation of the group and are complimented by a broad array of spectroscopic and electrochemical techniques.

We are seeking students who are interested in creative inorganic synthesis, structure-function relationships in catalysis, electronic structure of heterometallic d-block/f-block complexes, and molecular species with unusual charges.

# keywords[]
3403 Macromolecular And Materials Chemistry

# educationAndTraining[].organization.label
University of Wisconsin - Madison - (Madison, Wisconsin, United States)

# educationAndTraining[].organization.label
Technical University of Berlin - (Berlin, Germany)

# awardsAndHonors[].label
Faculty Early Career Development (CAREER) Program

# publications[].label
Towards a comprehensive understanding of visible-light photogeneration of hydrogen from water using cobalt(II) polypyridyl catalysts

# publications[].label
Cobalt Polypyridyl Complexes as Transparent SolutionProcessable Solid- State Charge Transport Materials

# publications[].label
Magnetization dynamics in heterometallic lanthanide: Transition metal complexes

# publications[].label
Do Metal-Metal Multiply-Bonded "Ligands" Have a trans Influence? Structural and Magnetic Comparisons of Heterometallic Cr Cr center dot center dot center dot Co and Mo Mo center dot center dot center dot Co Interactions

# publications[].label
Mechanistic study for the reduction of CO2 to CO using M[bpyMe(ImMe)](CO)3Cl]+ complexes: Probing the role of the imidazolium moiety in the secondary coordination sphere

# publications[].label
Trends in trigonal prismatic Ln-[1]ferrocenophane complexes and discovery of a Ho3+ single-molecule magnet.

# publications[].label
Modulating electrocatalytic CO2 reduction via secondary coordination sphere functional groups

# publications[].label
Structure and Magnetization Dynamics of DyFe and DyRu Bonded Complexes

# publications[].label
Dinuclear Cobalt Complexes with a Decadentate Ligand Scaffold: Hydrogen Evolution and Oxygen Reduction Catalysis.

# publications[].label
Enabling Light-Driven CO2 Removal from Seawater using Metastable Photoacids

# publications[].label
Oxidative stretching of metal-metal bonds to their limits.

# publications[].label
Tuning Second Coordination Sphere Interactions in Polypyridyl–Iron Complexes to Achieve Selective Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide

# publications[].label
Group 6 complexes with iron and zinc heterometals: understanding the structural, spectroscopic, and electrochemical properties of a complete series of MMM' compounds.

# publications[].label
Exchange coupling and magnetic blocking in bipyrimidyl radical-bridged dilanthanide complexes.

# publications[].label
Magnetization dynamics of a heterometallic Dy-isocarbonyl complex

# publications[].label
Oxidation chemistry of axially protected Mo(2) and W(2) quadruply bonded compounds.

# publications[].label
Crystals in which some metal atoms are more equal than others: inequalities from crystal packing and their spectroscopic/magnetic consequences.

# publications[].label
Computational modeling of rhenium electrocatalysts featuring charged functional groups in the secondary coordination sphere for CO2 reduction

# publications[].label
Lanthanide-based single-molecule magnets with high blocking temperatures

# publications[].label
Strong exchange coupling in radical-bridged dilanthanide complexes

# publications[].label
Metallocenophane chemistry of the lanthanides: Structure and Magnetism

# publications[].label
Tuning Second Coordination Sphere Interactions in PolypyridylIron Complexes to Achieve Selective Electrocatalytic Reduction of Carbon Dioxide to Carbon Monoxide

# publications[].label
A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands.

# publications[].label
A Caged Neutral 17-Valence-Electron Iron(I) Radical [Fe(CO)2(Cl)(P((CH2)10)3P)]: Synthetic, Structural, Spectroscopic, Redox, and Computational Studies.

# publications[].label
Zero-field slow magnetic relaxation in radical-bridged dilanthanide complexes

# publications[].label
Structure and Magnetization Dynamics of Dy-Fe and Dy-Ru Bonded Complexes.

# publications[].label
Computational modeling of molecular electrocatalysts featuring N-heterocyclic carbenes for carbon dioxide reduction

# publications[].label
Slow magnetization of axial Dy(III) complexes and their relaxation in zero field

# publications[].label
Manipulation of the exchange coupling in dilanthanide radical-bridged complexes

# publications[].label
Computational study for the mechanism of CO2 reduction using imidazolium-functionalized Rhenium electrocatalysts

# publications[].label
Introducing a metal-metal multiply bonded group as an "axial ligand" to iron: synthetic design of a linear Cr-Cr...Fe framework.

# publications[].label
INOR 702-Quadruply bonded metal-metal units as axial ligands in "octahedral" transition metal complexes

# publications[].label
Heterometallic lanthanide-transition metal gomplexes: Synthesis, magnetism, and redox properties

# publications[].label
Slow Magnetic Relaxation in a Lanthanide-[1]Metallocenophane Complex.

# publications[].label
Supercharging electrocatalysts for carbon dioxide reduction

# publications[].label
Exchange coupling and magnetic blocking in dilanthanide complexes bridged by the multi-electron redox-active ligand 2,3,5,6-tetra(2-pyridyl)pyrazine

# publications[].label
Catalytic proton reduction with transition metal complexes of the redox-active ligand bpy2PYMe

# publications[].label
Electrocatalytic CO2 reduction by imidazolium-functionalized molecular catalysts at mild potentials

# publications[].label
A well-defined terminal vanadium(III) oxo complex.

# publications[].label
Lanthanide-based single-molecule magnets with high blocking temperatures

# publications[].label
Transition metal redox switches for reversible "on/off" and "slow/fast" single-molecule magnet behaviour in dysprosium and erbium bis-diamidoferrocene complexes.

# publications[].label
Synthesis of Magnetite Nanorods from the Reduction of Iron Oxy-Hydroxide with Hydrazine.

# publications[].label
Kinetic Versus Thermodynamic Metalation Enables Synthesis of Isostructural Homo- and Heterometallic Trinuclear Clusters

# publications[].label
Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium and Terbium[1]Ruthenocenophane Complexes

# publications[].label
A comparative study of magnetization dynamics in dinuclear dysprosium complexes featuring bridging chloride or trifluoromethanesulfonate ligands.

# publications[].label
Stable dye-sensitized solar cell electrolytes based on cobalt(II)/(III) complexes of a hexadentate pyridyl ligand.

# publications[].label
Remote effects of axial ligand substitution in heterometallic CrCrM chains.

# publications[].label
Lanthanide-based single-molecule magnets with high blocking temperatures

# publications[].label
Chemically reversible four-electron oxidation and reduction utilizing two inorganic functional groups.

# publications[].label
Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium‐ and Terbium‐[1]Ruthenocenophane Complexes

# publications[].label
Remarkable regioselectivity in the preparation of the first heterotrimetallic Mo[quadruple bond]W...Cr chain.

# publications[].label
Towards understanding of lanthanide-transition metal bonding: investigations of the first Ce-Fe bonded complex.

# publications[].label
Kinetic Versus Thermodynamic Metalation Enables Synthesis of Isostructural Homo- and Heterometallic Trinuclear Clusters

# publications[].label
Selective electrocatalytic CO2 reduction by a polypyridyl-iron complex

# publications[].label
Hard Single-Molecule Magnet Behavior by a Linear Trinuclear Lanthanide-[1]Metallocenophane Complex.

# publications[].label
Efficient Redox-Neutral Photocatalytic Formate to Carbon Monoxide Conversion Enabled by Long-Range Hot Electron Transfer from Mn-Doped Quantum Dots.

# publications[].label
New single-molecule magnets with high blocking temperatures

# publications[].label
New single-molecule magnets with high blocking temperatures

# publications[].label
Unsupported Lanthanide-Transition Metal Bonds: Ionic vs Polar Covalent?

# publications[].label
Synergistic Effects of Imidazolium-Functionalization on fac-Mn(CO)3 Bipyridine Catalyst Platforms for Electrocatalytic Carbon Dioxide Reduction

# publications[].label
Kinetic versus thermodynamic metalation enables synthesis of isostructural homo- and heterometallic trinuclear clusters.

# publications[].label
Unusual multinuclear complexes and design strategies for molecular electrocatalysts for proton reduction

# publications[].label
Nickel-Borolide Complexes and Their Complex Electronic Structure.

# publications[].label
Recent advances in f-block metallocenophane chemistry: Development of mono- and multi-lanthanide-[1]ferrocenophane single-molecule magnets

# publications[].label
Applications of coordination chemistry in the synthesis of single-molecule magnets

# publications[].label
Breaking the short-range proximity requirement in quantum dot/molecular catalyst hybrids for CO2 reduction via long-range hot electron sensitization

# publications[].label
Ferrocene-based redox switches for reversible single-molecule magnet behaviour in dysprosium(III) and erbium(III) bis-diamidoferrocene complexes

# publications[].label
Electrocatalytic reduction of carbon dioxide by finely tuned molecular catalysts

# researcherOn[].label
CAREER: Exploiting Novel Architectures for Advanced Heterometallic Magnetic Molecules and Materials

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# researcherOn[].label
Hybrid Catalyst System Combining Hot Electron-Generating Quantum Dots and Molecular Catalyst for Efficient Photocatalytic CO2 Reduction

# researcherOn[].awardedBy.label
National Science Foundation - (Arlington, Virginia, United States)

# streetAddress
Texas A&M University; Chemistry; 3255 TAMU

# organizations[]
Texas A&M Engineering Experiment Station (TEES)

# schools[]
Texas A&M Engineering Experiment Station (TEES)

# inTheNews[].label
College Of Science Awarded 3 Department Of Energy Grants